Helichromic-smectic liquid crystal compositions and display cells

Claim 2

A composition consisting essentially of a smectic liquid crystal material, and, in admixture therewith, an organic, nonionic, nonliquid-crystalline helichromic compound, said helichromic compound being soluble in said smectic liquid crystal material, said helichromic compound being a circularly dichroic dye, and said helichromic compound having the general formula Q--Z).sub.n wherein Q is an organic group having a chromophoric character; Z is an optically-active organic group; and n is an integer having a value of 1 or greater.

Claim 3

The composition of claim 1 wherein said Z comprises an asymmetric carbon atom.

Claim 4

The composition of claim 1 wherein Z is selected from the group consisting of (+)-2-methylalkyl, (+)-3-methylalkyl, (+)-2-methylalkoxy, (+)-3-methylalkoxy, (+)-citronellyl, (+)-camphanyl, (+)-3-methylcyclohexyl, (+)-α-methylbenzyl, (+)-2-methylbutylbiphenyl, (+)-2-methylbutylphenylthio, (+)-3-ethylhexylphenylbenzoate, (+)-2-methylbutylmethyl-2,3-dihydropermidine, (+)-3-methylcyclopentyl-2,3-dihydropermidine, (+)-2-methylcyclohexyl-2,3-dihydropermidine, (+)-2-phenethylamine, and (+)-N-2-methylbutylaminonapthalene.

Claim 5

The composition of claim 1 wherein Q is a radical selected from the group consisting of azo, azo-stilbene, benzothiazolyl polyazo, methine, azo-methine, merocyanine, methine-arylidene, tetrazine, oxadiazine and carbozole-azo radicals.

Claim 6

The composition of claim 1 wherein Q is an anthraquinone radical and Z is substituted in one or more of the 1 through 8 positions of said anthraquinone radical.

Claim 7

The composition of claim 5 wherein n is an integer having a value between 1 and 4 and Z is substituted in the 2, 3, 6 or 7 positions of said anthraquinone radical, or combinations thereof.

Claim 8

The composition of claim 1 wherein Q is an anthraquinone heterocyclic dicarboximide radical and Z is substituted on the nitrogen of said heterocyclic dicarboximide radical.

Claim 9

The composition of claim 3 wherein Z additionally comprises an organic linking group, said linking group selected from the group consisting of --CH═N--, --CH═CH--, --C═C, --N═N--, --NH--, --N(alk)--, --O--, --S--, --CH 2 -- p , --O--CH 2 -- p , ##STR79## --C 6 H 10 -- phenyl groups, naphthyl groups, cyclic carboximide groups and combinations thereof, wherein p is 1, 2, 3, 4 or 5.

Claim 10

The composition of claim 1 wherein Q additionally comprises one or more ballasting groups selected from the group consisting of --NH 2 , --CH 2 -- p CH 3 , --O--(CH 2 -- p CH 3 , --CH(CH 3 ) 2 , ##STR80## C 6 H 11 , phenyl groups, naphthyl groups, heterocyclic nitrogen, oxygen and sulfur-containing rings and combinations thereof, wherein p is 0, 1, 2, 3 or 4.

Claim 11

The composition of claim 1 wherein Q comprises at least one aromatic ring having one or more auxochromic substituents independently selected from the group consisting of lower alkyl, lower alkoxy, F, Cl, Br, NO 2 , NH 2 , N(alk) 2 , --N═CH(alk), OH, CN, CF 3 , SCN, OCH 3 , SH and carbonyl groups substituted thereon.

Claim 12

The composition of claim 1 wherein said helichromic compound is selected from the group consisting of ##STR81##

Claim 13

The composition of claim 1 wherein said helichromic compound is present in an amount effective to provide said composition with the ability to propagate incident light in a circularly polarized manner, so that all polarizations of said light are absorbed when said composition is used in a helichromic-smectic liquid crystal display device.

Claim 14

The composition of claim 12 wherein said helichromic compound is present in a concentration of between about 0.1 and 5 percent by weight of said smectic liquid crystal material.

Claim 15

The composition of claim 1 wherein said smectic liquid crystal material is selected from the group consisting of smectic A and smectic C liquid crystal materials.

Claim 16

The composition of claim 14 wherein said smectic liquid crystal material is selected from the group consisting of alkyl and alkoxy substituted cyano diphenyls and esters of alkyl and alkoxy substituted cyano diphenyls.

Claim 17

A thermally addressable liquid crystal display device having no auxiliary polarizers, which provides a high contrast image against a background comprising: a layer of a composition consisting essentially of a liquid crystal medium in admixture with an organic, nonionic, nonliquid-crystalline helichromic compound, said layer disposed between a top substrate and a bottom substrate, said helichromic compound being soluble in said liquid crystal medium, said helichromic compound being a circularly dichroic dye, and said helichromic compound having the general formula Q(Z).sub.n wherein Q is an organic group having a chromophoric character; Z is an optically-active organic group; and n is an integer having a value of 1 or greater; said liquid crystal medium being thermally sensitive and having a transition between at least two thermal phases, an upper phase being a nematic phase and a lower thermal phase being a smectic phase, said mixture having two possible states of orientation in said smectic phase, a first orientation state being substantially light absorbing and a second state being substantially light transmissive; a means of affecting a thermal transition between said lower thermal phase and said upper thermal phase; and a means of electrically addressing portions of said mixture to develop said second light transmissive state when said mixture passes rapidly into said lower thermal state from said upper thermal state, the remaining unaddressed portions of said mixture developing said first substantially light absorbing state when said mixture passes rapidly into said lower thermal state from said upper thermal state.

Claim 18

A thermally addressable liquid crystal display device having no auxiliary polarizers, which provides a high contrast image against a background comprising: a layer of a composition consisting essentially of a liquid crystal medium in admixture with an organic, nonionic, nonliquid-crystalline helichromic compound, said layer disposed between a top substrate and a bottom substrate, said helichromic compound being soluble in said liquid crystal medium, said helichromic compound being a circularly dichroic dye, and said helichromic compound having the general formula Q(Z).sub.n wherein Q is an organic group having a chromophoric character; Z is an optically-active organic group; and n is an integer having a value of 1 or greater; said liquid crystal medium being thermally sensitive and having a transition between at least two thermal phases, an upper phase being a nematic phase and a lower thermal phase being a smectic phase, said mixture having two possible states of orientation in said smectic phase, a first orientation state being substantially light absorbing and a second state being substantially light transmissive; a means of affecting a thermal transition between said lower thermal phase and said upper thermal phase; and a means of electrically addressing portions of said mixture to develop said second light transmissive state when said mixture passes rapidly into said lower thermal state from said upper thermal state, the remaining unaddressed portions of said mixture developing said first substantially light absorbing state when said mixture passes rapidly into said lower thermal state from said upper thermal state.

Claim 19

The display device of claim 16 wherein said means of electrically addressing portions of said medium comprises at least one electrode disposed adjacent said medium.

Claim 20

The display device of claim 17 wherein said electrode comprises a transparent electrically-conductive material which is disposed between said top substrate and said medium, said top substrate comprised of a transparent material.

Claim 21

The display device of claim 18 wherein said means of affecting a thermal transition between said lower thermal phase and said upper thermal phase comprises at least one heating electrode disposed between said bottom substrate and said medium.

Claim 22

The display device of claim 19 wherein said device additionally comprises a thermal barrier layer disposed between said heating electrode and said bottom substrate, said liquid crystal medium thus capable of absorbing a substantial amount of the heat from said heating electrode due to the insulative character of said thermal barrier layer.

Claim 23

The display device of claim 20 wherein said thermal barrier layer comprises polymonochloro-paraxylylene.

Claim 24

The display device of claim 16 wherein said device additionally comprises means disposed between said bottom substrate and said medium for reflecting light passing through said medium.

Claim 25

The display device of claim 22 wherein said means for reflecting said light and said means for affecting a thermal transition between said lower thermal phase and said upper thermal phase are comprised in at least one reflective heating electrode.

Claim 26

The display device of claim 23 wherein said reflective heating electrode has a micro-lenticular surface of concave or convex shaped cavities having a depth range of from about 0.5 to 2.5 micrometers and a diameter ranging from about 10 to 20 micrometers.

Claim 27

The display device of claim 22 wherein said device additionally comprises a light transparent material disposed adjacent said medium, between said medium and said top substrate, said light transparent material having an index of refraction equal to or less than about 1.6.

Claim 28

The display device of claim 16 wherein said means of electrically addressing portions of said medium comprises a number of column electrodes disposed between said medium and said top substrate, and said means of affecting a thermal transition comprises a number of row heating electrodes disposed between said medium and said bottom substrate, said column electrodes being substantially at right angles to said row electrodes, and said column electrodes capable of applying voltages sequentially to portions of said medium.