US4481180A
Expired / Lapsed
US
⏱️ 0.0 years remaining
Diamond synthesis process
Assignee: Commissariat à l'Énergie Atomique et Aux Énergies Alternatives
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Filing: 1983-02-09
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Granted: 1984-11-06
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Expires: 2003-02-09
Abstract
Abstract The present invention relates to a diamond synthesis process. A stack of graphite and alloy pellets of at least one metal of group VIII or VII of the periodic system with an element having the same crystallographic structure as the diamond are placed in an enclosure. The pressure and temperature are raised so that the alloy starts to liquefy. Part of the element remains in the state of solid particles used in the nucleation by epitaxy of the diamond crystals. The carbon migrates through the liquid alloy from the pellets to the solid particles.
Inventors
- 👤 Serge Bedere
- 👤 Jean-Phillippe Borgoltz
- 👤 Claude Moussin
Bibliographic Details
Application Number
—
Jurisdiction
US
Data Source
google_patents
Last Synchronized
2026-10-26 09:21
CPC Classifications
B; B01; B01J; B01J3/00; B01J3/06; B01J3/062; B01J2203/00; B01J2203/06; B01J2203/0605; B01J2203/061; B01J2203/065; B01J2203/0655; B01J2203/0675; B01J2203/068
Claims Analysis
Total Claims: 8
Claim 1
Independent Claim
171 words
A process for the synthesis of diamond, comprising: placing in a high pressure enclosure a stack of graphite pellets and a catalyst material, wherein said catalyst material is a eutectic alloy of at least one metal of group VII or VIII of the periodic system with an element having the same crystallographic structure as the diamond selected from the group consisting of germanium and silicon; increasing the pressure in the enclosure to a pressure ranging from 30 to 60 kilobars and then the temperature to within the range of 800° C. to 1200° C. until the alloy starts to liquefy, at least part of the said element being in the form of solid particles within the liquid mass; maintaining the temperature and pressure conditions for a sufficient time for the graphite to be changed into diamond, the carbon migrating through the liquefied alloy from the pellets to the aforementioned solid particles on which it is deposited and crystallized by epitaxy in the diamond system; and then returning to the initial conditions.
Claim 2
Dependent Claim
171 words
A process for the synthesis of diamond, comprising: placing in a high pressure enclosure a stack of graphite pellets and a catalyst material, wherein said catalyst material is a eutectic alloy of at least one metal of group VII or VIII of the periodic system with an element having the same crystallographic structure as the diamond selected from the group consisting of germanium and silicon; increasing the pressure in the enclosure to a pressure ranging from 30 to 60 kilobars and then the temperature to within the range of 800° C. to 1200° C. until the alloy starts to liquefy, at least part of the said element being in the form of solid particles within the liquid mass; maintaining the temperature and pressure conditions for a sufficient time for the graphite to be changed into diamond, the carbon migrating through the liquefied alloy from the pellets to the aforementioned solid particles on which it is deposited and crystallized by epitaxy in the diamond system; and then returning to the initial conditions.
Claim 3
Dependent Claim
20 words
A process according to claim 1, wherein the graphite and/or alloy is in the form of a previously compacted powder.
Claim 4
Dependent Claim
47 words
A process according to claim 1, wherein the alloy is a ternary or quaternary alloy which also comprises, in addition to the element having the same crystallographic structure as the diamond, at least two metals selected from the group consisting of iron, cobalt, nickel, manganese and platinum.
Claim 5
Dependent Claim
19 words
A process according to claim 1, wherein the pressure rise takes place at a rate of approximately 0.4 kilobars/minute.
Claim 6
Dependent Claim
20 words
A process according to claim 1, wherein the temperature rise takes place at a rate between 10° and 150° C./minute.
Claim 7
Dependent Claim
20 words
A process according to claim 1 wherein the pressure and temperature maintainance time is between 3 minutes and 2 hours.
Claim 8
Dependent Claim
18 words
The process according to claim 5, wherein the temperature rise takes place at a rate of 60° C./minute.
References Cited (Backward Citations)
US2947609A
Cited
US2992900A
Cited
USPTO Annuity & Maintenance Windows
| Annuity Stage | Window Opens | Payment Deadline | Surcharge Period Until | Estimated Fee | Status |
|---|---|---|---|---|---|
| 3.5 Years (Year 4) | 1987-11-06 | 1988-05-07 | 1988-11-06 | $2000.00 | Window Closed / Lapsed |
| 7.5 Years (Year 8) | 1991-11-06 | 1992-05-07 | 1992-11-06 | $3760.00 | Window Closed / Lapsed |
| 11.5 Years (Year 12) | 1995-11-06 | 1996-05-07 | 1996-11-06 | $7700.00 | Window Closed / Lapsed |