Patent US4481315A successfully refreshed from Google Patents.
US4481315A
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Polyalkylpiperidine light stabilizers
Assignee: BASF Corp
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Filing: 1983-02-28
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Granted: 1984-11-06
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Expires: 2003-02-28
Abstract
Abstract Compounds which contain, in their molecule, at least one 2-(2'-hydroxyphenyl)-benztriazole group or one 2-hydroxybenzophenone group and at least one polyalkylpiperidine group are effective light stabilizers for organic materials, in particular for polymers. The use of the compounds as light stabilizers for lacquers is of particular importance.
Inventors
- 👤 Jean Rody
- 👤 Mario Slongo
Bibliographic Details
Application Number
—
Jurisdiction
US
Data Source
google_patents
Last Synchronized
2026-11-05 18:50
CPC Classifications
C; C08; C08K; C08K5/00; C08K5/16; C08K5/34; C08K5/3412; C08K5/3432; C08K5/3435; C07; C07D; C07D211/00; C07D211/04; C07D211/06; C07D211/36; C07D211/40; C07D211/44; C07D211/46; C09; C09D; C09D7/00; C09D7/40; C09D7/48
Claims Analysis
Total Claims: 13
Claim 1
Independent Claim
482 words
A compound of the formula A--B or A--Z--B wherein A is one of the groups ##STR14## in which one R is H and the other R is a free valency; R 1 is H, Cl, C 1 -C 4 alkyl, OH or C 1 -C 4 alkoxy; R 2 and R 3 independently of one another are H, Cl, C 1 -C 12 alkyl, C 5 -C 8 cycloalkyl, phenyl, C 7 -C 9 phenylalkly, OH or C 1 -C 12 alkoxy; R 4 and R 5 independently of one another are H, Cl, OH, C 1 -C 12 alkoxy or C 1 -C 12 alkyl; R 6 is H or CH 3 ; R 7 is H, O, C 1 -C 12 alkyl, C 3 -C 8 alkenyl, benzyl, acetyl or a group --CH 2 --CH(OH)--R 13 ; R 8 is C 1 -C 12 alkyl, C 3 -C 8 alkenyl or C 7 -C 9 phenylalkyl; R 10 and R 11 are hydrogen, C 1 -C 12 alkyl, phenyl or benzyl, or R 10 and R 11 are together C 4 -C 19 alkylene; R 12 is H; R 13 is H, CH 3 , C 2 H 5 or phenyl; X is a ##STR15## alkyl group; Y is C 2 -C 8 alkylene; and --Z-- is one of the following groups: --(CH 2 )--CO--O--, --(CH 2 ) m --CO--O--R 14 --, --O--(CH 2 ) n --CO--O--R 14 --, --CH 2 --CH(OH)--CH 2 --O--CO--(CH 2 ) m --, --O--CH 2 --CH(OH)--CH 2 --O--CO--(CH 2 ) m --, --CH 2 --CH(OH)--CH 2 --, --CH 2 --CH(OH)--CH 2 --O--, --CH 2 --CH(OH)--CH 2 --N(R 15 )--(CH 2 ) m --, --O--CH 2 --CH(OH)--CH 2 --N(R 15 )--(CH 2 ) m --, --N(R 15 )--CH 2 --CH(OH)--CH 2 --N(R 16 )--(CH 2 ) m --, --CH 2 --CH(R 13 )--O--CH 2 --CH(OH)--CH 2 --N(R 15 )--(CH 2 ) m --, --CH 2 --CH(R 13 )--O--CH 2 --CH(OH)--CH 2 --O--CO--(CH 2 ) m --, --(CH 2 ) m --N(R 15 )--CO--, --(CH 2 ) m --N(R 15 )--CO--(CH 2 ) n --, --O--(CH 2 ) 3 --N(R 15 )--CO--(CH 2 ) m --, --CH 2 --NH--CO--CH 2 --O--, --CH 2 --NH--CO--CH 2 --O--CH(R 13 )--CH 2 --, --CH 2 --NH--CO--CH 2 --N(R 15 )--(CH 2 ) m --, --CH 2 --NH--CO--CH 2 CH 2 --N(R 15 )--(CH 2 ) m -- or ##STR16## in which m is 0, 1 or 2, n is 1 or 2, R 14 is --CH 2 -- or --CH(R 13 )--CH 2 --, R 15 and R 16 are H, C 1 -C 12 -alkyl, cyclohexyl or benzyl, R 17 is --O-- or --NR 15 -- and R 18 is C 1 -C 12 -alkoxy, phenoxy or an amino group ##STR17## or a group AII is linked to a group B via a radical --O--(CH 2 ) n --CO--O--.
Claim 2
Dependent Claim
482 words
A compound of the formula A--B or A--Z--B wherein A is one of the groups ##STR14## in which one R is H and the other R is a free valency; R 1 is H, Cl, C 1 -C 4 alkyl, OH or C 1 -C 4 alkoxy; R 2 and R 3 independently of one another are H, Cl, C 1 -C 12 alkyl, C 5 -C 8 cycloalkyl, phenyl, C 7 -C 9 phenylalkly, OH or C 1 -C 12 alkoxy; R 4 and R 5 independently of one another are H, Cl, OH, C 1 -C 12 alkoxy or C 1 -C 12 alkyl; R 6 is H or CH 3 ; R 7 is H, O, C 1 -C 12 alkyl, C 3 -C 8 alkenyl, benzyl, acetyl or a group --CH 2 --CH(OH)--R 13 ; R 8 is C 1 -C 12 alkyl, C 3 -C 8 alkenyl or C 7 -C 9 phenylalkyl; R 10 and R 11 are hydrogen, C 1 -C 12 alkyl, phenyl or benzyl, or R 10 and R 11 are together C 4 -C 19 alkylene; R 12 is H; R 13 is H, CH 3 , C 2 H 5 or phenyl; X is a ##STR15## alkyl group; Y is C 2 -C 8 alkylene; and --Z-- is one of the following groups: --(CH 2 )--CO--O--, --(CH 2 ) m --CO--O--R 14 --, --O--(CH 2 ) n --CO--O--R 14 --, --CH 2 --CH(OH)--CH 2 --O--CO--(CH 2 ) m --, --O--CH 2 --CH(OH)--CH 2 --O--CO--(CH 2 ) m --, --CH 2 --CH(OH)--CH 2 --, --CH 2 --CH(OH)--CH 2 --O--, --CH 2 --CH(OH)--CH 2 --N(R 15 )--(CH 2 ) m --, --O--CH 2 --CH(OH)--CH 2 --N(R 15 )--(CH 2 ) m --, --N(R 15 )--CH 2 --CH(OH)--CH 2 --N(R 16 )--(CH 2 ) m --, --CH 2 --CH(R 13 )--O--CH 2 --CH(OH)--CH 2 --N(R 15 )--(CH 2 ) m --, --CH 2 --CH(R 13 )--O--CH 2 --CH(OH)--CH 2 --O--CO--(CH 2 ) m --, --(CH 2 ) m --N(R 15 )--CO--, --(CH 2 ) m --N(R 15 )--CO--(CH 2 ) n --, --O--(CH 2 ) 3 --N(R 15 )--CO--(CH 2 ) m --, --CH 2 --NH--CO--CH 2 --O--, --CH 2 --NH--CO--CH 2 --O--CH(R 13 )--CH 2 --, --CH 2 --NH--CO--CH 2 --N(R 15 )--(CH 2 ) m --, --CH 2 --NH--CO--CH 2 CH 2 --N(R 15 )--(CH 2 ) m -- or ##STR16## in which m is 0, 1 or 2, n is 1 or 2, R 14 is --CH 2 -- or --CH(R 13 )--CH 2 --, R 15 and R 16 are H, C 1 -C 12 -alkyl, cyclohexyl or benzyl, R 17 is --O-- or --NR 15 -- and R 18 is C 1 -C 12 -alkoxy, phenoxy or an amino group ##STR17## or a group AII is linked to a group B via a radical --O--(CH 2 ) n --CO--O--.
Claim 3
Dependent Claim
53 words
A compound according to claim 1 which contains a group B I, B II, B IV or B V, in which R 6 is hydrogen, R 7 is hydrogen, C 1 -C 8 alkyl, allyl or benzyl and R 8 is C 1 -C 12 alkyl, C 3 -C 5 alkenyl or benzyl.
Claim 4
Dependent Claim
23 words
A compound according to claim 1, which contains a group of the formula A I, in which R 1 is hydrogen or chlorine.
Claim 5
Dependent Claim
80 words
A compound according to claim 1, in which the groups A are linked to the groups B by a direct bond or one of the groups --(CH 2 ) m --CO--O--, --(CH 2 ) m --CO--O--R 14 --, --O--(CH 2 ) n --CO--O--R 14 --, --(CH 2 ) m --N(R 15 )--CO--, --(CH 2 ) m --N(R 15 )--CO--(CH 2 ) n --, --CH 2 --NH--CO--CH 2 --O-- or --CH 2 --NH--CO--CH 2 --N(R 15 )--(CH 2 ) m --.
Claim 6
Dependent Claim
10 words
The compound according to claim 1, of the formula ##STR18##
Claim 7
Dependent Claim
10 words
The compound according to claim 1, of the formula ##STR19##
Claim 8
Dependent Claim
10 words
The compound according to claim 1, of the formula ##STR20##
Claim 9
Dependent Claim
10 words
The compound according to claim 1, of the formula ##STR21##
Claim 10
Dependent Claim
29 words
A method of stabilizing a polymer normally subject to deterioration by light which comprises incorporating into said polymer an effective stabilizing amount of a compound according to claim 1.
Claim 11
Dependent Claim
13 words
The method of claim 9, wherein said polymer is a binder for lacquers.
Claim 12
Dependent Claim
30 words
A composition of matter stabilized against light induced deterioration comprising a polymer normally subject to deterioration by light and 0.05 to 5%, by weight, of a compound of claim 1.
Claim 13
Dependent Claim
13 words
The composition of claim 11, wherein said polymer is a binder for lacquers.
References Cited (Backward Citations)
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USPTO Annuity & Maintenance Windows
| Annuity Stage | Window Opens | Payment Deadline | Surcharge Period Until | Estimated Fee | Status |
|---|---|---|---|---|---|
| 3.5 Years (Year 4) | 1987-11-06 | 1988-05-07 | 1988-11-06 | $2000.00 | Window Closed / Lapsed |
| 7.5 Years (Year 8) | 1991-11-06 | 1992-05-07 | 1992-11-06 | $3760.00 | Window Closed / Lapsed |
| 11.5 Years (Year 12) | 1995-11-06 | 1996-05-07 | 1996-11-06 | $7700.00 | Window Closed / Lapsed |