2-Hydroxypropane sulphonic acid derivatives: their preparation and curable compositions thereof

Claim 2

A 2-hydroxypropane sulphonic acid derivative of general formula ##STR5## wherein n is a number having an average value from 0 to 12, ○A denotes saturation of aromatic unsaturation in an associated carbocyclic ring, and each of the R 1 and R 2 groups are independently selected from hydrogen and C 1-12 alkyl groups provided that each --C(R 1 )(R 2 )-group contains not more than 13 carbon atoms; or a salt thereof.

Claim 3

The derivative of claim 1 wherein each A moiety denotes aromatic unsaturation, n has an average value from 0 to 9 and the R 1 and R 2 groups are methyl groups.

Claim 4

The derivative of claim 1 in the form of the free acid or a tertiary or quaternary ammonium salt thereof.

Claim 5

A process for preparing the derivative of claim 1 wherein an epoxy resin of general formula ##STR6## wherein R 1 , R 2 , n and A are as defined in claim 1, is reacted with an ammonium sulphite or bisulphite of formula ##STR7## wherein R 3 is hydrogen and either R 4 , R 5 and R 6 are independently, selected from C 1-6 alkyl and 2-hydroxyalkyl groups or R 4 is a benzyl group optionally substituted by a methyl, methoxy or trifluoromethyl group and/or one or more halogen atoms or nitro groups and R 5 is a methyl group and R 6 is a methyl, ethyl or 2-hydroxyethyl group, provided that the total number of carbon atoms in the groups R 4 , R 5 and R 6 does not exceed 10; or R 3 , R 4 , R 5 and R 6 are independently C 1-4 alkyl groups; or R 3 , R 4 and R 5 are methyl groups and R 6 is a benzyl group or a C 5-16 alkyl group in homogeneous solution in an inert solvent, followed by evaporation of the solvent to isolate the corresponding ammonium salt of the sulphonic acid derivative.

Claim 6

A curable composition comprising a 2-hydroxypropane sulphonic acid derivative of claim 1 or a salt thereof and a synthetic co-curing resin selected from the group consisting of urea-formaldehyde resins, melamine-formaldehyde resins, benzo-guanamine-formaldehyde resins and phenolic resins.

Claim 7

A curable composition of claim 5 wherein the co-curing resin is a melamine-formaldehyde resin.

Claim 8

The curable composition of claim 6 wherein the melamine-formaldehyde resin is hexamethoxymethylmelamine.

Claim 9

The process of claim 4 wherein the ammonium salt is converted to the corresponding free acid by the addition of a strong acid followed by the separation of the precipitated free acid.

Claim 10

The process of claim 4 wherein the ammonium salt is converted to the corresponding sodium or potassium salt with an appropriate metal oxide or hydroxide.