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US4490490A Expired / Lapsed US ⏱️ 0.0 years remaining

High load bearing flexible polyurethane foams

Assignee: BASF Corp
•
Filing: 1983-05-24
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Granted: 1984-12-25
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Expires: 2003-05-24
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Abstract

Abstract Enhanced load-bearing properties for flexible polyurethane foam can be achieved by employing a hydroxyl compound-modified benzyl ether-containing resole polyol as part of the polyol component (5 to 25 weight percent based on polyol) in the preparation of the foam.

Inventors

  • 👤 John T. Patton, Jr.
  • 👤 Thirumurti Narayan
  • 👤 Louis H. Dumas

Bibliographic Details

Application Number —
Jurisdiction US
Data Source google_patents
Last Synchronized 2026-10-29 07:29
CPC Classifications
C; C08; C08G; C08G18/00; C08G18/06; C08G18/28; C08G18/40; C08G18/4009; C08G18/4027; C08G18/04; C08G18/54; C08G18/542; C08G8/00; C08G8/04; C08G2110/00; C08G2110/0008; C08G2110/0041; C08G2110/005; C08G2110/0083

Claims Analysis

Total Claims: 10
Claim 1
Independent Claim 149 words
In the process for the preparation of a flexible polyurethane foam by reacting a mixture comprising a polyol, an organic polyisocyanate, a blowing agent, a surfactant, and a catalyst for the urethane reaction, the improvement wherein the polyol component is a mixture of 95 to 75 weight percent of a polyol having a functionality of about 1.5 to about 3.0 with a hydroxyl number of about 25 to about 60 and 5 to 25 weight percent of a hydroxyl compound-modified benzyl ether-containing resole polyol obtained by the metal carboxylate catalyzed reaction at 100° C. to 130° C. of a phenol or mixture of phenols, a molar excess relative to the phenolic component of a non-aqueous aldehyde having 1 to 6 carbon atoms, and a modifying amount of an aliphatic hydroxyl compound having 1 to 4 hydroxyl groups, 1 to 12 carbon atoms, and 0 to 5 ether oxygen atoms.
Claim 2
Dependent Claim 149 words
In the process for the preparation of a flexible polyurethane foam by reacting a mixture comprising a polyol, an organic polyisocyanate, a blowing agent, a surfactant, and a catalyst for the urethane reaction, the improvement wherein the polyol component is a mixture of 95 to 75 weight percent of a polyol having a functionality of about 1.5 to about 3.0 with a hydroxyl number of about 25 to about 60 and 5 to 25 weight percent of a hydroxyl compound-modified benzyl ether-containing resole polyol obtained by the metal carboxylate catalyzed reaction at 100° C. to 130° C. of a phenol or mixture of phenols, a molar excess relative to the phenolic component of a non-aqueous aldehyde having 1 to 6 carbon atoms, and a modifying amount of an aliphatic hydroxyl compound having 1 to 4 hydroxyl groups, 1 to 12 carbon atoms, and 0 to 5 ether oxygen atoms.
Claim 3
Dependent Claim 32 words
The process of claim 1 wherein the polyol constituting 95 to 75 weight percent of the polyol component is a polyether polyol derived from alkylene oxides having 2 to 4 carbon atoms.
Claim 4
Dependent Claim 40 words
The process of claim 1 wherein the polyol constituting 95 to 75 weight percent of the polyol component is a polymer modified polyether polyol in which the polymer is selected from the group consisting of vinyl polymer, polyisocyanurate, and polyhydrazodicarbonomide.
Claim 5
Dependent Claim 17 words
The process of claim 1 wherein the modified resole polyol is prepared from phenol, formaldehyde, and 1,4-butanediol.
Claim 6
Dependent Claim 142 words
Flexible polyurethane foam prepared by the reaction of a mixture comprising a polyol, an organic polyisocyanate, a blowing agent, a surfactant, and a catalyst for the urethane reaction, wherein the polyol component is a mixture of 95 to 75 weight percent of a polyol having a functionality of about 1.5 to about 3.0 with a hydroxyl number of about 25 to about 60, and 5 to 25 weight percent of a hydroxyl compound-modified benzyl ether-containing resole polyol obtained by the metal carboxylate catalyzed reaction at 100° C. to 130° C. of a phenol or mixture of phenols, a molar excess relative to the phenolic component of a non-aqueous aldehyde having 1 to 6 carbon atoms, and a modifying amount of an aliphatic hydroxyl compound having 1 to 4 hydroxyl groups, 1 to 12 carbon atoms, and 0 to 5 ether oxygen atoms.
Claim 7
Dependent Claim 142 words
Flexible polyurethane foam prepared by the reaction of a mixture comprising a polyol, an organic polyisocyanate, a blowing agent, a surfactant, and a catalyst for the urethane reaction, wherein the polyol component is a mixture of 95 to 75 weight percent of a polyol having a functionality of about 1.5 to about 3.0 with a hydroxyl number of about 25 to about 60, and 5 to 25 weight percent of a hydroxyl compound-modified benzyl ether-containing resole polyol obtained by the metal carboxylate catalyzed reaction at 100° C. to 130° C. of a phenol or mixture of phenols, a molar excess relative to the phenolic component of a non-aqueous aldehyde having 1 to 6 carbon atoms, and a modifying amount of an aliphatic hydroxyl compound having 1 to 4 hydroxyl groups, 1 to 12 carbon atoms, and 0 to 5 ether oxygen atoms.
Claim 8
Dependent Claim 32 words
The product of claim 5 wherein the polyol constituting 95 to 75 weight percent of the polyol component is a polyether polyol derived from alkylene oxides having 2 to 4 carbon atoms.
Claim 9
Dependent Claim 40 words
The product of claim 5 wherein the polyol constituting 95 to 75 weight percent of the polyol component is a polymer modified polyether polyol in which the polymer is selected from the group consisting of vinyl polymer, polyisocyanurate, and polyhydrazodicarbonomide.
Claim 10
Dependent Claim 17 words
The product of claim 5 wherein the modified resole polyol is prepared from phenol, formaldehyde, and 1,4-butanediol.

References Cited (Backward Citations)

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USPTO Annuity & Maintenance Windows

Annuity Stage Window Opens Payment Deadline Surcharge Period Until Estimated Fee Status
3.5 Years (Year 4) 1987-12-25 1988-06-25 1988-12-25 $2000.00 Window Closed / Lapsed
7.5 Years (Year 8) 1991-12-25 1992-06-25 1992-12-25 $3760.00 Window Closed / Lapsed
11.5 Years (Year 12) 1995-12-25 1996-06-25 1996-12-25 $7700.00 Window Closed / Lapsed

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