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US4497657A Expired / Lapsed US ⏱️ 0.0 years remaining

Method for recovering platinum in a nitric acid plant

Assignee: BASF Catalysts LLC
•
Filing: 1983-04-27
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Granted: 1985-02-05
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Expires: 2003-04-27
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Abstract

Abstract Improved recovery of platinum lost from the catalyst gauze in a nitric acid plant is obtained by using palladium containing recovery gauzes configured to enhance the mass transfer characteristics of the system.

Inventors

  • 👤 William R. Hatfield
  • 👤 Ronald M. Heck
  • 👤 Thomas H. Hsiung

Bibliographic Details

Application Number —
Jurisdiction US
Data Source google_patents
Last Synchronized 2026-11-05 23:26
CPC Classifications
C; C22; C22B; C22B11/00; C22B11/02; C22B11/021; Y; Y02; Y02P; Y02P10/00; Y02P10/20; Y10; Y10T; Y10T428/00; Y10T428/12; Y10T428/12014; Y10T428/1216; Y10T428/1234

Claims Analysis

Total Claims: 24
Claim 1
Independent Claim 137 words
A method for the recovery of platinum and/or rhodium lost from a platinum-containing catalyst during ammonia oxidation processes at temperatures above 850° C.; which comprises bringing said lost platinum and/or rhodium into contact with a foraminate element fabricated from material consisting essentially of palladium and nickel characterized by (a) a novel configuration whereby the initial product of mesh size (N) and wire diameter (d w ) for said element is greater than at least about 0.2 and (b) where, for a given nitrogen throughput, the weight recovery efficiency (η') is a function of the wire diameter (d w ) and mesh size (N) combination, and such that weight recovery efficiency is improved by increasing either the mesh size (N) at a given recovery, wire diameter (d w ) or the wire diameter at a given mesh size.
Claim 2
Independent Claim 137 words
A method for the recovery of platinum and/or rhodium lost from a platinum-containing catalyst during ammonia oxidation processes at temperatures above 850° C.; which comprises bringing said lost platinum and/or rhodium into contact with a foraminate element fabricated from material consisting essentially of palladium and nickel characterized by (a) a novel configuration whereby the initial product of mesh size (N) and wire diameter (d w ) for said element is greater than at least about 0.2 and (b) where, for a given nitrogen throughput, the weight recovery efficiency (η') is a function of the wire diameter (d w ) and mesh size (N) combination, and such that weight recovery efficiency is improved by increasing either the mesh size (N) at a given recovery, wire diameter (d w ) or the wire diameter at a given mesh size.
Claim 3
Dependent Claim 26 words
The method according to claim 1 wherein the initial product of N and d w is in the range of from about 0.3 to about 0.9.
Claim 4
Dependent Claim 13 words
The method according to claim 1 wherein said element is a woven gauze.
Claim 5
Dependent Claim 21 words
The method according to claim 1 wherein one or more of said elements are sandwiched between a plurality of separator screens.
Claim 6
Dependent Claim 23 words
The method according to claim 1 wherein said element is comprised of at least about 80% palladium by weight and the balance nickel.
Claim 7
Dependent Claim 48 words
The method according to claim 1 wherein N is in the range of from about 10-80, d w is in the range of from about 0.003 to 0.090 and their respective values are such that the initial product of N×d w is greater than at least about 0.2.
Claim 8
Dependent Claim 23 words
The method according to claim 1 wherein the initial product of N×d w is in the range of from about 0.2 to 0.9.
Claim 9
Dependent Claim 118 words
A foraminate element for the recovery of platinum and/or rhodium lost from a platinum-containing catalyst; said element being fabricated from a material consisting essentially of palladium and nickel characterized by (a) a novel configuration whereby the initial product of mesh size (N) and wire diameter (d w ) for said element is greater than at least about 0.2 and (b) where, for a given nitrogen throughput, the weight recovery efficiency (η') is a function of the wire diameter (d w ) and mesh size (N) combination and weight recovery efficiency is improved by increasing the mesh size (N) for a given wire diameter (d w ) or increasing wire diameter (d w ) for a given mesh size.
Claim 10
Dependent Claim 118 words
A foraminate element for the recovery of platinum and/or rhodium lost from a platinum-containing catalyst; said element being fabricated from a material consisting essentially of palladium and nickel characterized by (a) a novel configuration whereby the initial product of mesh size (N) and wire diameter (d w ) for said element is greater than at least about 0.2 and (b) where, for a given nitrogen throughput, the weight recovery efficiency (η') is a function of the wire diameter (d w ) and mesh size (N) combination and weight recovery efficiency is improved by increasing the mesh size (N) for a given wire diameter (d w ) or increasing wire diameter (d w ) for a given mesh size.
Claim 11
Dependent Claim 23 words
The element of claim 8 wherein the initial value of Nd w is in the range of from about 0.2 to about 0.9.
Claim 12
Dependent Claim 12 words
The element of clam 8 in the form of a woven gauze.
Claim 13
Dependent Claim 12 words
The element of clam 8 in the form of a woven gauze.
Claim 14
Dependent Claim 20 words
The element of claim 8 consisting essentially of from at least about 80% palladium by weight and the balance nickel.
Claim 15
Dependent Claim 47 words
The element of claim 8 wherein N is in the range of from about 10-80, d w is in the range of from about 0.003 to 0.090 and their respective values are such that the initial product of N×d w is greater than at least about 0.2.
Claim 16
Dependent Claim 22 words
The element of claim 12 wherein the initial product of N×d w is in the range of from about 0.2 to 0.9.
Claim 17
Dependent Claim 146 words
In the method for the recovery of platinum and/or rhodium lost from a platinum-containing catalyst during ammonia oxidation processes at temperatures above 850° C. by bringing said lost platinum and/or rhodium into contact with a foraminate element; the improvement which comprises utilizing for recovery purposes a foraminate element fabricated from a material consisting essentially of palladium and nickel, characterized by (a) a novel configuration whereby the initial product of mesh size (N) and wire diameter (d w ) for said element is greater that at least about 0.2 and (b) where, for a given nitrogen throughput, the weight recovery efficiency (η') is a function of the wire diameter (d w ) and mesh size (N) combination and weight recovery efficiency is improved by increasing the mesh size (N) at a given wire diameter or increasing the wire diameter (d w ) for a given mesh size.
Claim 18
Dependent Claim 146 words
In the method for the recovery of platinum and/or rhodium lost from a platinum-containing catalyst during ammonia oxidation processes at temperatures above 850° C. by bringing said lost platinum and/or rhodium into contact with a foraminate element; the improvement which comprises utilizing for recovery purposes a foraminate element fabricated from a material consisting essentially of palladium and nickel, characterized by (a) a novel configuration whereby the initial product of mesh size (N) and wire diameter (d w ) for said element is greater that at least about 0.2 and (b) where, for a given nitrogen throughput, the weight recovery efficiency (η') is a function of the wire diameter (d w ) and mesh size (N) combination and weight recovery efficiency is improved by increasing the mesh size (N) at a given wire diameter or increasing the wire diameter (d w ) for a given mesh size.
Claim 19
Dependent Claim 20 words
The method according to claim 14 wherein the initial value of Nd w is from about 0.2 to about 0.9.
Claim 20
Dependent Claim 13 words
The method according to claim 14 wherein said element is a woven gauze.
Claim 21
Dependent Claim 21 words
The method according to claim 14 wherein one or more of said elements are sandwiched between a plurality of separator screens.
Claim 22
Dependent Claim 23 words
The method according to claim 14 wherein said element is comprised of at least about 80% palladium by weight and the balance nickel.
Claim 23
Dependent Claim 48 words
The method according to claim 14 wherein N is in the range of from about 10-80, d w is in the range of from about 0.003 to 0.090 and their respective values are such that the initial product of N×d w is greater than at least about 0.2.
Claim 24
Dependent Claim 23 words
The method according to claim 14 wherein the initial product of N×d w is in the range of from about 0.2 to 0.9.

References Cited (Backward Citations)

US2648393A Cited
US2730189A Cited
US2747679A Cited
GB1082105A Cited
US3434826A Cited
US4239833A Cited
GB2050189A Cited
US4412859A Cited

USPTO Annuity & Maintenance Windows

Annuity Stage Window Opens Payment Deadline Surcharge Period Until Estimated Fee Status
3.5 Years (Year 4) 1988-02-05 1988-08-06 1989-02-05 $2000.00 Window Closed / Lapsed
7.5 Years (Year 8) 1992-02-05 1992-08-06 1993-02-05 $3760.00 Window Closed / Lapsed
11.5 Years (Year 12) 1996-02-05 1996-08-06 1997-02-05 $7700.00 Window Closed / Lapsed

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