US4342840A
Expired / Lapsed
US
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Process for producing polymer polyol
Assignee: AGC Inc
•
Filing: 1980-12-08
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Granted: 1982-08-03
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Expires: 2000-12-08
Abstract
Abstract A polymer polyol is produced by polymerizing a monomer having a polymerizable unsaturated group in a nitrogen bond-containing unsaturated polyol or polyol mixture having at least two nitrogen-containing bonds formed by reacting isocyanate groups with active hydrogen groups, at least one polymerizable unsaturated group and at least 1.7 hydroxyl groups, as average. A polymer polyol is produced by polymerizing a monomer having a polymerizable unsaturated group in a nitrogen bond-containing unsaturated polyol or polyol mixture having at least 1.7 hydroxyl groups as average obtained by reacting a polyisocyanate with a mixture of a substantially saturated polyol having at least two hydroxyl groups and an unsaturated active hydrogen compound having at least one active hydrogen group and at least one polymerizable unsaturated group or by reacting said polyisocyanate with either of said substantially saturated polyol or said unsaturated active hydrogen compound and then reacting the remainder with the intermediate; or a polyol mixture obtained by diluting said nitrogen bond-containing unsaturated polyol or polyol mixture with a substantially saturated polyol.
Inventors
- 👤 Shigeyuki Kozawa
- 👤 Takao Doi
- 👤 Nobuaki Kunii
Bibliographic Details
Application Number
—
Jurisdiction
US
Data Source
google_patents
Last Synchronized
2026-10-29 02:54
CPC Classifications
C; C08; C08G; C08G18/00; C08G18/06; C08G18/28; C08G18/67; C08G18/675; C08G18/40; C08G18/63; C08G18/635
Claims Analysis
Total Claims: 27
Claim 1
Independent Claim
62 words
A process for producing a polymer polyol which comprises polymerizing a monomer having a polymerizable unsaturated group in a nitrogen bond-containing unsaturated polyol or polyol mixture and said nitrogen bond-containing unsaturated polyol having at least two nitrogen-containing bonds formed by reacting organic isocyanate groups with active hydrogen groups, at least one polymerizable unsaturated group and at least 1.7 hydroxyl groups, as average.
Claim 2
Dependent Claim
62 words
A process for producing a polymer polyol which comprises polymerizing a monomer having a polymerizable unsaturated group in a nitrogen bond-containing unsaturated polyol or polyol mixture and said nitrogen bond-containing unsaturated polyol having at least two nitrogen-containing bonds formed by reacting organic isocyanate groups with active hydrogen groups, at least one polymerizable unsaturated group and at least 1.7 hydroxyl groups, as average.
Claim 3
Dependent Claim
41 words
The process according to claim 1 wherein said polyol mixture including said unsaturated polyol has at least 0.2 nitrogen-containing bonds and at least 0.1 polymerizable unsaturated groups and at least 1.7 hydroxyl groups as average per 1 molecule of said polyol.
Claim 4
Dependent Claim
52 words
The process according to claim 1 wherein said unsaturated polyol is obtained by reacting a substantially saturated polyol having at least two hydroxyl groups, an unsaturated active hydrogen compound having at least one active hydrogen group and at least one polymerizable unsaturated group and a polyisocyanate having at least two isocyanate groups.
Claim 5
Dependent Claim
46 words
The process according to claim 3 wherein said unsaturated polyol is obtained by reacting all of the isocyanate groups of said polyisocyanate with at least one hydroxy group of said substantially saturated polyol and at least one active hydrogen group of said unsaturated active hydrogen compound.
Claim 6
Dependent Claim
17 words
The process according to claim 3 or 4 wherein said substantially saturated polyol is a polyether polyol.
Claim 7
Dependent Claim
19 words
The process according to claim 3 or 4 wherein said unsaturated active hydrogen compound is an unsaturated polyhydroxy compound.
Claim 8
Dependent Claim
19 words
The process according to claim 3 or 4 wherein said unsaturated active hydrogen compound is an unsaturated monohydroxy compound.
Claim 9
Dependent Claim
15 words
The process according to claim 3 or 4 wherein said polyisocyanate is an aromatic polyisocyanate.
Claim 10
Dependent Claim
13 words
The process according to claim 1 wherein said monomer is a vinyl monomer.
Claim 11
Dependent Claim
22 words
The process according to claim 9 wherein said vinyl monomer is selected from the group consisting of acrylonitrile, styrene and mixtures thereof.
Claim 12
Dependent Claim
17 words
A polyurethane made of a polyisocyanate with a polymer polyol obtained by the process of claim 1.
Claim 13
Dependent Claim
27 words
The polyurethane according to claim 11 which is a polyurethane foam obtained by reacting said polyisocyanate with said polymer polyol in the presence of a blowing agent.
Claim 14
Dependent Claim
123 words
A process for producing a polymer polyol which comprises polymerizing a monomer having a polymerizable unsaturated group in a nitrogen bond-containing unsaturated polyol or polyol mixture having at least 1.7 hydroxyl groups as average obtained by reacting an organic polyisocyanate with a mixture of a substantially saturated polyol having at least 2 hydroxyl groups and an unsaturated active hydrogen compound having at least one active hydrogen group and and at least one polymerizable unsaturated group or by reacting said polyisocyanate with either of said substantially saturated polyol or said unsaturated active hydrogen compound to form an intermediate, and then reacting the remainder with the intermediate; or a polyol mixture obtained by diluting said unsaturated polyol or polyol mixture with a substantially saturated polyol.
Claim 15
Dependent Claim
123 words
A process for producing a polymer polyol which comprises polymerizing a monomer having a polymerizable unsaturated group in a nitrogen bond-containing unsaturated polyol or polyol mixture having at least 1.7 hydroxyl groups as average obtained by reacting an organic polyisocyanate with a mixture of a substantially saturated polyol having at least 2 hydroxyl groups and an unsaturated active hydrogen compound having at least one active hydrogen group and and at least one polymerizable unsaturated group or by reacting said polyisocyanate with either of said substantially saturated polyol or said unsaturated active hydrogen compound to form an intermediate, and then reacting the remainder with the intermediate; or a polyol mixture obtained by diluting said unsaturated polyol or polyol mixture with a substantially saturated polyol.
Claim 16
Dependent Claim
62 words
The process according to claim 13 wherein 1 mol of said substantially saturated polyol and 0.1 to 4 moles of said unsaturated active hydrogen compound and 0.1 to 4 moles of said polyisocyanate at a molar ratio of more than 1 of said polyisocyanate to said unsaturated active hydrogen compound are used in the production of said unsaturated polyol or polyol mixture.
Claim 17
Dependent Claim
62 words
The process according to claim 14 wherein 1 mol of said substantially saturated polyol and 0.2 to 2 moles of said unsaturated active hydrogen compound and 0.1 to 2 moles of said polyisocyanate at a molar ratio of said polyisocyanate to said unsaturated active hydrogen compound of 1 to 2 are used in the production of said unsaturated polyol or polyol mixture.
Claim 18
Dependent Claim
32 words
The process according to claim 13 wherein the viscosity of said unsaturated polyol or polyol mixture having at least 1.7 hydroxyl groups as average is less than 20,000 cp at 25° C.
Claim 19
Dependent Claim
15 words
The process according to claim 13 wherein said substantially saturated polyol is a polyether polyol.
Claim 20
Dependent Claim
17 words
The process according to claim 13 wherein said unsaturated active hydrogen compound is an unsaturated polyhydroxy compound.
Claim 21
Dependent Claim
17 words
The process according to claim 13 wherein said unsaturated active hydrogen compound is an unsaturated monohydroxy compound.
Claim 22
Dependent Claim
25 words
The process according to claim 13 wherein said unsaturated active hydrogen compound is a mixture of an unsaturated polyhydroxy compound and an unsaturated monohydroxy compound.
Claim 23
Dependent Claim
13 words
The process according to claim 13 wherein said polyisocyanate is an aromatic polyisocyanate.
Claim 24
Dependent Claim
13 words
The process according to claim 13 wherein said monomer is a vinyl monomer.
Claim 25
Dependent Claim
22 words
The process according to claim 22 wherein said vinyl monomer is selected from the group consisting of acrylonitrile, styrene and mixtures thereof.
Claim 26
Dependent Claim
17 words
A polyurethane made of a polyisocyanate with a polymer polyol obtained by the process of claim 13.
Claim 27
Dependent Claim
27 words
The polyurethane according to claim 24 which is a polyurethane foam obtained by reacting said polyisocyanate with said polymer polyol in the presence of a blowing agent.
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USPTO Annuity & Maintenance Windows
| Annuity Stage | Window Opens | Payment Deadline | Surcharge Period Until | Estimated Fee | Status |
|---|---|---|---|---|---|
| 3.5 Years (Year 4) | 1985-08-02 | 1986-02-01 | 1986-08-03 | $2000.00 | Window Closed / Lapsed |
| 7.5 Years (Year 8) | 1989-08-02 | 1990-02-01 | 1990-08-03 | $3760.00 | Window Closed / Lapsed |
| 11.5 Years (Year 12) | 1993-08-02 | 1994-02-01 | 1994-08-03 | $7700.00 | Window Closed / Lapsed |