US4496686A
Expired / Lapsed
US
⏱️ 0.0 years remaining
Radiation-curable coatings containing reactive pigment dispersants
Assignee: Covestro Resins BV
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Filing: 1984-05-07
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Granted: 1985-01-29
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Expires: 2004-05-07
Abstract
Abstract Liquid coating compositions adapted to be cured by exposure to penetrating radiation are disclosed in which a liquid vehicle of coating viscosity having an ethylenically unsaturated portion comprising one or more polyethylenically unsaturated materials adapted to cure on radiation exposure, pigment dispersed in the vehicle, and an ethylenically unsaturated radiation-curable dispersant containing a carboxyl group for wetting the pigment and assisting in the stable dipsersion of the pigment in the vehicle. This dispersant is a half amide or half ester of an ethylenically unsaturated polycarboxylic acid anhydride, such as maleic anhydride, with an organic compound having a molecular weight of from 100 to 4000 and which contains a single hydroxy group or a single amino group as the sole reactive group thereof.
Inventors
- 👤 Robert E. Ansel
Bibliographic Details
Application Number
—
Jurisdiction
US
Data Source
google_patents
Last Synchronized
2026-10-28 21:26
CPC Classifications
C; C08; C08G; C08G18/00; C08G18/06; C08G18/28; C08G18/40; C08G18/42; C08G18/44; C08F; C08F299/00; C08F299/02; C08F299/022; C08F299/024; C08F299/06; C08F299/065; C08G18/67; C08G18/671; C08G18/672; G; G11; G11B; G11B5/00; G11B5/62; G11B5/68; G11B5/70; G11B5/702; G11B5/7026
Claims Analysis
Total Claims: 13
Claim 1
Independent Claim
116 words
A liquid coating composition adapted to be cured by exposure to ionizing radiation comprising, a liquid vehicle of coating viscosity having an ethylenically unsaturated portion comprising one or more polyethylenically unsaturated materials adapted to cure on radiation exposure, pigment dispersed in said vehicle, and an ethylenically unsaturated radiation-curable dispersant containing a carboxy group for wetting said pigment and assisting in the stable dispersion of said pigment in said vehicle, said dispersant being a half amide or half ester of an ethylenically unsaturated polycarboxylic acid anhydride with an organic compound having a molecular weight of from 100 to 4000 and which contains a single hydroxy group or a single amino group as the sole reactive group thereof.
Claim 2
Dependent Claim
116 words
A liquid coating composition adapted to be cured by exposure to ionizing radiation comprising, a liquid vehicle of coating viscosity having an ethylenically unsaturated portion comprising one or more polyethylenically unsaturated materials adapted to cure on radiation exposure, pigment dispersed in said vehicle, and an ethylenically unsaturated radiation-curable dispersant containing a carboxy group for wetting said pigment and assisting in the stable dispersion of said pigment in said vehicle, said dispersant being a half amide or half ester of an ethylenically unsaturated polycarboxylic acid anhydride with an organic compound having a molecular weight of from 100 to 4000 and which contains a single hydroxy group or a single amino group as the sole reactive group thereof.
Claim 3
Dependent Claim
25 words
A liquid coating composition as recited in claim 1 in which said polyethylenically unsaturated material comprises a polyether, and said organic compound is a polyether.
Claim 4
Dependent Claim
20 words
A liquid coating composition as recited in claim 1 in which said ethylenically unsaturated polycarboxylic acid anhydride is maleic anhydride.
Claim 5
Dependent Claim
34 words
A liquid coating composition as recited in claim 1 in which said polyethylenically unsaturated material comprise oligomers having a molecular weight of from 500 to 20,000 and providing from 2-10 hydroxy groups per molecule.
Claim 6
Dependent Claim
25 words
A liquid coating composition as recited in claim 4 in which said oligomers comprise polyether groups held together by from 4-20 urethane groups per molecule.
Claim 7
Dependent Claim
18 words
A liquid coating composition as recited in claim 4 in which said oligomers comprise hydroxy-functional diethylenically unsaturated polyurethanes.
Claim 8
Dependent Claim
29 words
A liquid coating composition as recited in claim 1 in which said polyethylenically unsaturated material comprise polyacrylates and polymethacrylates of polyhydric alcohols having from 2-4 hydroxy groups per molecule.
Claim 9
Dependent Claim
30 words
A liquid coating composition as recited in claim 1 in which at least 30% of the ethylenically unsaturated portion of the coating composition is constituted by said polyethylenically unsaturated material.
Claim 10
Dependent Claim
39 words
A liquid coating composition as recited in claim 8 in which the viscosity of the coating composition is reduced by having of at least 10% of the ethylenically unsaturated portion of the coating composition constituted by monoethylenically unsaturated liquid.
Claim 11
Dependent Claim
49 words
A liquid coating composition as recited in claim 1 containing pigment in a pigment to binder weight ratio in excess of 1:1 and inert volatile organic solvent in an amount to reduce the total solids content of the pigmented coating composition to the range of from 25% to 60%.
Claim 12
Dependent Claim
49 words
A liquid coating composition as recited in claim 9 containing pigment in a pigment to binder weight ratio in excess of 1:1 and inert volatile organic solvent in an amount to reduce the total solids content of the pigmented coating composition to the range of from 25% to 60%.
Claim 13
Dependent Claim
30 words
A liquid coating composition as recited in claim 1 containing pigment in a pigment to binder weight ratio in excess of 0.5:1 and from 0.25% to 7% of said dispersant.
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USPTO Annuity & Maintenance Windows
| Annuity Stage | Window Opens | Payment Deadline | Surcharge Period Until | Estimated Fee | Status |
|---|---|---|---|---|---|
| 3.5 Years (Year 4) | 1988-01-29 | 1988-07-30 | 1989-01-29 | $2000.00 | Window Closed / Lapsed |
| 7.5 Years (Year 8) | 1992-01-29 | 1992-07-30 | 1993-01-29 | $3760.00 | Window Closed / Lapsed |
| 11.5 Years (Year 12) | 1996-01-29 | 1996-07-30 | 1997-01-29 | $7700.00 | Window Closed / Lapsed |