Abstract A process for preparing a catalyst for the oxidation of sulfur dioxide comprising: (a) intimately contacting a siliceous support with a mixture of a water-insoluble vanadium (V) compound, a potassium (K) salt so that the K/V molar ratio is maintained between about 2.5 and about 4.0, a source of sulfite anion, a water-insoluble sodium (Na) salt of an acid having a pKa between about 3 and about 7 so that the K/Na molar ratio is between about 4 and about 8, and water to form an intermediate product; (b) drying the intermediate product; (c) calcining the dried intermediate product; and (d) sulfating the calcined intermediate product; thus providing a catalyst with high durability and high catalytic activity with an alpha-cristobalite content between from about 1 to about 30 percent. The wet catalyst may be extruded into shaped forms such as spheres, cylinders, trilobes, or tablets before drying.
A process for preparing a catalyst for the oxidation of sulfur dioxide which comprises the steps of: (a) intimately contacting a siliceous support with a mixture comprising a solution of vanadium (V) pentoxide dissolved in potassium (K) hydroxide to provide a K/V molar ratio between about 2.5 and about 4.0, dissolved gaseous sulfur dioxide, a sufficient amount of a water-soluble sodium (Na) salt of an acid having a pKa between about 3 and about 7 to provide a K/Na molar ratio between about 4 and about 8, and water, the mixture being brought to a pH of about 9 to about 11 before impregnation, to form an impregnated support; (b) drying the impregnated support; and (c) calcining the dried impregnated support thus providing a catalyst with high durability and high catalytic activity with an alpha-cristobalite content between from about 1 to about 30 percent.
Claim 2
Dependent Claim
144 words
A process for preparing a catalyst for the oxidation of sulfur dioxide which comprises the steps of: (a) intimately contacting a siliceous support with a mixture comprising a solution of vanadium (V) pentoxide dissolved in potassium (K) hydroxide to provide a K/V molar ratio between about 2.5 and about 4.0, dissolved gaseous sulfur dioxide, a sufficient amount of a water-soluble sodium (Na) salt of an acid having a pKa between about 3 and about 7 to provide a K/Na molar ratio between about 4 and about 8, and water, the mixture being brought to a pH of about 9 to about 11 before impregnation, to form an impregnated support; (b) drying the impregnated support; and (c) calcining the dried impregnated support thus providing a catalyst with high durability and high catalytic activity with an alpha-cristobalite content between from about 1 to about 30 percent.