← Back to Patent Explorer
US4499663A Expired / Lapsed US ⏱️ 0.0 years remaining

Method of fabricating a monolithic core for a solid oxide fuel cell

Assignee: United States Department of Energy
•
Filing: 1983-10-12
•
Granted: 1985-02-19
•
Expires: 2003-10-12
📄 Original PDF 🌐 Google Patents 🔄 Sync Now

Abstract

Abstract A method is disclosed for forming a core for use in a solid oxide fuel cell that electrochemically combines fuel and oxidant for generating galvanic output. The core has an array of electrolyte and interconnect walls that are substantially devoid of any composite inert materials for support consisting instead only of the active anode, cathode, electrolyte and interconnect materials. Each electrolyte wall consists of cathode and anode materials sandwiching electrolyte material therebetween, and each interconnect wall consists of the cathode and anode materials sandwiching interconnect material therebetween. The electrolyte and interconnect walls define a plurality of substantially parallel core passageways alternately having respectively the inside faces thereof with only the anode material or with only the cathode material exposed. In the wall structure, the electrolyte and interconnect materials are only 0.002-0.01 cm thick; and the cathode and anode materials are only 0.002-0.05 cm thick. The method consists of building up the electrolyte and interconnect walls by depositing each material on individually and endwise of the wall itself, where each material deposit is sequentially applied for one cycle; and where the depositing cycle is repeated many times until the material buildup is sufficient to formulate the core. The core is heat cured to become dimensionally and structurally stable.

Inventors

  • 👤 Stanley A. Zwick
  • 👤 John P. Ackerman

Bibliographic Details

Application Number —
Jurisdiction US
Data Source google_patents
Last Synchronized 2026-10-25 21:40
CPC Classifications
H; H01; H01M; H01M8/00; H01M8/10; H01M8/12; H01M8/1213; H01M4/00; H01M4/86; H01M4/90; H01M4/9016; H01M4/9025; H01M4/9033; H01M4/9041; H01M4/905; H01M4/9066; Y; Y02; Y02E; Y02E60/00; Y02E60/30; Y02E60/50; Y10; Y10T; Y10T29/00; Y10T29/49; Y10T29/49002; Y10T29/49108

Claims Analysis

Total Claims: 20
Claim 1
Independent Claim 255 words
A method of making a fuel cell core for electrochemically combining fuel and oxidant for generation of galvanic output, the core having an array of electrolyte and interconnect walls, each electrolyte wall consisting of thin layers of cathode and anode materials respectively, sandwiching a thin layer of electrolyte material therebetween, each interconnect wall consisting of thin layers of the cathode and anode, respectively sandwiching a thin layer of interconnect material therebetween, whereby separate sections of said electrolyte wall are arranged between separate sections of adjacent interconnect walls operable to define a plurality of core passageways alternately arranged respectively where the inside faces thereof are formed either of only the anode material or of only the cathode material, each core passageway having the anode material on the inside being for the passage of fuel and each core passageway having the cathode material on the inside being for the passage of oxidant, the method being to build up the core electrolyte and interconnect walls simultaneously in a direction endwise of the walls and axially of the defined core passageways by applying the separate anode, cathode, electrolyte and interconnect materials onto itself as fine deposits or buildups according to the pattern of material as required in the core, the material applications for the respective materials being made separately and sequentially and repetitively to buildup the wall structure endwise of itself or axially of the core passageways, and heat curing the composite core to fuse the material layers and deposits together and make the core monolithic and dimensionally stable.
Claim 2
Independent Claim 255 words
A method of making a fuel cell core for electrochemically combining fuel and oxidant for generation of galvanic output, the core having an array of electrolyte and interconnect walls, each electrolyte wall consisting of thin layers of cathode and anode materials respectively, sandwiching a thin layer of electrolyte material therebetween, each interconnect wall consisting of thin layers of the cathode and anode, respectively sandwiching a thin layer of interconnect material therebetween, whereby separate sections of said electrolyte wall are arranged between separate sections of adjacent interconnect walls operable to define a plurality of core passageways alternately arranged respectively where the inside faces thereof are formed either of only the anode material or of only the cathode material, each core passageway having the anode material on the inside being for the passage of fuel and each core passageway having the cathode material on the inside being for the passage of oxidant, the method being to build up the core electrolyte and interconnect walls simultaneously in a direction endwise of the walls and axially of the defined core passageways by applying the separate anode, cathode, electrolyte and interconnect materials onto itself as fine deposits or buildups according to the pattern of material as required in the core, the material applications for the respective materials being made separately and sequentially and repetitively to buildup the wall structure endwise of itself or axially of the core passageways, and heat curing the composite core to fuse the material layers and deposits together and make the core monolithic and dimensionally stable.
Claim 3
Dependent Claim 74 words
The method of making an electrochemical fuel cell core according to claim 1, wherein said cathode material is lanthanum manganite (LaMnO 3 ); said anode material is cobalt yttria-stabilized zirconia cermet or mixture (Co+ZrO 2 +Y 2 O 3 ); said electrolyte is yttria-stabilized zirconia (ZrO 2 +Y 2 O 3 ) and said interconnect is lanthanum chromite (LaCrO 3 ), the lanthanum manganite and lanthanum chromite being suitably doped to obtain electrical conductivity.
Claim 4
Dependent Claim 65 words
The method of making an electrochemical fuel cell core according to claim 1, wherein the cathode and anode materials are each applied in a continuous endless loop pattern spaced from one another and disposed substantially parallel to one another as they are being built up the define core passageways are generally parallel relative to one another and extended in a direction axially through the core.
Claim 5
Dependent Claim 40 words
The method of making an electrochemical fuel cell core according to claim 3, wherein said electrolyte and interconnect materials are each applied between the deposits of the cathode and anode materials sequentially after the later material deposits had been applied.
Claim 6
Dependent Claim 35 words
The method of making an electrochemical fuel cell core according to claim 4, wherein the cathode and anode material deposits are each of the order of 0.002-0.05 cm in the thickness and are correspondingly similar.
Claim 7
Dependent Claim 65 words
The method of making an electrochemical fuel cell core according to claim 5, wherein the electrolyte and interconnect materials each is of the order of 0.002-0.01 cm in the layer thickness of the defined wall structure, and wherein the material deposit of each per application is of the order of 0.002-0.05 cm to correspond to the buildup per application of the anode and cathode materials.
Claim 8
Dependent Claim 25 words
The method of making an electrochemical fuel cell core according to claim 5, wherein each electrolyte wall is of the order of 0.006-0.110 cm thick.
Claim 9
Dependent Claim 25 words
The method of making an electrochemical fuel cell core according to claim 5, wherein each interconnect wall is of the order of 0.006-0.110 cm thick.
Claim 10
Dependent Claim 27 words
The method of making an electrochemical fuel cell core according to claim 1, wherein the electrolyte and interconnect walls are substantially devoid of any composite inert material.
Claim 11
Dependent Claim 24 words
The method of making an electrochemical fuel cell core according to claim 1, and further etching or trimming the deposits by high energy beam.
Claim 12
Dependent Claim 27 words
The method of making an electrochemical fuel cell according to claim 1, wherein each application of the cathode and anode materials is by means such as painting.
Claim 13
Dependent Claim 27 words
The method of making an electrochemical fuel cell according to claim 1, wherein each application of the cathode and anode materials is by means such as spraying.
Claim 14
Dependent Claim 28 words
The method of making an electrochemical fuel cell according to claim 1, wherein each application of the cathode and anode materials is by means such as vapor deposition.
Claim 15
Dependent Claim 27 words
The method of making an electrochemical fuel cell core according to claim 12, wherein the electrolyte and interconnect walls are substantially devoid of any composite inert material.
Claim 16
Dependent Claim 24 words
The method of making an electrochemical fuel cell core according to claim 14, and further etching or trimming the deposits by high energy beam.
Claim 17
Dependent Claim 40 words
The method of making an electrochemical fuel cell core according to claim 15, wherein said electrolyte and interconnect materials are each applied between the deposits of the cathode and anode materials sequentially after the later material deposits had been applied.
Claim 18
Dependent Claim 35 words
The method of making an electrochemical fuel cell core according to claim 16, wherein the cathode and anode material deposits are each of the order of 0.002-0.05 cm in the thickness and are correspondingly similar.
Claim 19
Dependent Claim 65 words
The method of making an electrochemical fuel cell core according to claim 17, wherein the electrolyte and interconnect materials each is of the order of 0.002-0.01 cm in the layer thickness of the defined wall structure, and wherein the material deposit of each per application is of the order of 0.002-0.05 cm to correspond to the buildup per application of the anode and cathode materials.
Claim 20
Dependent Claim 50 words
The method of making an electrochemical fuel cell according to claim 1, wherein further applying a filter material separately and sequentially and repetitively where the passageways will be defined to fill the passageways, and heating the core as it has been built up so as to remove the filler material.

References Cited (Backward Citations)

US3402230A Cited
US3647542A Cited
US3558360A Cited
US3617385A Cited
US3754995A Cited
US3834943A Cited
US3905775A Cited
US4142024A Cited
US4195119A Cited
US4317867A Cited
US4248941A Cited

USPTO Annuity & Maintenance Windows

Annuity Stage Window Opens Payment Deadline Surcharge Period Until Estimated Fee Status
3.5 Years (Year 4) 1988-02-19 1988-08-20 1989-02-19 $2000.00 Window Closed / Lapsed
7.5 Years (Year 8) 1992-02-19 1992-08-20 1993-02-19 $3760.00 Window Closed / Lapsed
11.5 Years (Year 12) 1996-02-19 1996-08-20 1997-02-19 $7700.00 Window Closed / Lapsed

Assigned Categories & Tags

No categories assigned to this patent yet.

Assign Category Tag