US4483973A
Expired / Lapsed
US
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Adhesion promoters for one-component RTV silicone compositions
Assignee: General Electric Co
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Filing: 1982-02-17
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Granted: 1984-11-20
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Expires: 2002-02-17
Abstract
Abstract A self-bonding alkoxy-functional one-component RTV composition which contains as a self-bonding additive a silane which is functionalized by radicals selected from amino, ether, epoxy, isocyanato, cyano, acryloxy, and acyloxy. Such a composition is also shelf-stable and substantially non-corrosive.
Inventors
- 👤 Gary M. Lucas
- 👤 John J. Dziark
Bibliographic Details
Application Number
—
Jurisdiction
US
Data Source
google_patents
Last Synchronized
2026-10-24 15:42
CPC Classifications
C; C08; C08L; C08L83/00; C08L83/04; C08K; C08K5/00; C08K5/16; C08K5/29; C08K5/31; C08K5/54; C08L83/14; C08L83/16; C08G; C08G77/00; C08G77/04; C08G77/14; C08G77/18; Y; Y10; Y10S; Y10S528/00; Y10S528/901
Claims Analysis
Total Claims: 13
Claim 1
Independent Claim
161 words
A stable, one-package, substantially anhydrous and substantially acid-free, room temperature vulcanizable organopolysiloxane composition stable under ambient conditions in the substantial absence of moisture over an extended period of time and convertible to a tack-free elastomer comprising: (1) an organopolysiloxane wherein the silicon atom at each polymer chain end is terminated with at least two alkoxy radicals; (2) an effective amount of a condensation catalyst; (3) a stabilizing amount of scavenger for hydroxy functional groups; (4) an effective amount of a curing accelerator selected from the group consisting of substituted guanidines, amines and mixtures thereof; and (5) an effective amount of an adhesion promoter having the formula ##STR39## where R 10 and R 11 are C 1-8 monovalent hydrocarbon radicals, t varies from 0 to 3, and Z is a saturated, unsaturated or aromatic hydrocarbon radical, said radical being further functionalized by a member selected from the group consisting of amino, ether, epoxy, isocyanato, cyano, isocyanurate, acryloxy and acyloxy and mixtures thereof.
Claim 2
Dependent Claim
161 words
A stable, one-package, substantially anhydrous and substantially acid-free, room temperature vulcanizable organopolysiloxane composition stable under ambient conditions in the substantial absence of moisture over an extended period of time and convertible to a tack-free elastomer comprising: (1) an organopolysiloxane wherein the silicon atom at each polymer chain end is terminated with at least two alkoxy radicals; (2) an effective amount of a condensation catalyst; (3) a stabilizing amount of scavenger for hydroxy functional groups; (4) an effective amount of a curing accelerator selected from the group consisting of substituted guanidines, amines and mixtures thereof; and (5) an effective amount of an adhesion promoter having the formula ##STR39## where R 10 and R 11 are C 1-8 monovalent hydrocarbon radicals, t varies from 0 to 3, and Z is a saturated, unsaturated or aromatic hydrocarbon radical, said radical being further functionalized by a member selected from the group consisting of amino, ether, epoxy, isocyanato, cyano, isocyanurate, acryloxy and acyloxy and mixtures thereof.
Claim 3
Dependent Claim
82 words
The composition of claim 1 wherein Z is a saturated, unsaturated or aromatic hydrocarbon radical further functionalized by an amine group to provide an adhesion promoter of the formula ##STR40## where R 10 and R 11 are C 1-8 monovalent hydrocarbon radicals, R 12 is a C 2-12 divalent hydrocarbon radical, R 13 and R 14 are selected from the group consisting of hydrogen, amine radicals and C 1-8 monovalent hydrocarbon radicals and mixtures thereof, and t varies from 0 to 3.
Claim 4
Dependent Claim
104 words
The composition of claim 1 wherein Z is a saturated, unsaturated or aromatic hydrocarbon radical further functionalized by an isocyanurate group to provide an adhesion promoter of the formula ##STR41## where G is selected from R 20 radicals, radicals of the formula ##STR42## styryl, vinyl, allyl, chloroallyl and cyclohexenyl radicals, where R 20 is a C 1-8 monovalent hydrocarbon radical or cyanoalkyl radical, R 21 is a C 1-8 monovalent hydrocarbon radical or cyanoalkyl radical, R 22 is a C 2-12 divalent hydrocarbon radical selected from alkylenearylene, alkylene, and cycloalkylene and halogenated alkylenearylene, alkylene and cycloalkylene and where b varies from 0 to 3.
Claim 5
Dependent Claim
79 words
The composition of claim 1 wherein Z is a saturated, unsaturated or aromatic hydrocarbon radical further functionalized by a radical of the formula ##STR43## to provide an adhesion promoter of the formula ##STR44## where R 10 and R 11 are C 1-8 monovalent hydrocarbon radicals, R 12 and R 16 are C 2-12 divalent hydrocarbon radicals, R 17 is selected from the group consisting of hydrogen and C 1-8 monovalent hydrocarbon radicals, and t varies from 0 to 3.
Claim 6
Dependent Claim
71 words
The composition of claim 1 wherein Z is a saturated, unsaturated or aromatic hydrocarbon radical further functionalized by an epoxy group to provide an adhesion promoter of the formula ##STR45## where R 10 and R 11 are C 1-8 monovalent hydrocarbon radicals, R 12 is a C 2-12 divalent hydrocarbon radical, Q is an epoxy functional radical having a saturated hydrocarbon ring attached thereto, and t varies from 0 to 3.
Claim 7
Dependent Claim
77 words
The composition of claim 1 wherein Z is a saturated, unsaturated or aromatic hydrocarbon radical further functionalized by an isocyanato group to provide an adhesion promoter of the formula ##STR46## where R 10 and R 11 are C 1-8 monovalent hydrocarbon radicals, R 12 is a C 2-12 divalent hydrocarbon radical, R 25 and R 26 are selected from the group consisting of hydrogen and C 1-8 monovalent hydrocarbon radicals, and t varies from 0 to 3.
Claim 8
Dependent Claim
58 words
The composition of claim 1 wherein Z is a saturated, unsaturated or aromatic hydrocarbon radical further functionalized by a cyano group to provide an adhesion promoter of the formula ##STR47## where R 10 and R 11 are C 1-8 monovalent hydrocarbon radicals, R 12 is a C 2-12 divalent hydrocarbon radical, and t varies from 0 to 3.
Claim 9
Dependent Claim
77 words
The composition of claim 1 wherein Z is a saturated, unsaturated or aromatic hydrocarbon radical further functionalized by an acryloxy radical to provide an adhesion promoter of the formula ##STR48## where R 10 and R 11 are C 1-8 monovalent hydrocarbon radicals, R 12 is a C 2-12 divalent hydrocarbon radical, R 30 and R 31 are selected from the group consisting of hydrogen and C 1-8 monovalent hydrocarbon radicals, and t varies from 0 to 3.
Claim 10
Dependent Claim
67 words
The composition of claim 1 wherein Z is a saturated, unsaturated or aromatic hydrocarbon radical further functionalized by an acyloxy radical to provide an adhesion promoter of the formula ##STR49## where R 10 and R 11 are C 1-8 monovalent hydrocarbon radicals, R 12 is a C 2-12 divalent hydrocarbon radical, R 33 is a C 1-8 monovalent hydrocarbon radical and t varies from 0 to 3.
Claim 11
Dependent Claim
11 words
The composition of claim 1 wherein the adhesion promoter is cyanoethyltrimethoxysilane.
Claim 12
Dependent Claim
11 words
The composition of claim 1 wherein the adhesion promoter is aminoethylaminopropyltrimethoxysilane.
Claim 13
Dependent Claim
16 words
The composition of claim 1 wherein the adhesion promoter is a mixture of cyanoethyltrimethoxysilane and aminoethylaminopropyltrimethoxysilane.
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USPTO Annuity & Maintenance Windows
| Annuity Stage | Window Opens | Payment Deadline | Surcharge Period Until | Estimated Fee | Status |
|---|---|---|---|---|---|
| 3.5 Years (Year 4) | 1987-11-20 | 1988-05-21 | 1988-11-20 | $2000.00 | Window Closed / Lapsed |
| 7.5 Years (Year 8) | 1991-11-20 | 1992-05-21 | 1992-11-20 | $3760.00 | Window Closed / Lapsed |
| 11.5 Years (Year 12) | 1995-11-20 | 1996-05-21 | 1996-11-20 | $7700.00 | Window Closed / Lapsed |