Patent US1699398A successfully refreshed from Google Patents.
Patent US4515710A successfully refreshed from Google Patents.
US4515710A
Expired / Lapsed
US
⏱️ 0.0 years remaining
In-mold coating composition
Assignee: Omnova Services Inc
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Filing: 1984-04-05
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Granted: 1985-05-07
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Expires: 2004-04-05
Abstract
Abstract An FRP molding can be in-mold coated using a free radical peroxide initiated thermosetting composition of at least one polymerizable epoxy based oligomer having at least two acrylate groups, at least one copolymerizable ethylenically unsaturated monomer, at least one copolymerizable monoethylenically unsaturated compound having a --CO-- group and a --NH 2 , --NH-- and/or --OH group, carboxylated polyvinyl acetate, at least one zinc salt of a fatty acid, at least one calcium salt of a fatty acid, at least one copolymerizable tri or tetra acrylate, at least one accelerator for a peroxide initiator, conductive carbon black, a filler such as talc and at least one polyoxyalkylene glycol oligomer having two acrylate groups.
Inventors
- 👤 David S. Cobbledick
Bibliographic Details
Application Number
—
Jurisdiction
US
Data Source
google_patents
Last Synchronized
2026-10-25 15:30
CPC Classifications
C; C08; C08J; C08J5/00; C08F; C08F299/00; C08F299/02; C08F299/022; C08F299/024; C08F299/026; C09; C09D; C09D163/00; C09D163/10; C09D4/00
Claims Analysis
Total Claims: 13
Claim 1
Independent Claim
287 words
A composition useful as a thermosetting coating composition comprising (a) 100 parts by weight of at least one polymerizable epoxy based oligomer having at least two acrylate groups and a weight average molecular weight of from about 500 to 1,500, (b) from about 80 to 160 parts by weight of at least one copolymerizable ethylenically unsaturated monomer, (c) from about 10 to 120 parts by weight of at least one copolymerizable monoethylenically unsaturated compound having --CO-- group and a --NH 2 , --NH-- and/or --OH group, (d) from about 20 to 90 parts by weight of carboxylated polyvinyl acetate having an acid number of from about 1.5 to 4, (e) from about 0.2 to 5 parts by weight of at least one zinc salt of a fatty acid having at least 10 carbon atoms, (f) from about 0.01 to 1.0 part by weight of at least one accelerator for a peroxide initiator, (g) from about 5 to 30 parts by weight of conductive carbon black, (h) from about 50 to 155 parts by weight of a filler, (i) a copolymerizable or cocurable diacrylate compound having a weight average molecular weight of from about 250 to 5,000 and being at least one polyoxyalkylene glycol oligomer having two acrylate groups and (j) at least one copolymerizable tri or tetra acrylate having an average molecular weight of from about 250 to 1,000, the total of (i) and (j) being from about 5 to 120 parts by weight and the weight ratio of (i) to (j) being from about 10:1 to 1:10 and (k) at least one calcium salt of a fatty acid having at least 10 carbon atoms in an amount of from about 0.2 to 5 parts by weight.
Claim 2
Dependent Claim
287 words
A composition useful as a thermosetting coating composition comprising (a) 100 parts by weight of at least one polymerizable epoxy based oligomer having at least two acrylate groups and a weight average molecular weight of from about 500 to 1,500, (b) from about 80 to 160 parts by weight of at least one copolymerizable ethylenically unsaturated monomer, (c) from about 10 to 120 parts by weight of at least one copolymerizable monoethylenically unsaturated compound having --CO-- group and a --NH 2 , --NH-- and/or --OH group, (d) from about 20 to 90 parts by weight of carboxylated polyvinyl acetate having an acid number of from about 1.5 to 4, (e) from about 0.2 to 5 parts by weight of at least one zinc salt of a fatty acid having at least 10 carbon atoms, (f) from about 0.01 to 1.0 part by weight of at least one accelerator for a peroxide initiator, (g) from about 5 to 30 parts by weight of conductive carbon black, (h) from about 50 to 155 parts by weight of a filler, (i) a copolymerizable or cocurable diacrylate compound having a weight average molecular weight of from about 250 to 5,000 and being at least one polyoxyalkylene glycol oligomer having two acrylate groups and (j) at least one copolymerizable tri or tetra acrylate having an average molecular weight of from about 250 to 1,000, the total of (i) and (j) being from about 5 to 120 parts by weight and the weight ratio of (i) to (j) being from about 10:1 to 1:10 and (k) at least one calcium salt of a fatty acid having at least 10 carbon atoms in an amount of from about 0.2 to 5 parts by weight.
Claim 3
Dependent Claim
36 words
A composition according to claim 1 containing additionally at least one organic free radical peroxide initiator in an amount of up to about 5% by weight based on the weight of the polymerizable ethylenically unsaturated materials.
Claim 4
Dependent Claim
10 words
A composition according to claim 1 where (h) comprises talc.
Claim 5
Dependent Claim
59 words
A composition according to claim 1 where (a) is a diacrylate ester of a liquid Bisphenol A epoxy resin, (b) is styrene, (c) is hydroxypropyl methacrylate, (e) is zinc stearate, (f) is cobalt octoate, (h) is talc, (i) is polyoxyethylene glycol dimethacrylate having a molecular weight of about 770, (j) is trimethylol propane trimethacrylate and (k) is calcium stearate.
Claim 6
Independent Claim
379 words
A method which comprises in-mold coating a molded thermoset polyester resin or thermoset vinyl ester resin glass fiber composition containing from about 10 to 75% by weight of glass fibers with a thermosetting in-mold coating composition under pressure, at a temperature and for a period of time sufficient to cure said in-mold coating composition to form an adherent thermoset coating on said molded thermoset resin glass fiber composition, said in-mold coating composition comprising (a) 100 parts by weight of at least one polymerizable epoxy based oligomer having at least two acrylate groups and a weight average molecular weight of from about 500 to 1,500, (b) from about 80 to 160 parts by weight of at least one copolymerizable ethylenically unsaturated monomer, (c) from about 10 to 120 parts by weight of at least one copolymerizable monoethylenically unsaturated compound having a --CO-- group and a --NH 2 , --NH-- and/or --OH group, (d) from about 20 to 90 parts by weight of carboxylated polyvinyl acetate having an acid number of from about 1.5 to 4, (e) from about 0.2 to 5 parts by weight of at least one zinc salt of a fatty acid having at least 10 carbon atoms, (f) from about 0.01 to 1.0 part by weight of at least one accelerator for a peroxide initiator, (g) from about 5 to 30 parts by weight of conductive carbon black, (h) from about 50 to 155 parts by weight of a filler, (i) a copolymerizable or cocurable diacrylate compound having a weight average molecular weight of from about 250 to 5,000 and being at least one polyoxyalkylene glycol oligomer having two acrylate groups, (j) at least one copolymerizable tri or tetra acrylate having an average molecular weight of from about 250 to 1,000, the total of (i) and (j) being from about 5 to 120 parts by weight and the weight ratio of (i) to (j) being from about 10:1 to 1:10, (k) at least one calcium salt of a fatty acid having at least 10 carbon atoms in an amount of from about 0.2 to 5 parts by weight and at least one organic free radical peroxide initiator in an amount of up to about 5% by weight based on the weight of the polymerizable ethylenically unsaturated materials.
Claim 7
Independent Claim
379 words
A method which comprises in-mold coating a molded thermoset polyester resin or thermoset vinyl ester resin glass fiber composition containing from about 10 to 75% by weight of glass fibers with a thermosetting in-mold coating composition under pressure, at a temperature and for a period of time sufficient to cure said in-mold coating composition to form an adherent thermoset coating on said molded thermoset resin glass fiber composition, said in-mold coating composition comprising (a) 100 parts by weight of at least one polymerizable epoxy based oligomer having at least two acrylate groups and a weight average molecular weight of from about 500 to 1,500, (b) from about 80 to 160 parts by weight of at least one copolymerizable ethylenically unsaturated monomer, (c) from about 10 to 120 parts by weight of at least one copolymerizable monoethylenically unsaturated compound having a --CO-- group and a --NH 2 , --NH-- and/or --OH group, (d) from about 20 to 90 parts by weight of carboxylated polyvinyl acetate having an acid number of from about 1.5 to 4, (e) from about 0.2 to 5 parts by weight of at least one zinc salt of a fatty acid having at least 10 carbon atoms, (f) from about 0.01 to 1.0 part by weight of at least one accelerator for a peroxide initiator, (g) from about 5 to 30 parts by weight of conductive carbon black, (h) from about 50 to 155 parts by weight of a filler, (i) a copolymerizable or cocurable diacrylate compound having a weight average molecular weight of from about 250 to 5,000 and being at least one polyoxyalkylene glycol oligomer having two acrylate groups, (j) at least one copolymerizable tri or tetra acrylate having an average molecular weight of from about 250 to 1,000, the total of (i) and (j) being from about 5 to 120 parts by weight and the weight ratio of (i) to (j) being from about 10:1 to 1:10, (k) at least one calcium salt of a fatty acid having at least 10 carbon atoms in an amount of from about 0.2 to 5 parts by weight and at least one organic free radical peroxide initiator in an amount of up to about 5% by weight based on the weight of the polymerizable ethylenically unsaturated materials.
Claim 8
Dependent Claim
10 words
A method according to claim 5 where (h) comprises talc.
Claim 9
Dependent Claim
65 words
A method according to claim 5 where (a) is a diacrylate ester of a liquid Bisphenol A epoxy resin, (b) is styrene, (c) is hydroxypropyl methacrylate, (e) is zinc stearate, (f) is cobalt octoate, (h) is talc, (i) is polyoxyethylene glycol dimethacrylate having a molecular weight of about 770, (j) is trimethylol propane trimethacrylate, (k) is calcium stearate and said initiator is tertiary butyl perbenzoate.
Claim 10
Dependent Claim
300 words
A laminate comprising an adherent, thermoset in-mold coating composition in-mold coated onto a molded thermoset polyester resin or thermoset vinyl ester resin glass fiber composition containing from about 10 to 75% by weight of glass fibers, said in-mold coating composition comprising the reaction product of 100 parts by weight of at least one polymerizable epoxy based oligomer having at least two acrylate groups and a weight average molecular weight of from about 500 to 1,500, from about 80 to 160 parts by weight of at least one copolymerizable ethylenically unsaturated monomer, from about 10 to 120 parts by weight of at least one copolymerizable monoethylenically unsaturated compound having a --CO-- group and a --NH 2 , --NH-- and/or --OH group, (I) a copolymerizable or cocurable diacrylate compound having a weight average molecular weight of from about 250 to 5,000 and being at least one polyoxyalkylene glycol oligomer having two acrylate groups, (II) at least one copolymerizable tri or tetra acrylate having an average molecular weight of from about 250 to 1,000, the total of (I) and (II) being from about 5 to 120 parts by weight and the weight ratio of (I) to (II) being from about 10:1 to 1:10, in admixture with from about 20 to 90 parts by weight of carboxylated polyvinyl acetate having an acid number of from about 1.5 to 4, from about 0.2 to 5 parts by weight of at least one zinc salt of a fatty acid having at least 10 carbon atoms, at least one calcium salt of a fatty acid having at least 10 carbon atoms in an amount of from about 0.2 to 5 parts by weight, from about 5 to 30 parts by weight of conductive carbon black and from about 50 to 155 parts by weight of a filler.
Claim 11
Dependent Claim
300 words
A laminate comprising an adherent, thermoset in-mold coating composition in-mold coated onto a molded thermoset polyester resin or thermoset vinyl ester resin glass fiber composition containing from about 10 to 75% by weight of glass fibers, said in-mold coating composition comprising the reaction product of 100 parts by weight of at least one polymerizable epoxy based oligomer having at least two acrylate groups and a weight average molecular weight of from about 500 to 1,500, from about 80 to 160 parts by weight of at least one copolymerizable ethylenically unsaturated monomer, from about 10 to 120 parts by weight of at least one copolymerizable monoethylenically unsaturated compound having a --CO-- group and a --NH 2 , --NH-- and/or --OH group, (I) a copolymerizable or cocurable diacrylate compound having a weight average molecular weight of from about 250 to 5,000 and being at least one polyoxyalkylene glycol oligomer having two acrylate groups, (II) at least one copolymerizable tri or tetra acrylate having an average molecular weight of from about 250 to 1,000, the total of (I) and (II) being from about 5 to 120 parts by weight and the weight ratio of (I) to (II) being from about 10:1 to 1:10, in admixture with from about 20 to 90 parts by weight of carboxylated polyvinyl acetate having an acid number of from about 1.5 to 4, from about 0.2 to 5 parts by weight of at least one zinc salt of a fatty acid having at least 10 carbon atoms, at least one calcium salt of a fatty acid having at least 10 carbon atoms in an amount of from about 0.2 to 5 parts by weight, from about 5 to 30 parts by weight of conductive carbon black and from about 50 to 155 parts by weight of a filler.
Claim 12
Dependent Claim
17 words
A laminate according to claim 8 in which in said in-mold coating composition said filler comprises talc.
Claim 13
Dependent Claim
87 words
A laminate according to claim 8 in which in said in-mold coating composition said epoxy based oligomer is a diacrylate ester of a liquid Bisphenol A epoxy resin, said ethylenically unsaturated monomer is styrene, said monoethylenically unsaturated compound is hydroxy propyl methacrylate, said (I) copolymerizable or cocurable diacrylate compound is polyoxyethylene glycol dimethacrylate having a molecular weight of about 770, said (II) tri or tetra acrylate is trimethylol propane trimethacrylate, said filler comprises talc, said zinc salt is zinc stearate and said calcium salt is calcium stearate.
References Cited (Backward Citations)
No citation records indexed.
USPTO Annuity & Maintenance Windows
| Annuity Stage | Window Opens | Payment Deadline | Surcharge Period Until | Estimated Fee | Status |
|---|---|---|---|---|---|
| 3.5 Years (Year 4) | 1988-05-06 | 1988-11-05 | 1989-05-07 | $2000.00 | Window Closed / Lapsed |
| 7.5 Years (Year 8) | 1992-05-06 | 1992-11-05 | 1993-05-07 | $3760.00 | Window Closed / Lapsed |
| 11.5 Years (Year 12) | 1996-05-06 | 1996-11-05 | 1997-05-07 | $7700.00 | Window Closed / Lapsed |