Blend of polyalkylene terephthalate and wholly aromatic polyester

Claim 2

A polymer blend which is capable of exhibiting an anisotropic melt phase and the ability to form shaped articles having satisfactory mechanical properties comprising: (a) approximately 5 to approximately 50 percent by weight, based upon the total weight of components (a) and (b), of a polyalkylene terephthalate wherein the alkylene units contain B 2 to 5 carbon atoms, and (b) approximately 50 to approximately 95 percent by weight, based upon the total weight of components (a) and (b), of a melt processable wholly aromatic polyester which is capable of forming an anisotropic melt phase apart from said blend.

Claim 3

A polymer blend according to claim 1 which is capable of undergoing melt processing at a temperature within the range of approximately 260° C. to 350° C.

Claim 4

A polymer blend according to claim 1 which is capable of undergoing melt processing at a temperature within the range of approximately 280° C. to 300° C.

Claim 5

A polymer blend according to claim 1 wherein the alkylene units of said polyalkylene terephthalate contain 2 to 4 carbon atoms.

Claim 6

A polymer blend according to claim 1 wherein said polyalkylene terephthalate is polyethylene terephthalate.

Claim 7

A polymer blend according to claim 1 wherein said wholly aromatic polyester apart from said blend is capable of forming an anisotropic melt phase at a temperature below approximately 350° C.

Claim 8

A polymer blend according to claim 1 wherein said wholly aromatic polyester apart from said blend exhibits an inherent viscosity of at least 2.0 dl./g. when dissolved in a concentration of 0.1 percent by weight in pentafluorophenol at 60° C.

Claim 9

A polymer blend according to claim 1 wherein said melt processable wholly aromatic polyester is capable of forming an anisotropic melt phase at a temperature no higher than approximately 320° C. apart from said blend and consists essentially of the recurring moieties I, II, III, and IV wherein: ##STR3## where R is methyl, chloro, bromo, or mixtures thereof, and is substituted for a hydrogen atom present upon the aromatic ring, wherein said melt processable wholly aromatic polyester consists of approximately 20 to 60 mole percent of moiety I, approximately 5 to 18 mole percent of moiety II, approximately 5 to 35 mole percent of moiety III, and approximately 20 to 40 mole percent of moiety IV.

Claim 10

A polymer blend according to claim 8 wherein said R group of moiety IV is a methyl group.

Claim 11

A polymer blend according to claim 1 wherein said melt processable wholly aromatic polyester is capable of forming an anisotropic melt phase at a temperature below approximately 325° C. apart from said blend and consists essentially of the recurring moieties I, II, and III wherein: ##STR4## wherein said polyester comprises approximately 30 to 70 mole percent of moiety I.

Claim 12

A molding compound comprising the polymer blend of claim 1 which incorporates approximately 1 to 50 percent by weight, based upon the total weight of said molding compound, of a material selected from the group consisting of solid filler, reinforcing agent, and the mixtures thereof.

Claim 13

A molding compound according to claim 11 which incorporates approximately 10 to approximately 30 percent by weight, based upon the total weight of said molding compound, of a material selected from the group consisting of solid filler, reinforcing agent, and mixtures thereof.

Claim 14

A molded article comprising the blend of claim 1.

Claim 15

A fiber which has been melt spun from the blend of claim 1.

Claim 16

A film which has been melt extruded from the blend of claim 1.

Claim 17

A polymer blend according to claim 1 which is capable of being satisfactorily molded while employing a mold temperature less than approximately 100° C.

Claim 18

A polymer blend which is capable of exhibiting an anisotropic melt phase and the ability to form shaped articles having improved mechanical properties comprising: (a) approximately 5 to approximately 50 percent by weight, based upon the total weight of components (a) and (b), of polyethylene terephthalate, and (b) approximately 50 to approximately 95 percent by weight, based upon the total weight of components (a) and (b), of a melt processable wholly aromatic polyester which is capable of forming an anisotropic melt phase at a temperature no higher than approximately 320° C. apart from said blend and consists essentially of the recurring moieties I, II, III, and IV wherein: ##STR5## wherein said polyester comprises approximately 20 to 60 mole percent of moiety I, approximately 5 to 18 mole percent of moiety II, approximately 5 to 35 mole percent of moiety III, and approximately 20 to 40 mole percent of moiety IV.

Claim 19

A polymer blend which is capable of exhibiting an anisotropic melt phase and the ability to form shaped articles having improved mechanical properties comprising: (a) approximately 5 to approximately 50 percent by weight, based upon the total weight of components (a) and (b), of polyethylene terephthalate, and (b) approximately 50 to approximately 95 percent by weight, based upon the total weight of components (a) and (b), of a melt processable wholly aromatic polyester which is capable of forming an anisotropic melt phase at a temperature no higher than approximately 320° C. apart from said blend and consists essentially of the recurring moieties I, II, III, and IV wherein: ##STR5## wherein said polyester comprises approximately 20 to 60 mole percent of moiety I, approximately 5 to 18 mole percent of moiety II, approximately 5 to 35 mole percent of moiety III, and approximately 20 to 40 mole percent of moiety IV.

Claim 20

A polymer blend according to claim 17 wherein said melt processable wholly aromatic polyester consists essentially of approximately 35 to 45 mole percent of moiety I, approximately 10 to 15 mole percent of moiety II, approximately 15 to 25 mole percent of moiety III, and approximately 25 to 35 mole percent of moiety IV, with the proviso that the total molar concentration of moieties II and III is substantially identical to that of moiety IV.

Claim 21

A polymer blend according to claim 18 which is capable of undergoing melt processing at a temperature within the range of approximately 280° C. to 300° C.

Claim 22

A polymer blend according to claim 18 wherein said wholly aromatic polyester exhibits an inherent viscosity of at least 2.0 dl./g. when dissolved in a concentration of 0.3 weight/volume percent in pentafluorophenol at 60° C.

Claim 23

A molding compound comprising the polymer blend of claim 18 which incorporates approximately 1 to 50 percent by weight, based upon the total weight of said molding compound, of a material selected from the group consisting of solid filler, reinforcing agent, and mixtures thereof.

Claim 24

A molding compound according to claim 21 which incorporates approximately 10 to 30 percent by weight, based upon the total weight of said molding compound, of a material selected from the group consisting of solid filler, reinforcing agent, and mixtures thereof.

Claim 25

A molded article comprising the polymer blend of claim 17.

Claim 26

A fiber which has been melt spun from the polymer blend of claim 17.

Claim 27

A film which has been melt extruded from the polymer blend of claim 17.

Claim 28

A polymer blend which is capable of exhibiting an anisotropic melt phase and the ability to form shaped articles having improved mechanical properties comprising: (a) approximately 5 to approximately 50 percent by weight, based upon the total weight of components (a) and (b), of polyethylene terephthalate, and (b) approximately 50 to approximately 95 percent by weight, based upon the total weight of components (a) and (b), of a melt processable wholly aromatic polyester which is capable of forming an anisotropic melt phase at a temperature no higher than approximately 320° C. and consists essentially of the recurring moieties I, II, III, and IV wherein: ##STR6## wherein said polyester comprises approximately 35 to 45 mole percent of moiety I, approximately 10 to 15 mole percent of moiety II, approximately 15 to 25 mole percent of moiety III, and approximately 25 to 35 mole percent of moiety IV, with the proviso that the total molar concentration of moieties II and III is substantially identical to that of moiety IV.

Claim 29

A polymer blend which is capable of exhibiting an anisotropic melt phase and the ability to form shaped articles having improved mechanical properties comprising: (a) approximately 5 to approximately 50 percent by weight, based upon the total weight of components (a) and (b), of polyethylene terephthalate, and (b) approximately 50 to approximately 95 percent by weight, based upon the total weight of components (a) and (b), of a melt processable wholly aromatic polyester which is capable of forming an anisotropic melt phase at a temperature no higher than approximately 320° C. and consists essentially of the recurring moieties I, II, III, and IV wherein: ##STR6## wherein said polyester comprises approximately 35 to 45 mole percent of moiety I, approximately 10 to 15 mole percent of moiety II, approximately 15 to 25 mole percent of moiety III, and approximately 25 to 35 mole percent of moiety IV, with the proviso that the total molar concentration of moieties II and III is substantially identical to that of moiety IV.

Claim 30

A polymer blend according to claim 26 which is capable of undergoing melt processing at a temperature within the range of approximately 280° C. to 300° C.

Claim 31

A polymer blend according to claim 26 wherein said wholly aromatic polyester apart from said blend exhibits an inherent viscosity of approximately 2.0 to 8.0 dl./g. when dissolved in a concentration of 0.3 weight/volume percent in pentafluorophenol at 60° C.

Claim 32

A molding compound comprising the polymer blend of claim 26 which incorporates approximately 1 to 50 percent by weight, based upon the total weight of said molding compound, of a material selected from the group consisting of solid filler, reinforcing agent, and mixtures thereof.

Claim 33

A molding compound according to claim 29 which incorporates approximately 10 to approximately 30 percent by weight, based upon the total weight of said molding compound, of a material selected from the group consisting of solid filler, reinforcing agent, and mixtures thereof.

Claim 34

A molded article comprising the polymer blend of claim 26.

Claim 35

A molded article according to claim 31 which exhibits a tensile strength of no less than approximately 24,000 p.s.i. and a flexural strength of no less than approximately 20,000 p.s.i.

Claim 36

A fiber which has been melt spun from the polymer blend of claim 26.

Claim 37

A film which has been melt extruded from the polymer blend of claim 26.