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US4412859A Expired / Lapsed US ⏱️ 0.0 years remaining

Method for recovering platinum in a nitric acid plant

Assignee: BASF Catalysts LLC
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Filing: 1982-08-02
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Granted: 1983-11-01
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Expires: 2002-08-02
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Abstract

Abstract Improved recovery of platinum lost from the catalyst gauze in a nitric acid plant is obtained by using palladium containing recovery gauzes configured to enhance the mass transfer characteristics of the system.

Inventors

  • 👤 W. Robert Hatfield
  • 👤 Ronald M. Heck
  • 👤 Thomas H. Hsiung

Bibliographic Details

Application Number —
Jurisdiction US
Data Source google_patents
Last Synchronized 2026-10-27 22:18
CPC Classifications
C; C22; C22B; C22B11/00; C22B11/02; C22B11/021; C22B11/026; C22B11/028; C22B7/00; C22B7/009; Y; Y02; Y02P; Y02P10/00; Y02P10/20; Y10; Y10T; Y10T428/00; Y10T428/12; Y10T428/12014; Y10T428/1216; Y10T428/1234

Claims Analysis

Total Claims: 18
Claim 1
Independent Claim 131 words
A method for the recovery of platinum and/or rhodium lost from a platinum-containing catalyst during ammonia oxidation processes at temperatures above 850° C.; which comprises bringing said lost platinum and/or rhodium into contact with a foraminate element fabricated from material consisting essentially of palladium characterized by (a) a novel configuration whereby the initial product of mesh size (N) and wire diameter (d w ) for said element is greater than at least about 0.3 and (b) where, for a given nitrogen throughput, the weight recovery efficiency (η') is a function of the wire diameter (d w ) and mesh size (N) combination and weight recovery efficiency is improved by increasing mesh size (N) for a given wire diameter or increasing the wire diameter (d w ) for a given mesh size.
Claim 2
Independent Claim 131 words
A method for the recovery of platinum and/or rhodium lost from a platinum-containing catalyst during ammonia oxidation processes at temperatures above 850° C.; which comprises bringing said lost platinum and/or rhodium into contact with a foraminate element fabricated from material consisting essentially of palladium characterized by (a) a novel configuration whereby the initial product of mesh size (N) and wire diameter (d w ) for said element is greater than at least about 0.3 and (b) where, for a given nitrogen throughput, the weight recovery efficiency (η') is a function of the wire diameter (d w ) and mesh size (N) combination and weight recovery efficiency is improved by increasing mesh size (N) for a given wire diameter or increasing the wire diameter (d w ) for a given mesh size.
Claim 3
Dependent Claim 26 words
The method according to claim 1 wherein the initial product of N and d w is in the range of from about 0.3 to about 0.9.
Claim 4
Dependent Claim 13 words
The method according to claim 1 wherein said element is a woven gauze.
Claim 5
Dependent Claim 20 words
The method according to claim 1 wherein one or more of said elements are sandwiched between a plurality of screens.
Claim 6
Dependent Claim 33 words
The method according to claim 1 wherein said element consists essentially of palladium alloyed with one or more metals selected from the group consisting of cobalt, platinum, ruthenium, iridium, gold, silver and copper.
Claim 7
Dependent Claim 29 words
The method according to claim 5 wherein the element consists essentially of palladium and gold, said palladium being present in an amount of at least about 80% by weight.
Claim 8
Dependent Claim 48 words
The method according to claim 1 wherein N is in the range of from about 50-80, d w is in the range of from about 0.003 to 0.018 and their respective values are such that the initial product of N×d w is greater than at least about 0.3.
Claim 9
Dependent Claim 21 words
The method according to claim 1 wherein the initial product of N×d w is in the range of from about 0.35-0.9.
Claim 10
Dependent Claim 145 words
In the method for the recovery of platinum and/or rhodium lost from a platinum-containing catalyst during ammonia oxidation processes at temperatures above 850° C. by bringing said lost platinum and /or rhodium into contact with a foraminate element; the imrovement which comprises utilizing for recovery purposes a foraminate element fabricated from a material consisting essentially of palladium, characterized by (a) a novel configuration whereby the initial product of mesh size (N) and wire diameter (d w ) for said element is greater than at least about 0.3 and (b) where, for a given nitrogen throughput, the weight recovery efficiency (η') is a function of the wire diameter (d w ) and mesh size (N) combination and weight recovery efficiency is improved by increasing the mesh size (N) at a given wire diameter or increasing the wire diameter (d w ) at a given mesh size.
Claim 11
Dependent Claim 145 words
In the method for the recovery of platinum and/or rhodium lost from a platinum-containing catalyst during ammonia oxidation processes at temperatures above 850° C. by bringing said lost platinum and /or rhodium into contact with a foraminate element; the imrovement which comprises utilizing for recovery purposes a foraminate element fabricated from a material consisting essentially of palladium, characterized by (a) a novel configuration whereby the initial product of mesh size (N) and wire diameter (d w ) for said element is greater than at least about 0.3 and (b) where, for a given nitrogen throughput, the weight recovery efficiency (η') is a function of the wire diameter (d w ) and mesh size (N) combination and weight recovery efficiency is improved by increasing the mesh size (N) at a given wire diameter or increasing the wire diameter (d w ) at a given mesh size.
Claim 12
Dependent Claim 23 words
The method according to claim 9 in which the initial product of N and d w is from about 0.30 to about 0.90.
Claim 13
Dependent Claim 13 words
The method according to claim 9 wherein said element is a woven gauze.
Claim 14
Dependent Claim 21 words
The method according to claim 9 wherein one or more of said elements are sandwiched between a plurality of separator screens.
Claim 15
Dependent Claim 33 words
The method according to claim 9 wherein said element consists essentially of palladium alloyed with one or more metals selected from the group consisting of platinum, cobalt, ruthenium, iridium, gold, silver and copper.
Claim 16
Dependent Claim 19 words
The method according to claim 13 wherein said element consists essentially of palladium and at least about 19.5% gold.
Claim 17
Dependent Claim 48 words
The method according to claim 9 wherein N is in the range of from about 50-80, d w is in the range of from about 0.003 to 0.018, and their respective values are such that the initial product of N×d w is greater than at least about 0.3.
Claim 18
Dependent Claim 23 words
The method according to claim 9 wherien the initial product of N×d w is in the range of from about 0.35 to 0.9.

USPTO Annuity & Maintenance Windows

Annuity Stage Window Opens Payment Deadline Surcharge Period Until Estimated Fee Status
3.5 Years (Year 4) 1986-10-31 1987-05-02 1987-11-01 $2000.00 Window Closed / Lapsed
7.5 Years (Year 8) 1990-10-31 1991-05-02 1991-11-01 $3760.00 Window Closed / Lapsed
11.5 Years (Year 12) 1994-10-31 1995-05-02 1995-11-01 $7700.00 Window Closed / Lapsed

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