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US4501811A Expired / Lapsed US ⏱️ 0.0 years remaining

Process for making lithographic printing plates

Assignee: Mitsubishi Paper Mills Ltd
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Filing: 1983-10-13
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Granted: 1985-02-26
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Expires: 2003-10-13
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Abstract

Abstract Disclosed is a process for making a lithographic printing plate by utilizing the silver complex diffusion transfer process and using a neon-helium laser or an LED which comprises imagewise exposing to the radiation a photosensitive element including an emulsion layer which is spectrally sensitized with an anion- or betaine-type meso-substituted trimethine cyanine dye having at least one beta -naphthothiazole nucleus and developing the element by the silver complex diffusion transfer process.

Inventors

  • 👤 Masahiko Saikawa
  • 👤 Eiji Kanada
  • 👤 Akira Tanaka
  • 👤 Kazunaka Endo

Bibliographic Details

Application Number —
Jurisdiction US
Data Source google_patents
Last Synchronized 2026-11-06 08:23
CPC Classifications
G; G03; G03F; G03F7/00; G03F7/004; G03F7/06; G03F7/07; Y; Y10; Y10S; Y10S430/00; Y10S430/146

Claims Analysis

Total Claims: 10
Claim 1
Independent Claim 229 words
A process for making a lithographic printing plate, which comprises imagewise exposing to the radiation from a neon-helium laser or a light-emitting diode a photosensitive element comprising at least emulsion layer of silver halide containing 70 mol-% or more of silver chloride and surface layer containing physical development nuclei, said emulsion layer being spectrally sensitized with an anion- or betaine-type meso-substituted trimethine cyanine dye having at least one β-naphthothiazole nucelus represented by the general formula (I) ##STR12## where R 1 and R 2 each represents an alkyl group, an alkenyl group, an aryl group, or an aralkyl group, at least one of R 1 and R 2 is a group having a sulfo or carboxyl group; R 3 and R 4 each represents a hydrogen atom, an alkyl group, an alkoxy group, an aryl group, a hydroxyl group, an alkoxycarbonyl group, or a halogen atom, R 3 and R 4 may jointly form a benzene ring; R 5 represents an alkyl group, an aryl group, or an aralkyl group; Y 1 and Y 2 each represents a sulfur or selenium atom, provided that Y 1 and Y 2 are not simultaneously a selenium atom; X represents a cationic form of a hydrogen atom, an alkali metal atom, or an ammonium group; and m is 1 or 0, and developing the exposed element by the silver complex diffusion transfer process.
Claim 2
Dependent Claim 229 words
A process for making a lithographic printing plate, which comprises imagewise exposing to the radiation from a neon-helium laser or a light-emitting diode a photosensitive element comprising at least emulsion layer of silver halide containing 70 mol-% or more of silver chloride and surface layer containing physical development nuclei, said emulsion layer being spectrally sensitized with an anion- or betaine-type meso-substituted trimethine cyanine dye having at least one β-naphthothiazole nucelus represented by the general formula (I) ##STR12## where R 1 and R 2 each represents an alkyl group, an alkenyl group, an aryl group, or an aralkyl group, at least one of R 1 and R 2 is a group having a sulfo or carboxyl group; R 3 and R 4 each represents a hydrogen atom, an alkyl group, an alkoxy group, an aryl group, a hydroxyl group, an alkoxycarbonyl group, or a halogen atom, R 3 and R 4 may jointly form a benzene ring; R 5 represents an alkyl group, an aryl group, or an aralkyl group; Y 1 and Y 2 each represents a sulfur or selenium atom, provided that Y 1 and Y 2 are not simultaneously a selenium atom; X represents a cationic form of a hydrogen atom, an alkali metal atom, or an ammonium group; and m is 1 or 0, and developing the exposed element by the silver complex diffusion transfer process.
Claim 3
Dependent Claim 26 words
A process according to claim 1, wherein at least one of R 1 and R 2 is a sulfoalkyl group having 1 to 5 carbon atoms.
Claim 4
Dependent Claim 28 words
A process according to claim 1, wherein the dye is used in an amount of 1×10 -5 to 1×10 -2 mole for 1 mole of the silver halide.
Claim 5
Dependent Claim 18 words
A process according to claim 1, wherein the silver halide comprises at least 80 mole-% of silver chloride.
Claim 6
Dependent Claim 20 words
A process according to claim 1, wherein the silver halide has an average grain size of 0.2 to 0.6 μm.
Claim 7
Dependent Claim 23 words
A process according to claim 1, wherein the silver halide emulsion contains a compound of metals of Group VIII of the periodic table.
Claim 8
Dependent Claim 18 words
A process according to claim 1, wherein an antihalation layer is provided under the silver halide emulsion layer.
Claim 9
Dependent Claim 17 words
A process according to claim 1, wherein the photosensitive element is exposed to the neon-helium layer beam.
Claim 10
Dependent Claim 28 words
A printing process which comprises applying a printing ink to the silver image formed on the surface layer of the lithographic printing plate obtained according to claim 1.

References Cited (Backward Citations)

US3177210A Cited
US3459553A Cited
US3776739A Cited
US3867146A Cited
US4134769A Cited
US4134769B1 Cited

USPTO Annuity & Maintenance Windows

Annuity Stage Window Opens Payment Deadline Surcharge Period Until Estimated Fee Status
3.5 Years (Year 4) 1988-02-26 1988-08-27 1989-02-26 $2000.00 Window Closed / Lapsed
7.5 Years (Year 8) 1992-02-26 1992-08-27 1993-02-26 $3760.00 Window Closed / Lapsed
11.5 Years (Year 12) 1996-02-26 1996-08-27 1997-02-26 $7700.00 Window Closed / Lapsed

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