US4332850A
Expired / Lapsed
US
⏱️ 0.0 years remaining
Vinyl acetate-ethylene emulsions for nonwoven goods
Assignee: Air Products and Chemicals Inc
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Filing: 1981-05-26
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Granted: 1982-06-01
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Expires: 2001-05-26
Abstract
Abstract This invention relates to a vinyl acetate-ethylene copolymer containing emulsion particularly adapted for the preparation of nonwoven goods. The vinyl acetate-ethylene emulsion is prepared by an improved process for producing an aqueous emulsion suitably adapted for producing non-woven goods said emulsion containing a vinyl acetate-ethylene copolymer wherein said copolymer contains from about 75-96% by weight of vinyl acetate. It is produced by forming an aqueous suspension of vinyl acetate, ethylene, and stabilizer, initiating the polymerization of the reaction mixture by the addition of catalysts, and adding from about 0.5-10% by weight of the vinyl acetate of a crosslinkable monomer. The improvement for enhancing the absorptivity of the copolymer comprises: pressurizing the reactor with ethylene to an initial ethylene equilibrium pressure of from about 100 to 1,000 psig; initiating the reaction mixture by the addition of catalyst at a temperature from about 10°-35° C. and bringing the reaction mixture to a reaction temperature of from 45°-85° C. and operating pressure within a period of not more than 2 hours and the reaction temperature exceeds the initiation temperature by at least 20° C.; adding the crosslinkable monomer at a substantially uniform rate such that the major portion of monomer has been added by the time the vinyl acetate content in the emulsion has been reduced to a level of from 3-25% by weight of the emulsion; and continuing polymerization of the reaction mixture until the vinyl acetate content in said emulsion is reduced below about 1% by weight.
Inventors
- 👤 John G. Iacoviello
Bibliographic Details
Application Number
—
Jurisdiction
US
Data Source
google_patents
Last Synchronized
2026-11-07 21:23
CPC Classifications
C; C08; C08F; C08F218/00; C08F218/02; C08F218/04; C08F218/08; D; D04; D04H; D04H1/00; D04H1/40; D04H1/58; D04H1/587; D04H1/64; Y; Y10; Y10T; Y10T442/00; Y10T442/20; Y10T442/2484
Claims Analysis
Total Claims: 14
Claim 1
Independent Claim
254 words
In a process for producing an aqueous emulsion suitably adapted for producing non-woven goods said emulsion containing a vinyl acetate-ethylene copolymer wherein said copolymer contains from about 60-96% by weight of vinyl acetete and is produced by (a) forming an aqueous suspension of vinyl acetate, ethylene, and stabilizer, (b) pressurizing the reactor with ethylene to form a vinyl acetate-ethylene raction mixture, (c) initiating the polymerizaton of the reaction mixture by the addition of catalyst, incrementally adding a crosslinkable monomer in a proportion of the 0.5-10% by weight of the copolymer, and (d) carrying out said polymerization at a temperature from 45°-85° C. of 10-100 atmospheres, the improvement for enhancing the absorptive properties of said copolymer which comprises: pressurizing the reactor with ethylene to an initial ethylene equilibrium pressure of from about 100 to 1,000 psig; initiating the reaction mixture by the addition of catalyst at a temperature from about 10°-35° C. and bringing the reaction mixture to a reaction temperature of from 45°-85° C. and operating pressure within a period of not more than 2 hours and the reaction temperature exceeds the initiation temperature by at least 20° C.; adding the crosslinkable monomer at a substantially uniform rate such that the major portion of monomer has been added by the time the vinyl acetate content in the emulsion has been reduced to a level of from 3-25% by weight of the emulsion; and continuing polymerization of the reaction mixture until the vinyl acetate content in said emulsion is reduced below about 1% by weight.
Claim 2
Dependent Claim
254 words
In a process for producing an aqueous emulsion suitably adapted for producing non-woven goods said emulsion containing a vinyl acetate-ethylene copolymer wherein said copolymer contains from about 60-96% by weight of vinyl acetete and is produced by (a) forming an aqueous suspension of vinyl acetate, ethylene, and stabilizer, (b) pressurizing the reactor with ethylene to form a vinyl acetate-ethylene raction mixture, (c) initiating the polymerizaton of the reaction mixture by the addition of catalyst, incrementally adding a crosslinkable monomer in a proportion of the 0.5-10% by weight of the copolymer, and (d) carrying out said polymerization at a temperature from 45°-85° C. of 10-100 atmospheres, the improvement for enhancing the absorptive properties of said copolymer which comprises: pressurizing the reactor with ethylene to an initial ethylene equilibrium pressure of from about 100 to 1,000 psig; initiating the reaction mixture by the addition of catalyst at a temperature from about 10°-35° C. and bringing the reaction mixture to a reaction temperature of from 45°-85° C. and operating pressure within a period of not more than 2 hours and the reaction temperature exceeds the initiation temperature by at least 20° C.; adding the crosslinkable monomer at a substantially uniform rate such that the major portion of monomer has been added by the time the vinyl acetate content in the emulsion has been reduced to a level of from 3-25% by weight of the emulsion; and continuing polymerization of the reaction mixture until the vinyl acetate content in said emulsion is reduced below about 1% by weight.
Claim 3
Dependent Claim
54 words
The process of claim 1 wherein said crosslinkable monomer is selected from the group consisting of N-methylol amides of acrylic and methacrylic acid; acrylic and methacrylic acid, unsaturated dicarboxylic acids, crotonic acid glycidyl esters of acrylic and methacrylic acid, allylcarbamate, acrylamide and the ethers of the amides of acrylic and methacrylic acid and allylcarbamate.
Claim 4
Dependent Claim
17 words
The process of claim 2 wherein said reaction pressure prior to initiation is from about 400-750 psig.
Claim 5
Dependent Claim
19 words
The process of claim 3 wherein said reactor temperature at the time of initiation is from about 20°-30° C.
Claim 6
Dependent Claim
38 words
The process of claim 4 wherein said crosslinkable monomer is added at a substantially uniform rate during the polymerization and said monomer addition is complete when the vinyl acetate content in the emulsion is from 3-8% by weight.
Claim 7
Dependent Claim
19 words
The process of claim 4 wherein said stabilizer is an anionic surfactant, or anionic-nonionic mixture or protective colloid-nonionic mixture.
Claim 8
Dependent Claim
251 words
A nonwoven fabric formed from a loosely assembled web of fibers bonded together with a vinyl acetate-ethylene copolymer wherein said copolymer formed by an improved process for producing an aqueous emulsion suitably adapted for producing non-woven goods said emulsion containing about 60-96% by weight of vinyl acetate and produced by forming an aqueous suspension comprising vinyl acetate, and stabilizer, charging said suspension to a reactor, pressurizing the reactor with ethylene to form a reaction mixture initiating the polymerization of the reaction mixture by the addition of a catalyst, and adding from about 0.5-10% by weight of the vinyl acetate of a cross-linkable monomer, the improvement for enhancing the properties of said emulsion which comprises: pressurizing the reactor with ethylene to an initial ethylene equilibrium pressure of from about 100 to 1,000 psig; initiating the reaction mixture by the addition of catalyst at a temperature from about 10°-35° C. and bringing the reaction mixture to a reaction temperature of from 45°-85° C. and operating pressure within a period of not more than 2 hours and the reaction temperature exceeds the initiation temperature by at least 20° C.; adding the crosslinkable monomer at a substantially uniform rate such that the major portion of monomer has been added by the time the vinyl acetate content in the emulsion has been reduced to a level of from 3-25% by weight of the emulsion; and continuing polymerization of the reaction mixture until the vinyl acetate content in said emulsion is reduced below about 1% by weight.
Claim 9
Dependent Claim
251 words
A nonwoven fabric formed from a loosely assembled web of fibers bonded together with a vinyl acetate-ethylene copolymer wherein said copolymer formed by an improved process for producing an aqueous emulsion suitably adapted for producing non-woven goods said emulsion containing about 60-96% by weight of vinyl acetate and produced by forming an aqueous suspension comprising vinyl acetate, and stabilizer, charging said suspension to a reactor, pressurizing the reactor with ethylene to form a reaction mixture initiating the polymerization of the reaction mixture by the addition of a catalyst, and adding from about 0.5-10% by weight of the vinyl acetate of a cross-linkable monomer, the improvement for enhancing the properties of said emulsion which comprises: pressurizing the reactor with ethylene to an initial ethylene equilibrium pressure of from about 100 to 1,000 psig; initiating the reaction mixture by the addition of catalyst at a temperature from about 10°-35° C. and bringing the reaction mixture to a reaction temperature of from 45°-85° C. and operating pressure within a period of not more than 2 hours and the reaction temperature exceeds the initiation temperature by at least 20° C.; adding the crosslinkable monomer at a substantially uniform rate such that the major portion of monomer has been added by the time the vinyl acetate content in the emulsion has been reduced to a level of from 3-25% by weight of the emulsion; and continuing polymerization of the reaction mixture until the vinyl acetate content in said emulsion is reduced below about 1% by weight.
Claim 10
Dependent Claim
54 words
The process of claim 7 wherein said crosslinkable monomer is selected from the group consisting of N-methylol amides of acrylic and methacrylic acid; acrylic and methacrylic acid, unsaturated dicarboxylic acids, crotonic acid glycidyl esters of acrylic and methacrylic acid, allylcarbamate, acrylamide and the ethers of the amides of acrylic and methacrylic acid and allylcarbamate.
Claim 11
Dependent Claim
17 words
The process of claim 8 wherein said reaction pressure prior to initiation is from about 400-750 psig.
Claim 12
Dependent Claim
19 words
The process of claim 9 wherein said reaction temperature at the time of initiation is from about 20°-30° C.
Claim 13
Dependent Claim
38 words
The process of claim 10 wherein said crosslinkable monomer is added at a substantially uniform rate during the polymerization and said monomer addition is complete when the vinyl acetate content in the emulsion is from 3-8% by weight.
Claim 14
Dependent Claim
26 words
The process of claim 11 wherein said stabilizer is an anionic surfactant, or mixture of anionic±nonionic surfactant or a mixture of protective colloid and nonionic surfactant.
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USPTO Annuity & Maintenance Windows
| Annuity Stage | Window Opens | Payment Deadline | Surcharge Period Until | Estimated Fee | Status |
|---|---|---|---|---|---|
| 3.5 Years (Year 4) | 1985-05-31 | 1985-11-30 | 1986-06-01 | $2000.00 | Window Closed / Lapsed |
| 7.5 Years (Year 8) | 1989-05-31 | 1989-11-30 | 1990-06-01 | $3760.00 | Window Closed / Lapsed |
| 11.5 Years (Year 12) | 1993-05-31 | 1993-11-30 | 1994-06-01 | $7700.00 | Window Closed / Lapsed |