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US4491554A Expired / Lapsed US ⏱️ 0.0 years remaining

One part activator and blowing agent for foaming plastics

Assignee: ATK Launch Systems LLC
•
Filing: 1983-09-27
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Granted: 1985-01-01
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Expires: 2003-09-27
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Abstract

Abstract A one-part activator and blowing agent system for foaming plastics comprising an alkali metal borohydride and a salt hydrate blended in a single pellet or as separate pellets with a dry inert resinous polymer carrier. The one-part system is blended with a resinous polymer and then the blend extruded at a temperature at which the blend becomes molten such that the salt hydrate releases its water of hydration to hydrolyze the borohydride and produce a cellular article.

Inventors

  • 👤 Roger G. Hamel
  • 👤 Susan B. Poulin

Bibliographic Details

Application Number —
Jurisdiction US
Data Source google_patents
Last Synchronized 2026-11-03 12:46
CPC Classifications
B; B29; B29B; B29B9/00; B29B9/02; B29B9/06; C; C08; C08J; C08J9/00; C08J9/04; C08J9/06; C08J9/065; B29K; B29K2105/00; B29K2105/04; Y; Y10; Y10S; Y10S264/00; Y10S264/05

Claims Analysis

Total Claims: 12
Claim 1
Independent Claim 97 words
A method of making a stable one-part alkali metal borohydride concentrate comprising: (a) dry blending a mixture of an inert resinous polymer, an alkali metal borohydride, and a salt hydrate; (b) heating the mixture to a temperature above the melting point of the resin but a temperature less than that which would result in the release of a substantial amount of the water of hydration of the salt hydrate to form a molten mixture; (c) extruding the molten mixture and cooling to form a solid stable concentrate; and (d) forming the extruded and cooled concentrate into pellets.
Claim 2
Independent Claim 97 words
A method of making a stable one-part alkali metal borohydride concentrate comprising: (a) dry blending a mixture of an inert resinous polymer, an alkali metal borohydride, and a salt hydrate; (b) heating the mixture to a temperature above the melting point of the resin but a temperature less than that which would result in the release of a substantial amount of the water of hydration of the salt hydrate to form a molten mixture; (c) extruding the molten mixture and cooling to form a solid stable concentrate; and (d) forming the extruded and cooled concentrate into pellets.
Claim 3
Dependent Claim 19 words
The method of claim 1 wherein the borohydride is present at between about 0.5% and about 25.0% by weight.
Claim 4
Dependent Claim 14 words
The method of claim 1 wherein the borohydride is sodium borohydride or potassium borohydride.
Claim 5
Dependent Claim 32 words
The method of claim 1 wherein the salt hydrate is Na 2 B 4 O 7 .5H 2 O, MgSO 3 .6H 2 O, MgSO 4 .7H 2 O, or alumina trihydrate.
Claim 6
Dependent Claim 18 words
The method of claim 1 wherein the resin is a polyolefin, polydiene, polystyrene, polyphenylene oxide-styrene, polyacrylate, or polyvinylacetate.
Claim 7
Independent Claim 174 words
A method of making a stable one-part alkali metal borohydride activator system comprising: (a) dry blending a mixture of an inert resinous polymer and an alkali metal borohydride; (b) dry blending a mixture of an inert resinous polymer and a salt hydrate; (c) heating the mixture of (a) to a temperature above the melting point of the resin to form a molten mixture; (d) heating the mixture of (b) to a temperature above the melting point of the resin but a temperature less than that which would result in the release of a substantial amount of the water of hydration of the salt hydrate to form a molten mixture; (e) extruding the molten mixture of (c) to form a solid stable concentrate; (f) extruding the molten mixture of (d) to form a solid stable salt hydrate concentrate; (g) forming the extruded and cooled concentrate of (e) into pellets; (h) forming the extruded and cooled concentrate of (f) into pellets; (i) mixing the pellets of (g) with the pellets of (h) in an appropriate ratio.
Claim 8
Independent Claim 174 words
A method of making a stable one-part alkali metal borohydride activator system comprising: (a) dry blending a mixture of an inert resinous polymer and an alkali metal borohydride; (b) dry blending a mixture of an inert resinous polymer and a salt hydrate; (c) heating the mixture of (a) to a temperature above the melting point of the resin to form a molten mixture; (d) heating the mixture of (b) to a temperature above the melting point of the resin but a temperature less than that which would result in the release of a substantial amount of the water of hydration of the salt hydrate to form a molten mixture; (e) extruding the molten mixture of (c) to form a solid stable concentrate; (f) extruding the molten mixture of (d) to form a solid stable salt hydrate concentrate; (g) forming the extruded and cooled concentrate of (e) into pellets; (h) forming the extruded and cooled concentrate of (f) into pellets; (i) mixing the pellets of (g) with the pellets of (h) in an appropriate ratio.
Claim 9
Dependent Claim 19 words
The method of claim 6 wherein the borohydride is present at between about 0.5% and about 25.0% by weight.
Claim 10
Dependent Claim 13 words
The method of claim 6 wherein borohydride is sodium borohydride or potassium borohydride.
Claim 11
Dependent Claim 32 words
The method of claim 6 wherein the salt hydrate is Na 2 B 4 O 7 .5H 2 O, MgSO 3 .6H 2 O, MgSO 4 .7H 2 O, or alumina trihydrate.
Claim 12
Dependent Claim 18 words
The method of claim 6 wherein the resin is a polyolefin, polydiene, polystyrene, polyphenylene oxide-styrene, polyacrylate, or polyvinylacetate.

References Cited (Backward Citations)

US2758980A Cited
US2909493A Cited
US2930771A Cited
US2951819A Cited
US3167520A Cited
US3331790A Cited
US3393260A Cited
US4394458A Cited
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USPTO Annuity & Maintenance Windows

Annuity Stage Window Opens Payment Deadline Surcharge Period Until Estimated Fee Status
3.5 Years (Year 4) 1988-01-01 1988-07-02 1989-01-01 $2000.00 Window Closed / Lapsed
7.5 Years (Year 8) 1992-01-01 1992-07-02 1993-01-01 $3760.00 Window Closed / Lapsed
11.5 Years (Year 12) 1996-01-01 1996-07-02 1997-01-01 $7700.00 Window Closed / Lapsed

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