Alkoxylated aromatic amine-aromatic polyester polyol blend and polyisocyanurate foam therefrom

Claim 2

A laminate comprising at least one facing sheet adhered to a polyisocyanurate foam which comprises the reaction product of an organic polyisocyanate, a blowing agent, a trimerization catalyst, and a minor amount of a polyol blend comprising (a) about 5 percent to about 95 percent by weight of said blend of an alkylene oxide adduct of an aromatic amine of the formula ##STR7## wherein Z is a divalent aromatic radical, x, x', y, and y' each independently have an average value from about 1 to about 5, and each R is independently selected from the group consisting of hydrogen, alkyl or aryl, provided that the adduct is capped with ethylene oxide units, and (b) about 5 percent to about 95 percent by weight of said blend of an aromatic polyester polyol material having a molecular weight of from about 150 to about 5,000.

Claim 3

The laminate of claim 1 wherein said polyisocyanurate foam is reinforced by glass fibers.

Claim 4

The laminate of claim 1 wherein said facing sheet is a member selected from the group consisting of an asphalt fiber glass facer, an asphalt-saturated roofing felt, perlite board, aluminum foil and fiberboard.

Claim 5

The laminate of claim 1 wherein said organic polyisocyanate is a polymethylene polyphenylisocyanate.

Claim 6

The laminate of claim 4 wherein said alkylene oxide adduct of an aromatic amine is an ethylene oxide adduct of toluene diamine isomers of the formula ##STR8## wherein the average number of oxyethylene units per polyoxyethylene chain is from 2 to 3.

Claim 7

The laminate of claim 1 wherein said organic polyisocyanate is a mixture of components of the formula ##STR9## wherein n is an integer from 0 to 8 inclusive, and said mixture has: (a) a functionality of 2.1 to 3.2, (b) an equivalent weight between 120 and 180, and (c) a viscosity at 25° C. between 150 and 2500 centipoises.

Claim 8

The laminate of claim 1 wherein said aromatic polyester polyol material is a polyol mixture prepared by the transesterification, with a glycol of molecular weight from about 60 to 400, of a by-product fraction from the manufacture of dimethyl terephthalate, the major portion of said fraction comprising about 15 to 70 weight percent of dimethyl terephthalate, and about 85 to 30 weight percent of a mixture of monomethyl terephthalate, bi-ring esters and polymeric materials.

Claim 9

The laminate of claim 7 wherein said by-product fraction from the manufacture of dimethyl terephthalate comprises a mixture of (a) about 40 to 60 percent by weight of dimethyl terephthalate, (b) about 1 to 10 percent by weight of monomethyl terephthalate, (c) about 1 to 2 percent by weight of terephthalic acid, (d) about 10 to 25 percent by weight of bi-ring esters, (e) about 5 to 12 percent by weight of organic acid salts, (f) about 18 to 25 percent by weight of polymeric materials, and (g) about 1 to 4 percent by weight of ash.

Claim 10

The laminate of claim 1 wherein said aromatic polyester polyol material is a polyol mixture prepared by the transesterification, with a glycol of molecular weight from about 60 to about 400, of a residue remaining after dimethyl terephthalate and methyl p-toluate have been removed from a dimethyl terephthalate esterified oxidate reaction product, the major portion of said residue comprising a mixture of methyl and benzyl esters of benzene and biphenyl di- and tricarboxylic acids.

Claim 11

The laminate of claim 1 wherein said organic polyisocyanate is a polymethylene polyphenylisocyanate, and said aromatic polyester polyol material is a member selected from the group consisting of (a) a polyol mixture prepared by the transesterification, with a glycol of molecular weight from about 60 to 400, of a by-product fraction from the manufacture of dimethyl terephthalate, the major portion of said fraction comprising about 15 to 70 weight percent of dimethyl terephthlate, and about 85 to 30 weight percent of a mixture of monomethyl terephthalate, bi-ring esters and polymeric materials, (b) a polyol mixture prepared by the transesterification, with a glycol of molecular weight from about 60 to about 400, of a residue remaining after dimethyl terephthalate and methyl p-toluate have been removed from a dimethyl terephthalate esterified oxidate reaction product, the major portion of said residue comprising a mixture of methyl and benzyl esters of benzene and biphenyl di- and tricarboxylic acids, and (c) mixtures thereof, the equivalent ratio of said organic polyisocyanate to said polyol blend being about 1.5:1 to 6:1, and the weight ratio of said alkylene oxide adduct of an aromatic amine to said aromatic polyester polyol material being about 1:9 to 1:1.

Claim 12

The laminate of claim 10 wherein said alkylene oxide adduct of an aromatic amine is an ethylene oxide adduct of toluene diamine isomers of the formula ##STR10## wherein the average number of oxyethylene units per polyoxyethylene chain is from 2 to 3.

Claim 13

The laminate of claim 10 wherein (1) said polyol mixture (a) is transesterified with diethylene glycol and is characterized by a viscosity in cps at 25° C. of about 700 to 2500, a free diethylene glycol content of from about 10 to 30 percent by weight of said mixture, a hydroxyl number within a range of from about 350 to 468, and an acid number of about 0.2 to 10, and (2) said polyol mixture (b) is transesterified with diethylene glycol and is characterized by a viscosity in cps at 25° C. of about 1,600 to about 2,800, a free diethylene glycol content of from about 20 to about 30 percent by weight of said mixture, a hydroxyl number within a range of from about 400 to about 490, and an acid number of about 0.2 to about 8.

Claim 14

The laminate of claim 12 wherein said alkylene oxide adduct of an aromatic amine of the blend is an ethylene oxide adduct of toluene diamine isomers of the formula ##STR11## wherein the average number of oxyethylene units per polyoxyethylene chain is from 2 to 3.

Claim 15

The laminate of claim 13 wherein the weight ratio of said alkylene oxide adduct of an aromatic amine to said aromatic polyester polyol material is about 1:4 to 1:1.5.

Claim 16

The laminate of claim 14 wherein said blowing agent is a fluorocarbon and said trimerization catalyst comprises a mixture of a tertiary amino phenol and an alkali metal carboxylate.

Claim 17

The laminate of claim 15 wherein said trimerization catalyst comprises a mixture of 2,4,6-tris(dimethylaminomethyl) phenol and potassium-2-ethyl hexoate in an equivalent ratio of about 0.4:1 to 2.5:1.

Claim 18

The laminate of claim 14 wherein said facing sheet is a member selected from the group consisting of an asphalt fiber glass facer, an asphalt-saturated roofing felt, perlite board, aluminum foil and fiberboard.

Claim 19

The laminate of claim 14 wherein said blowing agent is a halohydrocarbon selected from the group consisting of chlorinated hydrocarbons, fluorinated hydrocarbons and mixtures thereof.

Claim 20

The laminate of claim 18 wherein said facing sheet is a member selected from the group consisting of an asphalt fiber glass facer, an asphalt-saturated roofing felt, perlite board, aluminum foil and fiberboard.

Claim 21

The laminate of claim 18 therein the weight ratio of said alkylene oxide adduct of an aromatic amine to said aromatic polyester polyol material is about 1:9 to 1:1.

Claim 22

The laminate of claim 20 wherein said trimerization catalyst comprises a mixture of a tertiary amino phenol and an alkali metal carboxylate.

Claim 23

The laminate of claim 21 wherein said facing sheet is a member selected from the group consisting of an asphalt fiber glass facer, an asphalt-saturated roofing felt, perlite board, aluminum foil and fiberboard.

Claim 24

The laminate of claim 22 wherein said trimerization catalyst comprises a mixture of 2,4,6-tris(dimethylaminomethyl) phenol and potassium-2-ethyl hexoate.

Claim 25

The laminate of claim 6 wherein said blowing agent is a halohydrocarbon selected from the group consisting of chlorinated hydrocarbons, fluorinated hydrocarbons and mixtures thereof.

Claim 26

The laminate of claim 24 wherein said facing sheet is a member selected from the group consisting of an asphalt fiber glass facer, an asphalt-saturated roofing felt, perlite board, aluminum foil and fiberboard.

Claim 27

The laminate of claim 25 wherein the weight ratio of said alkylene oxide adduct of an aromatic amine to said aromatic polyester polyol material is about 1:9 to 1:1, and said trimerization catalyst comprises a mixture of a tertiary amino phenol and an alkali metal carboxylate.

Claim 28

The laminate of claim 7 wherein said organic polyisocyanate is a polymethylene polyphenylisocyanate and said blowing agent is a halohydrocarbon selected from the group consisting of chlorinated hydrocarbons, fluorinated hydrocarbons and mixtures thereof.

Claim 29

The laminate of claim 27 wherein said facing sheet is a member selected from the group consisting of an asphalt fiber glass facer, an asphalt-saturated roofing felt, perlite board, aluminum foil and fiberboard.

Claim 30

The laminate of claim 28 wherein the weight ratio of said alkylene oxide adduct of an aromatic amine to said aromatic polyester polyol material is about 1:9 to 1:1, and said trimerization catalyst comprises a mixture of a tertiary amino phenol and an alkali metal carboxylate.

Claim 31

The laminate of claim 9 wherein said organic polyisocyanate is a polymethylene polyphenylisocyanate and said blowing agent is a halohydrocarbon selected from the group consisting of chlorinated hydrocarbons, fluorinated hydrocarbons and mixtures thereof.

Claim 32

The laminate of claim 30 wherein said facing sheet is a member selected from the group consisting of an asphalt fiber glass facer, an asphalt-saturated roofing felt, perlite board, aluminum foil and fiberboard.

Claim 33

The laminate of claim 31 wherein the weight ratio of said alkylene oxide adduct of an aromatic amine to said aromatic polyester polyol material is about 1:9 to 1:1, and said trimerization catalyst comprises a mixture of a tertiary amino phenol and an alkali metal carboxylate.

Claim 34

The laminate of claim 10 wherein said blowing agent is a halohydrocarbon selected from the group consisting of chlorinated hydrocarbons, fluorinated hydrocarbons and mixtures thereof, and said facing sheet is a member selected from the group consisting of an asphalt fiber glass facer, an asphalt-saturated roofing felt, perlite board, aluminum foil and fiberboard.

Claim 35

The laminate of claim 33 wherein said trimerization,catalyst comprises a mixture of a tertiary amino phenol and an alkali metal carboxylate.

Claim 36

The laminate of claim 11 wherein said blowing agent is a halohydrocarbon selected from the group consisting of chlorinated hydrocarbons, fluorinated hydrocarbons and mixtures thereof.

Claim 37

The laminate of claim 35 wherein said trimerization catalyst comprises a mixture of a tertiary amino phenol and an alkali metal carboxylate.

Claim 38

The laminate of claim 36 wherein said facing sheet is a member selected from the group consisting of an asphalt fiber glass facer, an asphalt-saturated roofing felt, perlite board, aluminum foil and fiberboard.

Claim 39

The laminate of claim 12 wherein said blowing agent is a halohydrocarbon selected from the group consisting of chlorinated hydrocarbons, fluorinated hydrocarbons and mixtures thereof.

Claim 40

The laminate of claim 38 wherein said trimerization catalyst comprises a mixture of a tertiary amino phenol and an alkali metal carboxylate.

Claim 41

The laminate of claim 39 wherein said facing sheet is a member selected from the group consisting of an asphalt fiber glass facer, an asphalt-saturated roofing felt, perlite board, aluminum foil and fiberboard.

Claim 42

The laminate of claim 13 wherein said blowing agent is a halohydrocarbon selected from the group consisting of chlorinated hydrocarbons, fluorinated hydrocarbons and mixtures thereof, and said facing sheet is a member selected from the group consisting of an asphalt fiber glass facer, an asphalt-saturated roofing felt, perlite board, aluminum foil and fiberboard.

Claim 43

The laminate of claim 41 wherein said trimerization catalyst comprises a mixture of a tertiary amino phenol and an alkali metal carboxylate.