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US4514537A Expired / Lapsed US ⏱️ 0.0 years remaining

Tetrafluoroethylene polymer dispersions

Assignee: EI PONT DE NEMOURS AND COMPANY A DE CORP
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Filing: 1984-02-09
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Granted: 1985-04-30
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Expires: 2004-02-09
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Abstract

Abstract Tetrafluoroethylene polymer coating dispersions when coated on glass fabric improve flex life of the fabric if the dispersions contain a selected silane, siloxane, water repellant, and polyethylene oxide surfactant of the formula C 9 F 17 O(CH 2 CH 2 O) 5 CH 3 .

Inventors

  • 👤 Robert J. Cavanaugh

Bibliographic Details

Application Number —
Jurisdiction US
Data Source google_patents
Last Synchronized 2026-11-04 03:23
CPC Classifications
C; C08; C08K; C08K5/00; C08K5/54

Claims Analysis

Total Claims: 8
Claim 1
Independent Claim 210 words
A coating dispersion which imparts resistance to attack by acidic flue gas to glass fabric coated with said dispersion, consisting essentially of (a) water, (b) 2-65% by weight tetrafluoroethylene polymer, said weight based on weight of water and polymer, said polymer being of film-forming molecular weight, (c) 2-60% by weight of a polyhydrolyzable silane of the formula R.sub.1 Si--OR).sub.3 wherein R is lower alkyl, preferably alkyl of 1-3 carbon atoms, and R 1 is phenyl or substituted lower alkyl, preferably of 1-3 carbon atoms, in which the substituents are selected from halogen, quaternary ammonium, or --NR'R" in which R' and R" are each H, lower alkyl, lower alkoxyalkyl, amino lower alkyl, hydroxyl lower alkyl, or substituted amino lower alkyl, said weight based on weight of tetrafluoroethylene polymer, (d) 1-20% by weight of a hydrocarbyl siloxane, said weight based on weight of tetrafluoroethylene polymer, (e) 1-20% by weight of a polymer of a fluorinated ester of an acrylic acid, said weight based on weight of tetrafluoroethylene polymer, and (f) 1-12% by weight of C 9 F 17 O(CH 2 CH 2 O) n R wherein n is an integer of 1 through 10 and R is hydrogen or alkyl of 1-10 carbon atoms, said weight based on weight of tetrafluoroethylene polymer.
Claim 2
Dependent Claim 210 words
A coating dispersion which imparts resistance to attack by acidic flue gas to glass fabric coated with said dispersion, consisting essentially of (a) water, (b) 2-65% by weight tetrafluoroethylene polymer, said weight based on weight of water and polymer, said polymer being of film-forming molecular weight, (c) 2-60% by weight of a polyhydrolyzable silane of the formula R.sub.1 Si--OR).sub.3 wherein R is lower alkyl, preferably alkyl of 1-3 carbon atoms, and R 1 is phenyl or substituted lower alkyl, preferably of 1-3 carbon atoms, in which the substituents are selected from halogen, quaternary ammonium, or --NR'R" in which R' and R" are each H, lower alkyl, lower alkoxyalkyl, amino lower alkyl, hydroxyl lower alkyl, or substituted amino lower alkyl, said weight based on weight of tetrafluoroethylene polymer, (d) 1-20% by weight of a hydrocarbyl siloxane, said weight based on weight of tetrafluoroethylene polymer, (e) 1-20% by weight of a polymer of a fluorinated ester of an acrylic acid, said weight based on weight of tetrafluoroethylene polymer, and (f) 1-12% by weight of C 9 F 17 O(CH 2 CH 2 O) n R wherein n is an integer of 1 through 10 and R is hydrogen or alkyl of 1-10 carbon atoms, said weight based on weight of tetrafluoroethylene polymer.
Claim 3
Dependent Claim 12 words
The coating dispersion of claim 1 wherein the tetrafluoroethylene polymer is polytetrafluoroethylene.
Claim 4
Dependent Claim 49 words
The coating dispersion of claim 2 wherein the silane has the formula R 1 Si(OR) 3 wherein R is --CH 3 or --CH 2 H 5 amd R 1 is substituted lower alkyl in which the substituent is in the γ position and is an amino- or amino-substituted group.
Claim 5
Dependent Claim 13 words
The coating dispersion of claim 3 wherein the silane is γ-aminopropyl triethoxy silane.
Claim 6
Dependent Claim 13 words
The coating dispersion of claim 3 wherein the silane is γ-aminopropyl trimethoxy silane.
Claim 7
Dependent Claim 15 words
The coating dispersion of claim 3 wherein the siloxane is an alkyl or alkyl/phenyl siloxane.
Claim 8
Dependent Claim 19 words
Glass fabric coated with the dispersion of claim 1, 2, 3, 4, 5 or 6, said coating being unsintered.

References Cited (Backward Citations)

US3142665A Cited
US3132123A Cited
US4370376A Cited

USPTO Annuity & Maintenance Windows

Annuity Stage Window Opens Payment Deadline Surcharge Period Until Estimated Fee Status
3.5 Years (Year 4) 1988-04-29 1988-10-29 1989-04-30 $2000.00 Window Closed / Lapsed
7.5 Years (Year 8) 1992-04-29 1992-10-29 1993-04-30 $3760.00 Window Closed / Lapsed
11.5 Years (Year 12) 1996-04-29 1996-10-29 1997-04-30 $7700.00 Window Closed / Lapsed

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