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US4481250A Expired / Lapsed US ⏱️ 0.0 years remaining

Vinyl acetate-ethylene binder composition having good wet tensile strength and low heat seal temperature for nonwoven products

Assignee: Air Products and Chemicals Inc
•
Filing: 1983-07-29
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Granted: 1984-11-06
•
Expires: 2003-07-29
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Abstract

Abstract An emulsion composition is disclosed which provides a binder having good wet tensile strength and low heat seal temperature for nonwoven products which comprises an aqueous dispersion of a mixture consisting essentially of 50 to 95 wt % of a vinyl acetate-ethylene copolymer and 5 to 50 wt % of a vinyl acetate-ethylene-crosslinking monomer copolymer.

Inventors

  • 👤 Gerald R. Cook
  • 👤 Phillip A. Mango

Bibliographic Details

Application Number —
Jurisdiction US
Data Source google_patents
Last Synchronized 2026-11-07 21:30
CPC Classifications
C; C08; C08L; C08L31/00; C08L31/02; C08L31/04; D; D04; D04H; D04H1/00; D04H1/40; D04H1/58; D04H1/587; D04H1/64; C08L2205/00; C08L2205/04; Y; Y10; Y10S; Y10S428/00; Y10S428/913; Y10T; Y10T428/00; Y10T428/249921; Y10T428/249924; Y10T428/24994; Y10T442/00; Y10T442/20; Y10T442/2738

Claims Analysis

Total Claims: 23
Claim 1
Independent Claim 77 words
An emulsion composition providing a binder having good wet tensile strength and heat sealability for nonwoven products comprising an aqueous dispersion of a mixture consisting essentially of (a) 50 to 95 wt% copolymer A containing 60 to 95 wt% vinyl acetate and 5 to 40 wt% ethylene, and (b) 5 to 50 wt% copolymer B containing 60 to 95 wt% vinyl acetate, 5 to 40 wt% ethylene and up to about 10 wt% crosslinking mono-olefinically unsaturated monomer.
Claim 2
Dependent Claim 77 words
An emulsion composition providing a binder having good wet tensile strength and heat sealability for nonwoven products comprising an aqueous dispersion of a mixture consisting essentially of (a) 50 to 95 wt% copolymer A containing 60 to 95 wt% vinyl acetate and 5 to 40 wt% ethylene, and (b) 5 to 50 wt% copolymer B containing 60 to 95 wt% vinyl acetate, 5 to 40 wt% ethylene and up to about 10 wt% crosslinking mono-olefinically unsaturated monomer.
Claim 3
Dependent Claim 25 words
The composition of claim 1 in which the mixture consists essentially of 65 to 90 wt% copolymer A and 10 to 35 wt% copolymer B.
Claim 4
Dependent Claim 58 words
The composition of claim 1 in which the vinyl acetate content is 75 to 85 wt% and the ethylene content is 15 to 25 wt% of copolymer A, and the vinyl acetate is 70 to 80 wt%, the ethylene is 15 to 25 wt% and the crosslinking mono-olefinically unsaturated monomer is 4 to 8 wt% of copolymer B.
Claim 5
Dependent Claim 58 words
The composition of claim 2 in which the vinyl acetate content is 75 to 85 wt% and the ethylene content is 15 to 25 wt% of copolymer A, and the vinyl acetate is 70 to 80 wt%, the ethylene is 15 to 25 wt% and the crosslinking mono-olefinically unsaturated monomer is 4 to 8 wt% of copolymer B.
Claim 6
Dependent Claim 32 words
The composition of claim 1 in which the crosslinking olefinically unsaturated monomer is N-methylol acrylamide, N-methylol methacrylamide, the lower alkyl ethers of N-methylol acrylamide or N-methylol methacrylamide, acrylamide, methacrylamide, or acrylic acid.
Claim 7
Dependent Claim 15 words
The composition of claim 4 in which the crosslinking mono-olefinically unsaturated monomer is 4-6 wt%.
Claim 8
Dependent Claim 78 words
A nonwoven product comprising a web of fibers bonded together with a binder deposited from an emulsion composition comprising an aqueous dispersion of a mixture consisting essentially of (a) 50 to 95 wt% copolymer A containing 60 to 95 wt% vinyl acetate and 50 to 40 wt% ethylene, and (b) 5 to 50 wt% copolymer B containing 60 to 95 wt% vinyl acetate, 5 to 40 wt% ethylene and up to about 10 wt% crosslinking mono-olefinically unsaturated monomer.
Claim 9
Dependent Claim 78 words
A nonwoven product comprising a web of fibers bonded together with a binder deposited from an emulsion composition comprising an aqueous dispersion of a mixture consisting essentially of (a) 50 to 95 wt% copolymer A containing 60 to 95 wt% vinyl acetate and 50 to 40 wt% ethylene, and (b) 5 to 50 wt% copolymer B containing 60 to 95 wt% vinyl acetate, 5 to 40 wt% ethylene and up to about 10 wt% crosslinking mono-olefinically unsaturated monomer.
Claim 10
Dependent Claim 26 words
The nonwoven product of claim 7 in which the mixture consists essentially of 65 to 90 wt% copolymer A and 10 to 35 wt% copolymer B.
Claim 11
Dependent Claim 59 words
The nonwoven product of claim 7 in which the vinyl acetate content is 75 to 85 wt% and the ethylene content is 15 to 25 wt% in copolymer A and the vinyl acetate is 70 to 80 wt%, the ethylene is 15 to 25 wt%, and the crosslinking mono-olefinically unsaturated monomer is 4 to 8 wt% of copolymer B.
Claim 12
Dependent Claim 59 words
The nonwoven product of claim 8 in which the vinyl acetate content is 75 to 85 wt% and the ethylene content is 15 to 25 wt% in copolymer A and the vinyl acetate is 70 to 80 wt%, the ethylene is 15 to 25 wt%, and the crosslinking mono-olefinically unsaturated monomer is 4 to 8 wt% of copolymer B.
Claim 13
Dependent Claim 33 words
The nonwoven product of claim 7 in which the crosslinking mono-olefinically unsaturated monomer is N-methylol acrylamide, N-methylol methacrylamide, the lower alkyl ethers of N-methylol acrylamide or N-methylol methacrylamide, acrylamide, methacrylamide, or acrylic acid.
Claim 14
Dependent Claim 16 words
The nonwoven product of claim 10 in which the crosslinking olefinically unsaturated monomer is 4-6 wt%.
Claim 15
Dependent Claim 75 words
An emulsion composition providing a binder having good wet tensile strength and heat sealability for nonwoven products comprising an aqueous dispersion of a mixture consisting essentially of (a) 50 to 95 wt% copolymer A containing 60 to 95 wt% vinyl acetate and 5 to 40 wt% ethylene, and (b) 5 to 50 wt% copolymer B containing 60 to 95 wt% vinyl acetate, 5 to 40 wt% ethylene and up to about 10 wt% N-methylol acrylamide.
Claim 16
Dependent Claim 75 words
An emulsion composition providing a binder having good wet tensile strength and heat sealability for nonwoven products comprising an aqueous dispersion of a mixture consisting essentially of (a) 50 to 95 wt% copolymer A containing 60 to 95 wt% vinyl acetate and 5 to 40 wt% ethylene, and (b) 5 to 50 wt% copolymer B containing 60 to 95 wt% vinyl acetate, 5 to 40 wt% ethylene and up to about 10 wt% N-methylol acrylamide.
Claim 17
Dependent Claim 25 words
The composition of claim 13 in which the mixture consists essentially of 65 to 90 wt% copolymer A and 10 to 35 wt% copolymer B.
Claim 18
Dependent Claim 53 words
The composition of claim 14 in which the vinyl acetate is 75 to 85 wt% and the ethylene is 15 to 25 wt% in copolymer A and the vinyl acetate is 70 to 80 wt%, ethylene is 15 to 25 wt% and the N-methylol acrylamide is 4 to 6 wt% of copolymer B.
Claim 19
Dependent Claim 53 words
The composition of claim 13 in which the vinyl acetate is 75 to 85 wt% and the ethylene is 15 to 25 wt% in copolymer A and the vinyl acetate is 70 to 80 wt%, ethylene is 15 to 25 wt% and the N-methylol acrylamide is 4 to 6 wt% of copolymer B.
Claim 20
Dependent Claim 20 words
A nonwoven product comprising a web of fibers bonded together with a binder deposited from the emulsion of claim 13.
Claim 21
Dependent Claim 20 words
A nonwoven product comprising a web of fibers bonded together with a binder deposited from the emulsion of claim 14.
Claim 22
Dependent Claim 20 words
A nonwoven product comprising a web of fibers bonded together with a binder deposited from the emulsion of claim 15.
Claim 23
Dependent Claim 20 words
A nonwoven product comprising a web of fibers bonded together with a binder deposited from the emulsion of claim 16.

References Cited (Backward Citations)

US3222419A Cited
US3671382A Cited
US4075387A Cited
US4332850A Cited

USPTO Annuity & Maintenance Windows

Annuity Stage Window Opens Payment Deadline Surcharge Period Until Estimated Fee Status
3.5 Years (Year 4) 1987-11-06 1988-05-07 1988-11-06 $2000.00 Window Closed / Lapsed
7.5 Years (Year 8) 1991-11-06 1992-05-07 1992-11-06 $3760.00 Window Closed / Lapsed
11.5 Years (Year 12) 1995-11-06 1996-05-07 1996-11-06 $7700.00 Window Closed / Lapsed

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