Patent US4501811A successfully refreshed from Google Patents.
US4501811A
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US
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Process for making lithographic printing plates
Assignee: Mitsubishi Paper Mills Ltd
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Filing: 1983-10-13
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Granted: 1985-02-26
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Expires: 2003-10-13
Abstract
Abstract Disclosed is a process for making a lithographic printing plate by utilizing the silver complex diffusion transfer process and using a neon-helium laser or an LED which comprises imagewise exposing to the radiation a photosensitive element including an emulsion layer which is spectrally sensitized with an anion- or betaine-type meso-substituted trimethine cyanine dye having at least one beta -naphthothiazole nucleus and developing the element by the silver complex diffusion transfer process.
Inventors
- 👤 Masahiko Saikawa
- 👤 Eiji Kanada
- 👤 Akira Tanaka
- 👤 Kazunaka Endo
Bibliographic Details
Application Number
—
Jurisdiction
US
Data Source
google_patents
Last Synchronized
2026-11-06 08:23
CPC Classifications
G; G03; G03F; G03F7/00; G03F7/004; G03F7/06; G03F7/07; Y; Y10; Y10S; Y10S430/00; Y10S430/146
Claims Analysis
Total Claims: 10
Claim 1
Independent Claim
229 words
A process for making a lithographic printing plate, which comprises imagewise exposing to the radiation from a neon-helium laser or a light-emitting diode a photosensitive element comprising at least emulsion layer of silver halide containing 70 mol-% or more of silver chloride and surface layer containing physical development nuclei, said emulsion layer being spectrally sensitized with an anion- or betaine-type meso-substituted trimethine cyanine dye having at least one β-naphthothiazole nucelus represented by the general formula (I) ##STR12## where R 1 and R 2 each represents an alkyl group, an alkenyl group, an aryl group, or an aralkyl group, at least one of R 1 and R 2 is a group having a sulfo or carboxyl group; R 3 and R 4 each represents a hydrogen atom, an alkyl group, an alkoxy group, an aryl group, a hydroxyl group, an alkoxycarbonyl group, or a halogen atom, R 3 and R 4 may jointly form a benzene ring; R 5 represents an alkyl group, an aryl group, or an aralkyl group; Y 1 and Y 2 each represents a sulfur or selenium atom, provided that Y 1 and Y 2 are not simultaneously a selenium atom; X represents a cationic form of a hydrogen atom, an alkali metal atom, or an ammonium group; and m is 1 or 0, and developing the exposed element by the silver complex diffusion transfer process.
Claim 2
Dependent Claim
229 words
A process for making a lithographic printing plate, which comprises imagewise exposing to the radiation from a neon-helium laser or a light-emitting diode a photosensitive element comprising at least emulsion layer of silver halide containing 70 mol-% or more of silver chloride and surface layer containing physical development nuclei, said emulsion layer being spectrally sensitized with an anion- or betaine-type meso-substituted trimethine cyanine dye having at least one β-naphthothiazole nucelus represented by the general formula (I) ##STR12## where R 1 and R 2 each represents an alkyl group, an alkenyl group, an aryl group, or an aralkyl group, at least one of R 1 and R 2 is a group having a sulfo or carboxyl group; R 3 and R 4 each represents a hydrogen atom, an alkyl group, an alkoxy group, an aryl group, a hydroxyl group, an alkoxycarbonyl group, or a halogen atom, R 3 and R 4 may jointly form a benzene ring; R 5 represents an alkyl group, an aryl group, or an aralkyl group; Y 1 and Y 2 each represents a sulfur or selenium atom, provided that Y 1 and Y 2 are not simultaneously a selenium atom; X represents a cationic form of a hydrogen atom, an alkali metal atom, or an ammonium group; and m is 1 or 0, and developing the exposed element by the silver complex diffusion transfer process.
Claim 3
Dependent Claim
26 words
A process according to claim 1, wherein at least one of R 1 and R 2 is a sulfoalkyl group having 1 to 5 carbon atoms.
Claim 4
Dependent Claim
28 words
A process according to claim 1, wherein the dye is used in an amount of 1×10 -5 to 1×10 -2 mole for 1 mole of the silver halide.
Claim 5
Dependent Claim
18 words
A process according to claim 1, wherein the silver halide comprises at least 80 mole-% of silver chloride.
Claim 6
Dependent Claim
20 words
A process according to claim 1, wherein the silver halide has an average grain size of 0.2 to 0.6 μm.
Claim 7
Dependent Claim
23 words
A process according to claim 1, wherein the silver halide emulsion contains a compound of metals of Group VIII of the periodic table.
Claim 8
Dependent Claim
18 words
A process according to claim 1, wherein an antihalation layer is provided under the silver halide emulsion layer.
Claim 9
Dependent Claim
17 words
A process according to claim 1, wherein the photosensitive element is exposed to the neon-helium layer beam.
Claim 10
Dependent Claim
28 words
A printing process which comprises applying a printing ink to the silver image formed on the surface layer of the lithographic printing plate obtained according to claim 1.
References Cited (Backward Citations)
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USPTO Annuity & Maintenance Windows
| Annuity Stage | Window Opens | Payment Deadline | Surcharge Period Until | Estimated Fee | Status |
|---|---|---|---|---|---|
| 3.5 Years (Year 4) | 1988-02-26 | 1988-08-27 | 1989-02-26 | $2000.00 | Window Closed / Lapsed |
| 7.5 Years (Year 8) | 1992-02-26 | 1992-08-27 | 1993-02-26 | $3760.00 | Window Closed / Lapsed |
| 11.5 Years (Year 12) | 1996-02-26 | 1996-08-27 | 1997-02-26 | $7700.00 | Window Closed / Lapsed |