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US4484971A Expired / Lapsed US ⏱️ 0.0 years remaining

Method and apparatus for making improved laminating film

Assignee: General Binding Corp
•
Filing: 1983-09-07
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Granted: 1984-11-27
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Expires: 2003-09-07
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Abstract

Abstract A method and apparatus for manufacturing a film suitable for use in lamination under heat and pressure. A plurality of resins is co-extruded into concentric annuli, the inner annulus being a polyester type resin, and at least one of the outer annuli consisting of a polyolefin based resin. The co-extrusion is carried out as the extruding die is rotated about its axis. After quenching to form a multi-layer seamless tube, the tube is collapsed and heated to a temperature suitable for biaxial orientation. An air bubble is introduced into the heated tube to expand the diameter thereof and simultaneously orient the tube biaxially by molecular orientation. The biaxially oriented tube is cooled sufficiently to retain its molecular orientation, and is then collapsed. The tube is then heated to a shrinking temperature while under controlled restraint to achieve a predetermined dimension in amount of shrinkage in the film. Finally, the edges of the shrunk tube are slit to form a pair of flat films. Additional improvements are achieved by including irradiation of the films by ultraviolet light, and by treating one of the film surfaces with a corona discharge.

Inventors

  • 👤 James C. Wang

Bibliographic Details

Application Number —
Jurisdiction US
Data Source google_patents
Last Synchronized 2026-10-31 13:23
CPC Classifications
B; B32; B32B; B32B37/00; B32B37/28; B29; B29C; B29C48/00; B29C48/001; B29C48/0022; B29C48/03; B29C48/09; B29C48/10; B29C48/16; B29C48/18; B29C48/21; B29C48/25; B29C48/30; B29C48/32; B29C48/33; B29C48/335; B29C48/337; B29C48/338; B29C71/00; B29C71/02; B32B27/00; B32B27/06; B32B27/08; B32B37/14; B32B37/15; B32B37/153; B29C35/00; B29C35/02; B29C35/08; B29C35/0805; B29C2035/0827; B29C2793/00; B29C2793/0063; B29C48/0018; B29C48/0019; B29C48/355; B29C59/00; B29C59/02; B29C59/04; B29C59/10; B29C59/16; B29C61/00; B29C61/02; B29K; B29K2995/00; B29K2995/0037; B29K2995/005; B29K2995/0053; B32B2310/00; B32B2310/08; B32B2310/0806; B32B2310/0831; B32B38/00; B32B38/08

Claims Analysis

Total Claims: 21
Claim 1
Independent Claim 167 words
The method of manufacturing a film suitable for use in lamination under heat and pressure which comprises: (1) co-extruding concentric annuli of a polyester as the inner annulus and a polyolefin based resin as the outer annulus while rotating said annuli about their common axis during extrusion, (2) quenching the extrudate to form a multi-layer seamless tube, (3) heating the tube to a temperature suitable for biaxial orientation, (4) providing an air bubble in the heated tube to expand the diameter thereof to a diameter greater than that of the original extrudate to thereby orient the tube biaxially by molecular orientation, (5) cooling the biaxially oriented tube sufficiently to retain its molecular orientation, (6) collapsing the tube, (7) heating the tube to a heat-set temperature in excess of the temperature at which the film is to be laminated while restraining shrinkage thereof to a predetermined dimension, and (8) slitting the edges of the tube to form a pair of flat films which retain some transverse shrinkage properties.
Claim 2
Independent Claim 167 words
The method of manufacturing a film suitable for use in lamination under heat and pressure which comprises: (1) co-extruding concentric annuli of a polyester as the inner annulus and a polyolefin based resin as the outer annulus while rotating said annuli about their common axis during extrusion, (2) quenching the extrudate to form a multi-layer seamless tube, (3) heating the tube to a temperature suitable for biaxial orientation, (4) providing an air bubble in the heated tube to expand the diameter thereof to a diameter greater than that of the original extrudate to thereby orient the tube biaxially by molecular orientation, (5) cooling the biaxially oriented tube sufficiently to retain its molecular orientation, (6) collapsing the tube, (7) heating the tube to a heat-set temperature in excess of the temperature at which the film is to be laminated while restraining shrinkage thereof to a predetermined dimension, and (8) slitting the edges of the tube to form a pair of flat films which retain some transverse shrinkage properties.
Claim 3
Dependent Claim 14 words
A method according to claim 1 in which: said polyester resin is polyethylene terephthalate.
Claim 4
Dependent Claim 17 words
A method according to claim 1 in which: said polyolefin based resin is an ethylene-vinyl acetate copolymer.
Claim 5
Dependent Claim 32 words
A method according to claim 1 in which: irradiation of the films by ultraviolet light to enhance the interfacial adhesion is incorporated in step (7) when film temperature is above 230° F.
Claim 6
Dependent Claim 23 words
A method according to claim 1 in which: the slitting of step (8) is followed by texturizing treatment of the olefinic film surface.
Claim 7
Dependent Claim 29 words
A method according to claim 5 in which: the treatment of the olefinic film surface is followed by treatment of the surface of the slit film with corona discharge.
Claim 8
Independent Claim 189 words
The method of manufacturing a film suitable for use in lamination under heat and pressure which comprises: (1) co-extruding concentric annuli of a polyester resin as the inner annulus, an adhesive, polyolefin based resin as a middle annulus, and a polyolefin based resin having adhesive properties toward the desired substrate as the outer annulus while rotating said annuli about their common axis during extrusion, (2) quenching the extrudate to form a three-layer seamless tube, (3) collapsing the tube, (4) heating the collapsed tube to a temperature suitable for biaxial orientation, (5) providing an air bubble in the heated tube to expand the diameter thereof to a diameter greater than that of the original extrudate to therebv orient the tube biaxially by molecular orientation, (6) cooling the biaxially oriented tube sufficiently to retain its molecular orientation, (7) collapsing the tube, (8) heating the tube to a heat-set temperature in excess of the temperature at which the film is to be laminated while restraining shrinkage thereof to a predetermined dimension, and (9) slitting the edges of the tube to form a pair of flat films which retain some transverse shrinkage properties.
Claim 9
Independent Claim 189 words
The method of manufacturing a film suitable for use in lamination under heat and pressure which comprises: (1) co-extruding concentric annuli of a polyester resin as the inner annulus, an adhesive, polyolefin based resin as a middle annulus, and a polyolefin based resin having adhesive properties toward the desired substrate as the outer annulus while rotating said annuli about their common axis during extrusion, (2) quenching the extrudate to form a three-layer seamless tube, (3) collapsing the tube, (4) heating the collapsed tube to a temperature suitable for biaxial orientation, (5) providing an air bubble in the heated tube to expand the diameter thereof to a diameter greater than that of the original extrudate to therebv orient the tube biaxially by molecular orientation, (6) cooling the biaxially oriented tube sufficiently to retain its molecular orientation, (7) collapsing the tube, (8) heating the tube to a heat-set temperature in excess of the temperature at which the film is to be laminated while restraining shrinkage thereof to a predetermined dimension, and (9) slitting the edges of the tube to form a pair of flat films which retain some transverse shrinkage properties.
Claim 10
Dependent Claim 47 words
A method according to claim 7 wherein said inner annulus is composed of polyethylene terephthalate, said middle annulus is composed of an ethylene-vinyl acetate copolymer, and said outer annulus is composed of an ethylene-vinyl acetate copolymer having a smaller proportion of vinyl acetate than said middle annulus.
Claim 11
Dependent Claim 32 words
A method according to claim 7 in which: irradiation of the films by ultraviolet light to enhance the interfacial adhesion is incorporated in step (8) when film temperature is above 230° F.
Claim 12
Dependent Claim 22 words
A method according to claim 7 in which: the slitting of step (9) is followed by texturizing of the olefinic film surface.
Claim 13
Dependent Claim 17 words
A method according to claim 10 in which: the film surface is treated with a corona discharge.
Claim 14
Independent Claim 209 words
An apparatus for manufacturing a laminating film which comprises: a co-extrusion head arranged to extrude a plurality of coaxial abutting annuli of differing compositions, means for rotating said co-extrusion head during such extrusion, quenching means disposed beyond said co-extrusion head and arranged to quench the extrudate leaving said coextrusion head, first pressure rollers located beyond said quenching means and arranged to flatten the extruded and quenched annuli into a multi-layer seamless tube, first heater means receiving the flattened tube and arranged to heat said tube to a biaxial orientation temperature, means for expanding the heated flattened tube to a diameter greater than that of said annuli while simultaneously biaxially orienting the same, cooling means positioned to cool the biaxially oriented tube sufficiently to control the orientation layer, second pressure rollers located beyond said cooling means and arranged to flatten the biaxially oriented tube, second heater means located beyond said second pressure rollers and arranged to heat the flattened tube to a heat-set temperature, a spreader positionable inside said flattened tube and arranged to support the tube and limit the amount of film shrinkage induced by said second heater means, and slitter means following said spreader arranged to slit said tube along its edges into a pair of flat films.
Claim 15
Independent Claim 209 words
An apparatus for manufacturing a laminating film which comprises: a co-extrusion head arranged to extrude a plurality of coaxial abutting annuli of differing compositions, means for rotating said co-extrusion head during such extrusion, quenching means disposed beyond said co-extrusion head and arranged to quench the extrudate leaving said coextrusion head, first pressure rollers located beyond said quenching means and arranged to flatten the extruded and quenched annuli into a multi-layer seamless tube, first heater means receiving the flattened tube and arranged to heat said tube to a biaxial orientation temperature, means for expanding the heated flattened tube to a diameter greater than that of said annuli while simultaneously biaxially orienting the same, cooling means positioned to cool the biaxially oriented tube sufficiently to control the orientation layer, second pressure rollers located beyond said cooling means and arranged to flatten the biaxially oriented tube, second heater means located beyond said second pressure rollers and arranged to heat the flattened tube to a heat-set temperature, a spreader positionable inside said flattened tube and arranged to support the tube and limit the amount of film shrinkage induced by said second heater means, and slitter means following said spreader arranged to slit said tube along its edges into a pair of flat films.
Claim 16
Dependent Claim 23 words
An apparatus according to claim 12 which includes: ultraviolet irradiation means disposed within said spreader for enhancing the interfacial adhesion of the film.
Claim 17
Dependent Claim 27 words
An apparatus according to claim 12 which includes: a corona discharge device located downstream of said slitter means and positioned to treat a surface of the films.
Claim 18
Dependent Claim 27 words
An apparatus according to claim 14 which includes: a texturizing means immediately preceding said coronaa discharge means and arranged to roughen the outer surface of the film.
Claim 19
Dependent Claim 13 words
The method of claim 1 wherein said heat-set temperature is about 400° F.
Claim 20
Dependent Claim 13 words
The method of claim 7 wherein said heat-set temperature is about 400° F.
Claim 21
Dependent Claim 13 words
The apparatus of claim 12 wherein said heat-set temperature is about 400° F.

References Cited (Backward Citations)

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US4198256A Cited
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US4198458A Cited
US4095012A Cited
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USPTO Annuity & Maintenance Windows

Annuity Stage Window Opens Payment Deadline Surcharge Period Until Estimated Fee Status
3.5 Years (Year 4) 1987-11-27 1988-05-28 1988-11-27 $2000.00 Window Closed / Lapsed
7.5 Years (Year 8) 1991-11-27 1992-05-28 1992-11-27 $3760.00 Window Closed / Lapsed
11.5 Years (Year 12) 1995-11-27 1996-05-28 1996-11-27 $7700.00 Window Closed / Lapsed

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