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US4515877A Expired / Lapsed US ⏱️ 0.0 years remaining

Image-recording materials and image-recording carried out using these to produce an optical mask

Assignee: BASF SE
•
Filing: 1983-11-22
•
Granted: 1985-05-07
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Expires: 2003-11-22
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Abstract

Abstract A resist film comprises a dimensionally stable base (B), which is transparent to actinic light in the wavelength range from 300 to 420 nm, and a mask-forming layer (ML) which is sensitive to heat radiation and contains a thermochromic system which, when irradiated with an IR laser having a wavelength greater than 1.00 μm, undergoes an irreversible change in its absorption spectrum in the wavelength range from 300 to 420 nm so that the optical density of the mask-forming layer (ML) in this wavelength range changes by not less than 1.3 units. The base of the resist film can also be applied onto the photosensitive relief-forming layer (RL) of a recording material to give a multilayer image-recording material. Imagewise irradiation with heat, for example using an IR laser, produces, in the mask-forming layer (ML) of the resist film, a UV photomask which is very useful for exposing photosensitive recording materials.

Inventors

  • 👤 Helmut Barzynski
  • 👤 Klaus Holoch

Bibliographic Details

Application Number —
Jurisdiction US
Data Source google_patents
Last Synchronized 2026-10-24 20:24
CPC Classifications
G; G03; G03F; G03F1/00; G03F1/68; B; B41; B41M; B41M5/00; B41M5/26; B41M5/28; B41M5/282; B41M5/30; B41M5/333; Y; Y10; Y10S; Y10S428/00; Y10S428/913; Y10S430/00; Y10S430/146; Y10S522/00; Y10S522/907

Claims Analysis

Total Claims: 8
Claim 1
Independent Claim 102 words
A resist film which comprises a dimensionally stable base (B), which is transparent to actinic light in the wavelength range from 300 to 420 nm, and a mask-forming layer (ML) which is applied on the base, wherein the said layer (ML) is sensitive to heat radiation and contains a thermochromic system which, when irradiated with an IR laser having a wavelength greater than 1.00 μm, undergoes an irreversible change in its absorption spectrum in the range from 300 to 420 nm so that the optical density of the mask-forming layer (ML) in this wavelength range changes by not less than 1.3 units.
Claim 2
Dependent Claim 102 words
A resist film which comprises a dimensionally stable base (B), which is transparent to actinic light in the wavelength range from 300 to 420 nm, and a mask-forming layer (ML) which is applied on the base, wherein the said layer (ML) is sensitive to heat radiation and contains a thermochromic system which, when irradiated with an IR laser having a wavelength greater than 1.00 μm, undergoes an irreversible change in its absorption spectrum in the range from 300 to 420 nm so that the optical density of the mask-forming layer (ML) in this wavelength range changes by not less than 1.3 units.
Claim 3
Dependent Claim 53 words
A resist film as claimed in claim 1, wherein the mask-forming layer (ML) has an optical density in the wavelength range from 300 to 420 nm of not more than 0.5, and, as a result of irradiation with heat, the absorption of actinic light in this wavelength range by the layer (ML) increases.
Claim 4
Dependent Claim 53 words
A resist film as claimed in claim 1, wherein the mask-forming layer (ML) has an optical density in the wavelength range from 300 to 420 nm of not less than 1.8, and, as a result of irradiation with heat, the absorption of actinic light in this wavelength range by the layer (ML) decreases.
Claim 5
Dependent Claim 35 words
A resist film as claimed in claim 1, wherein the mask-forming layer (ML) contains a thermochromic system comprising (a) a sulfonic acid ester and (b) an aromatic amine or the hydrochloride of an aromatic amine.
Claim 6
Dependent Claim 22 words
A resist film as claimed in claim 1, wherein the mask-forming layer contains a polymeric binder in addition to the thermochromic system.
Claim 7
Dependent Claim 20 words
A resist film as claimed in claim 1, wherein the mask-forming layer (ML) additionally contains a visible, thermochromic indicator system.
Claim 8
Dependent Claim 59 words
A process for the production of an optical mask, wherein a resist film consisting of a dimensionally stable base (B), which is transparent to actinic light in the wavelength range from 300 to 420 nm, and a mask-forming layer (ML) as claimed in claim 1 is exposed imagewise to an IR laser having a wavelength greater than 1.00 μm.

References Cited (Backward Citations)

GB1385241A Cited
GB1548439A Cited
US4225659A Cited
GB2081467A Cited
US4450023A Cited

USPTO Annuity & Maintenance Windows

Annuity Stage Window Opens Payment Deadline Surcharge Period Until Estimated Fee Status
3.5 Years (Year 4) 1988-05-06 1988-11-05 1989-05-07 $2000.00 Window Closed / Lapsed
7.5 Years (Year 8) 1992-05-06 1992-11-05 1993-05-07 $3760.00 Window Closed / Lapsed
11.5 Years (Year 12) 1996-05-06 1996-11-05 1997-05-07 $7700.00 Window Closed / Lapsed

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