US4412859A
Expired / Lapsed
US
⏱️ 0.0 years remaining
Method for recovering platinum in a nitric acid plant
Assignee: BASF Catalysts LLC
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Filing: 1982-08-02
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Granted: 1983-11-01
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Expires: 2002-08-02
Abstract
Abstract Improved recovery of platinum lost from the catalyst gauze in a nitric acid plant is obtained by using palladium containing recovery gauzes configured to enhance the mass transfer characteristics of the system.
Inventors
- 👤 W. Robert Hatfield
- 👤 Ronald M. Heck
- 👤 Thomas H. Hsiung
Bibliographic Details
Application Number
—
Jurisdiction
US
Data Source
google_patents
Last Synchronized
2026-10-27 22:18
CPC Classifications
C; C22; C22B; C22B11/00; C22B11/02; C22B11/021; C22B11/026; C22B11/028; C22B7/00; C22B7/009; Y; Y02; Y02P; Y02P10/00; Y02P10/20; Y10; Y10T; Y10T428/00; Y10T428/12; Y10T428/12014; Y10T428/1216; Y10T428/1234
Claims Analysis
Total Claims: 18
Claim 1
Independent Claim
131 words
A method for the recovery of platinum and/or rhodium lost from a platinum-containing catalyst during ammonia oxidation processes at temperatures above 850° C.; which comprises bringing said lost platinum and/or rhodium into contact with a foraminate element fabricated from material consisting essentially of palladium characterized by (a) a novel configuration whereby the initial product of mesh size (N) and wire diameter (d w ) for said element is greater than at least about 0.3 and (b) where, for a given nitrogen throughput, the weight recovery efficiency (η') is a function of the wire diameter (d w ) and mesh size (N) combination and weight recovery efficiency is improved by increasing mesh size (N) for a given wire diameter or increasing the wire diameter (d w ) for a given mesh size.
Claim 2
Independent Claim
131 words
A method for the recovery of platinum and/or rhodium lost from a platinum-containing catalyst during ammonia oxidation processes at temperatures above 850° C.; which comprises bringing said lost platinum and/or rhodium into contact with a foraminate element fabricated from material consisting essentially of palladium characterized by (a) a novel configuration whereby the initial product of mesh size (N) and wire diameter (d w ) for said element is greater than at least about 0.3 and (b) where, for a given nitrogen throughput, the weight recovery efficiency (η') is a function of the wire diameter (d w ) and mesh size (N) combination and weight recovery efficiency is improved by increasing mesh size (N) for a given wire diameter or increasing the wire diameter (d w ) for a given mesh size.
Claim 3
Dependent Claim
26 words
The method according to claim 1 wherein the initial product of N and d w is in the range of from about 0.3 to about 0.9.
Claim 4
Dependent Claim
13 words
The method according to claim 1 wherein said element is a woven gauze.
Claim 5
Dependent Claim
20 words
The method according to claim 1 wherein one or more of said elements are sandwiched between a plurality of screens.
Claim 6
Dependent Claim
33 words
The method according to claim 1 wherein said element consists essentially of palladium alloyed with one or more metals selected from the group consisting of cobalt, platinum, ruthenium, iridium, gold, silver and copper.
Claim 7
Dependent Claim
29 words
The method according to claim 5 wherein the element consists essentially of palladium and gold, said palladium being present in an amount of at least about 80% by weight.
Claim 8
Dependent Claim
48 words
The method according to claim 1 wherein N is in the range of from about 50-80, d w is in the range of from about 0.003 to 0.018 and their respective values are such that the initial product of N×d w is greater than at least about 0.3.
Claim 9
Dependent Claim
21 words
The method according to claim 1 wherein the initial product of N×d w is in the range of from about 0.35-0.9.
Claim 10
Dependent Claim
145 words
In the method for the recovery of platinum and/or rhodium lost from a platinum-containing catalyst during ammonia oxidation processes at temperatures above 850° C. by bringing said lost platinum and /or rhodium into contact with a foraminate element; the imrovement which comprises utilizing for recovery purposes a foraminate element fabricated from a material consisting essentially of palladium, characterized by (a) a novel configuration whereby the initial product of mesh size (N) and wire diameter (d w ) for said element is greater than at least about 0.3 and (b) where, for a given nitrogen throughput, the weight recovery efficiency (η') is a function of the wire diameter (d w ) and mesh size (N) combination and weight recovery efficiency is improved by increasing the mesh size (N) at a given wire diameter or increasing the wire diameter (d w ) at a given mesh size.
Claim 11
Dependent Claim
145 words
In the method for the recovery of platinum and/or rhodium lost from a platinum-containing catalyst during ammonia oxidation processes at temperatures above 850° C. by bringing said lost platinum and /or rhodium into contact with a foraminate element; the imrovement which comprises utilizing for recovery purposes a foraminate element fabricated from a material consisting essentially of palladium, characterized by (a) a novel configuration whereby the initial product of mesh size (N) and wire diameter (d w ) for said element is greater than at least about 0.3 and (b) where, for a given nitrogen throughput, the weight recovery efficiency (η') is a function of the wire diameter (d w ) and mesh size (N) combination and weight recovery efficiency is improved by increasing the mesh size (N) at a given wire diameter or increasing the wire diameter (d w ) at a given mesh size.
Claim 12
Dependent Claim
23 words
The method according to claim 9 in which the initial product of N and d w is from about 0.30 to about 0.90.
Claim 13
Dependent Claim
13 words
The method according to claim 9 wherein said element is a woven gauze.
Claim 14
Dependent Claim
21 words
The method according to claim 9 wherein one or more of said elements are sandwiched between a plurality of separator screens.
Claim 15
Dependent Claim
33 words
The method according to claim 9 wherein said element consists essentially of palladium alloyed with one or more metals selected from the group consisting of platinum, cobalt, ruthenium, iridium, gold, silver and copper.
Claim 16
Dependent Claim
19 words
The method according to claim 13 wherein said element consists essentially of palladium and at least about 19.5% gold.
Claim 17
Dependent Claim
48 words
The method according to claim 9 wherein N is in the range of from about 50-80, d w is in the range of from about 0.003 to 0.018, and their respective values are such that the initial product of N×d w is greater than at least about 0.3.
Claim 18
Dependent Claim
23 words
The method according to claim 9 wherien the initial product of N×d w is in the range of from about 0.35 to 0.9.
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USPTO Annuity & Maintenance Windows
| Annuity Stage | Window Opens | Payment Deadline | Surcharge Period Until | Estimated Fee | Status |
|---|---|---|---|---|---|
| 3.5 Years (Year 4) | 1986-10-31 | 1987-05-02 | 1987-11-01 | $2000.00 | Window Closed / Lapsed |
| 7.5 Years (Year 8) | 1990-10-31 | 1991-05-02 | 1991-11-01 | $3760.00 | Window Closed / Lapsed |
| 11.5 Years (Year 12) | 1994-10-31 | 1995-05-02 | 1995-11-01 | $7700.00 | Window Closed / Lapsed |