US4495335A
Expired / Lapsed
US
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Self-crosslinking heat-curable binder
Assignee: BASF Farben und Fasern AG
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Filing: 1983-03-07
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Granted: 1985-01-22
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Expires: 2003-03-07
Abstract
Abstract The invention relates to a self-crosslinking heatcurable binder, in particular for electropaints, which is based on an organic synthetic resin which contains primary and/or secondary and, if desired, also tertiary amino groups and esterified carboxyl groups and is water-dilutable due to partial or complete neutralization with acids. The esterified carboxyl groups are activated in the alcohol component by a substituent which induces a negative inductive effect.
Inventors
- 👤 Michael Geist
- 👤 Horst Diefenbach
Bibliographic Details
Application Number
—
Jurisdiction
US
Data Source
google_patents
Last Synchronized
2026-11-02 07:03
CPC Classifications
C; C08; C08G; C08G59/00; C08G59/18; C08G59/40; C08G59/50; C08G59/56; C08G59/58; C08G18/00; C08G18/06; C08G18/08; C08G18/0804; C08G18/0809; C08G18/0814; C08G59/42; C08G59/4284; C09; C09D; C09D5/00; C09D5/44; C09D5/4419; C09D5/443; C09D5/4434; C09D5/4442; C09D5/4446; C09D5/4465; C09D5/4488
Claims Analysis
Total Claims: 12
Claim 1
Independent Claim
223 words
A self-cross-linking heat-curable binder based on an organic synthetic resin which contains amino groups and esterified carboxyl groups and is water-dilutable due to neutralization with acids, in which the esterified carboxyl groups are activated in the alcohol component and are β-hydroxylalkyl ester groups or carbalkoxymethyl ester groups and said organic synthetic resin is an epoxy resin which has been prepared by reacting a polyglycidyl ester or ether with a compound which carries two groups which are reactive toward epoxy groups and at least one of said esterified carboxyl groups to give an intermediate produce having terminal epoxy groups, and reacting said terminal epoxy groups having open rings with a compound selected from the group consisting of primary amines, secondary amines, ketimines having a hydrogen atom on the nitrogen atom, and aminoalcohols blocked at the nitrogen atom or a polyurethane resin which has been prepared by reacting a diisocyanate with a compound which carries two groups which are reactive toward isocyanate groups and at least one of said esterified carboxyl groups to give an intermediate product having terminal isocyanate groups, and reacting said terminal isocyanate groups with a compound selected from the group consisting of primary amines, secondary amines, ketimines having a hydrogen atom on the nitrogen atom, aldimines having a hydrogen atom on the nitrogen atom, and aminoalcohols blocked at the nitrogen atom.
Claim 2
Dependent Claim
223 words
A self-cross-linking heat-curable binder based on an organic synthetic resin which contains amino groups and esterified carboxyl groups and is water-dilutable due to neutralization with acids, in which the esterified carboxyl groups are activated in the alcohol component and are β-hydroxylalkyl ester groups or carbalkoxymethyl ester groups and said organic synthetic resin is an epoxy resin which has been prepared by reacting a polyglycidyl ester or ether with a compound which carries two groups which are reactive toward epoxy groups and at least one of said esterified carboxyl groups to give an intermediate produce having terminal epoxy groups, and reacting said terminal epoxy groups having open rings with a compound selected from the group consisting of primary amines, secondary amines, ketimines having a hydrogen atom on the nitrogen atom, and aminoalcohols blocked at the nitrogen atom or a polyurethane resin which has been prepared by reacting a diisocyanate with a compound which carries two groups which are reactive toward isocyanate groups and at least one of said esterified carboxyl groups to give an intermediate product having terminal isocyanate groups, and reacting said terminal isocyanate groups with a compound selected from the group consisting of primary amines, secondary amines, ketimines having a hydrogen atom on the nitrogen atom, aldimines having a hydrogen atom on the nitrogen atom, and aminoalcohols blocked at the nitrogen atom.
Claim 3
Dependent Claim
36 words
The binder of claim 1, in which the synthetic resin contains 1 to 5 primary amino groups, secondary amino groups, or a mixture thereof and 1 to 5 activated ester groups per 1,000 molecular weight units.
Claim 4
Dependent Claim
26 words
The binder of claim 2, in which the equivalence ratio between the primary and/or secondary amino groups and the activated carboxylate groups is 2:1 to 1:2.
Claim 5
Dependent Claim
105 words
A process for preparing a binder which comprises reacting polyglycidyl ester or polyglycidyl ether with a first compound which carries two groups which are reactive toward epoxy groups and at least one carboxylate group which is activated in the alcohol component and are β-hydroxyalkyl ester groups or carbalkoxymethyl ester groups to give an intermediate product having terminal epoxy groups, and reacting these epoxy groups having open rings with a second compound selected from the group consisting of amines, secondary amines, ketimines having a hydrogen atom on the nitrogen atom, aldimines having a hydrogen atom on the nitrogen atom, and aminoalcohols blocked at the nitrogen atom.
Claim 6
Dependent Claim
105 words
A process for preparing a binder which comprises reacting polyglycidyl ester or polyglycidyl ether with a first compound which carries two groups which are reactive toward epoxy groups and at least one carboxylate group which is activated in the alcohol component and are β-hydroxyalkyl ester groups or carbalkoxymethyl ester groups to give an intermediate product having terminal epoxy groups, and reacting these epoxy groups having open rings with a second compound selected from the group consisting of amines, secondary amines, ketimines having a hydrogen atom on the nitrogen atom, aldimines having a hydrogen atom on the nitrogen atom, and aminoalcohols blocked at the nitrogen atom.
Claim 7
Dependent Claim
101 words
A process for preparing a binder which comprises reacting a diisocyanate with a first compound which carries two groups which are reactive toward isocyanate groups and at least one carboxylate group which is activated in the alcohol component and are β-hydroxyalkyl ester groups or carbalkoxy methyl ester groups to give an intermediate product having terminal isocyanate groups, and reacting these isocyanate groups with a second compound selected from the group consisting of primary amines, secondary amines, ketimines having a hydrogen atom on the nitrogen atom, aldimines having a hydrogen atom on the nitrogen atom, and aminoalcohols blocked at the nitrogen atom.
Claim 8
Dependent Claim
101 words
A process for preparing a binder which comprises reacting a diisocyanate with a first compound which carries two groups which are reactive toward isocyanate groups and at least one carboxylate group which is activated in the alcohol component and are β-hydroxyalkyl ester groups or carbalkoxy methyl ester groups to give an intermediate product having terminal isocyanate groups, and reacting these isocyanate groups with a second compound selected from the group consisting of primary amines, secondary amines, ketimines having a hydrogen atom on the nitrogen atom, aldimines having a hydrogen atom on the nitrogen atom, and aminoalcohols blocked at the nitrogen atom.
Claim 9
Dependent Claim
51 words
The process of claim 4, wherein the molar ratios of the starting materials used are chosen in such a way that a binder is obtained which has 1 to 5 primary amino groups, secondary amino groups or mixtures thereof, and 1 to 5 activated carboxylate groups per 1,000 molecular weight units.
Claim 10
Dependent Claim
51 words
The process of claim 5, wherein the molar ratios of the starting materials used are chosen in such a way that a binder is obtained which has 1 to 5 primary amino groups, secondary amino groups, or mixtures thereof, and 1 to 5 activated carboxylate groups per 1,000 molecular weight units.
Claim 11
Dependent Claim
42 words
The process of claim 4, wherein the molar ratios of the starting materials are chosen in such a way that a binder is obtained which has an equivalence ratio between the amino groups and the activated carboxylate groups of 2:1 to 1:2.
Claim 12
Dependent Claim
42 words
The process of claim 5, wherein the molar ratios of the starting materials are chosen in such a way that a binder is obtained which has an equivalence ratio between the amino groups and the activated carboxylate groups of 2:1 to 1:2.
References Cited (Backward Citations)
USPTO Annuity & Maintenance Windows
| Annuity Stage | Window Opens | Payment Deadline | Surcharge Period Until | Estimated Fee | Status |
|---|---|---|---|---|---|
| 3.5 Years (Year 4) | 1988-01-22 | 1988-07-23 | 1989-01-22 | $2000.00 | Window Closed / Lapsed |
| 7.5 Years (Year 8) | 1992-01-22 | 1992-07-23 | 1993-01-22 | $3760.00 | Window Closed / Lapsed |
| 11.5 Years (Year 12) | 1996-01-22 | 1996-07-23 | 1997-01-22 | $7700.00 | Window Closed / Lapsed |