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Fast drilling invert emulsion drilling fluids

Assignee: O BRIEN-GOINS-SIMPSON & ASSOCIATES HOUSTON TX
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Filing: 1983-05-19
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Granted: 1985-04-02
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Expires: 2003-05-19
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Abstract

Abstract Disclosed are invert oil emulsion drilling fluids containing a non-toxic, biodegradable oil having a viscosity at 25° C. of less than 1.5 centipoise, a flash point of at least 60° C., an aniline point of at least 80° C., and a content of aromatic hydrocarbons of less than 1% by volume. These drilling fluids have a low viscosity at the high shear rates imparted to a drilling fluid at the bit during drilling. This low bit viscosity provides for faster penetration rates. Such drilling fluids containing a temperature stabilizing additive exhibit superior thermal stability.

Inventors

  • 👤 Thad O. Walker
  • 👤 Jay P. Simpson
  • 👤 Harry L. Dearing

Bibliographic Details

Application Number —
Jurisdiction US
Data Source google_patents
Last Synchronized 2026-11-08 21:12
CPC Classifications
C; C09; C09K; C09K8/00; C09K8/02; C09K8/32; C09K8/36; Y; Y10; Y10S; Y10S507/00; Y10S507/901; Y10S507/905

Claims Analysis

Total Claims: 9
Claim 1
Independent Claim 281 words
A fast drilling invert oil emulsion drilling fluid having enhanced stability at elevated temperatures which comprises oil, water, a water-in-oil emulsifier, a weighting agent, a suspending agent, and a temperature stabilizing additive, wherein said oil is a refined petroleum oil fraction containing primarily straight chain paraffinic hydrocarbons and less than 1% by volume of aromatic hydrocarbons, having a viscosity less than 1.5 centipoises at 25° C., a flash point of at least 60° C., and an aniline point of at least 80° C.; wherein said water contains up to a saturation amount of NaCl or CaCl 2 ; wherein said suspending agent is an organophilic clay which comprises the reaction product of a clay selected from the group consisting of attapulgite, bentonite, hectorite, saponite, and sepiolite, and a quaternary ammonium salt having the structural formula: ##STR2## wherein R 1 , R 2 , R 3 , and R 4 are independently selected from the group consisting of C a H 2a+1-x B x , C b H 2b-1-x B x , C 6 H 5-x B x CH 2 , and mixtures thereof, 1≦a≦30, 3≦b≦30, 0≦x≦2, B is a radical selected from the group consisting of OH, Cl, Br, C 6 H 5 , and mixtures thereof, and A is a charge balancing anion, provided that at least one R contains at least 12 carbon atoms, and R 1 , R 2 , R 3 , and R 4 collectively contain at least 20 carbon atoms; and wherein said temperature stabilizing additive contains from 2 to 6 carbon atoms and from 2 to 4 polar groups selected from the group consisting of OH, NH 2 , and mixtures thereof, per molecule.
Claim 2
Dependent Claim 281 words
A fast drilling invert oil emulsion drilling fluid having enhanced stability at elevated temperatures which comprises oil, water, a water-in-oil emulsifier, a weighting agent, a suspending agent, and a temperature stabilizing additive, wherein said oil is a refined petroleum oil fraction containing primarily straight chain paraffinic hydrocarbons and less than 1% by volume of aromatic hydrocarbons, having a viscosity less than 1.5 centipoises at 25° C., a flash point of at least 60° C., and an aniline point of at least 80° C.; wherein said water contains up to a saturation amount of NaCl or CaCl 2 ; wherein said suspending agent is an organophilic clay which comprises the reaction product of a clay selected from the group consisting of attapulgite, bentonite, hectorite, saponite, and sepiolite, and a quaternary ammonium salt having the structural formula: ##STR2## wherein R 1 , R 2 , R 3 , and R 4 are independently selected from the group consisting of C a H 2a+1-x B x , C b H 2b-1-x B x , C 6 H 5-x B x CH 2 , and mixtures thereof, 1≦a≦30, 3≦b≦30, 0≦x≦2, B is a radical selected from the group consisting of OH, Cl, Br, C 6 H 5 , and mixtures thereof, and A is a charge balancing anion, provided that at least one R contains at least 12 carbon atoms, and R 1 , R 2 , R 3 , and R 4 collectively contain at least 20 carbon atoms; and wherein said temperature stabilizing additive contains from 2 to 6 carbon atoms and from 2 to 4 polar groups selected from the group consisting of OH, NH 2 , and mixtures thereof, per molecule.
Claim 3
Dependent Claim 87 words
The drilling fluid of claim 1 wherein said emulsifier is a polyamide obtained by reacting a monocarboxylic fatty acid, at least 50% by weight of which contains 18 carbon atoms, and a dicarboxylic acid containing from 4 to 8 carbon atoms with a polyethylene polyamine containing from 3 to 7 nitrogen atoms in a molar ratio of said monocarboxylic acid: dicarboxylic acid: polyethylene polyamine from about 0.4 n-0.7 n:0.3 n-0.15 n: 1 where n is the number of nitrogen atoms in each molecule of said polyethylene polyamine.
Claim 4
Dependent Claim 25 words
The drilling fluid of claim 2 wherein said monocarboxylic acid contains from 16 to 18 carbon atoms and said dicarboxylic acid contains 4 carbon atoms.
Claim 5
Dependent Claim 24 words
The drilling fluid of claim 3 wherein said dicarboxylic acid is selected from the group consisting of maleic acid, fumaric acid, and mixtures thereof.
Claim 6
Dependent Claim 57 words
The drilling fluid of claim 1 wherein said temperature stabilizing additive is selected from the group consisting of ethylene glycol, propylene glycol, glycerin, and amino compounds having the structural formula H.sub.y N(C.sub.2 H.sub.4 A).sub.z where 0≦y≦2, 1≦z≦3, y+z=3, and A is a polar group selected from the group consisting of NH 2 , OH, and mixtures thereof.
Claim 7
Dependent Claim 24 words
The drilling fluid of claim 1 which contains a stabilizing agent to promote the oil wetting of any solids which enter said drilling fluid.
Claim 8
Dependent Claim 19 words
The drilling fluid of claim 1 which contains an additive to reduce the fluid loss of said drilling fluid.
Claim 9
Dependent Claim 65 words
A method of enhancing the rate of penetration while drilling a well which comprises circulating the invert oil emulsion drilling fluid of claim 1 throughout a borehole while simultaneously rotating a string of drill pipe containing a rotary drill bit on its lower end in contact with the bottom of the borehole, thereby removing the drill cuttings formed by said drill bit from said borehole.

USPTO Annuity & Maintenance Windows

Annuity Stage Window Opens Payment Deadline Surcharge Period Until Estimated Fee Status
3.5 Years (Year 4) 1988-04-01 1988-10-01 1989-04-02 $2000.00 Window Closed / Lapsed
7.5 Years (Year 8) 1992-04-01 1992-10-01 1993-04-02 $3760.00 Window Closed / Lapsed
11.5 Years (Year 12) 1996-04-01 1996-10-01 1997-04-02 $7700.00 Window Closed / Lapsed

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