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US4480057A
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Impact-resistant poly(phenylene oxide) compositions comprising encapsulated filler material
Assignee: Mitsubishi Chemical Corp
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Filing: 1982-12-14
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Granted: 1984-10-30
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Expires: 2002-12-14
Abstract
Abstract A poly(phenylene oxide) (PPO) composition which comprises a matrix of PPO or a blend of PPO and a styrene-based polymer and a dispersed phase whose principal component is a crystalline olefin polymer surrounded by a crystalline hydrogenated styrene-conjugated diene copolymer or hydrogenated styrene-conjugated diene copolymer, said dispersed phase being filled with an inorganic filler. This composition is superior in rigidity and impact resistance.
Inventors
- 👤 Hironari Sano
Bibliographic Details
Application Number
—
Jurisdiction
US
Data Source
google_patents
Last Synchronized
2026-10-27 14:33
CPC Classifications
C; C08; C08L; C08L51/00; C08L51/06; C08K; C08K9/00; C08K9/08; C08K9/10; C08L53/00; C08L53/02; C08L71/00; C08L71/08; C08L71/10; C08L71/12; C08L71/123
Claims Analysis
Total Claims: 13
Claim 1
Independent Claim
230 words
An impact-resistant poly(phenylene oxide) composition comprising: (a) a matrix comprising poly(phenylene oxide) or a mixture of poly(phenylene oxide) and a styrene-based polymer, which is a polymer having at least 25 mol % of the polymer units derived from a compound having the formula: ##STR3## wherein R is hydrogen, a lower alkyl group, or a halogen, and Z is hydrogen, a lower alkyl group, chlorine, or vinyl and p is an integer from 1 to 5, and (b) dispersed in said matrix, a dispersed phase comprising a synthetic resin and a particulate inorganic filler, said synthetic resin dispersed phase substantially completely surrounding said each filler particle or aggregate thereof and being selected from the group consisting of (i) a crystalline olefin polymer phase comprising a functional derivative of a crystalline olefin polymer containing functional groups having an affinity for both said inorganic filler and a blend of said functional derivative of a crystalline olefin polymer with an underivatized crystalline olefin polymer, and, interposed between said crystalline olefin polymer phase and said matrix, a crystalline or elastomeric hydrogenated styrene-conjugated diene polymer, and (ii) a crystalline hydrogenated styrene-conjugated diene polymer phase comprising a functional derivative of a hydrogenated styrene-conjugated diene polymer containing functional groups having an affinity for both said inorganic filler and a blend of said functional derivative of a hydrogenated styrene-conjugated diene polymer with an underivatized crystalline hydrogenated styrene-conjugated diene polymer.
Claim 2
Dependent Claim
230 words
An impact-resistant poly(phenylene oxide) composition comprising: (a) a matrix comprising poly(phenylene oxide) or a mixture of poly(phenylene oxide) and a styrene-based polymer, which is a polymer having at least 25 mol % of the polymer units derived from a compound having the formula: ##STR3## wherein R is hydrogen, a lower alkyl group, or a halogen, and Z is hydrogen, a lower alkyl group, chlorine, or vinyl and p is an integer from 1 to 5, and (b) dispersed in said matrix, a dispersed phase comprising a synthetic resin and a particulate inorganic filler, said synthetic resin dispersed phase substantially completely surrounding said each filler particle or aggregate thereof and being selected from the group consisting of (i) a crystalline olefin polymer phase comprising a functional derivative of a crystalline olefin polymer containing functional groups having an affinity for both said inorganic filler and a blend of said functional derivative of a crystalline olefin polymer with an underivatized crystalline olefin polymer, and, interposed between said crystalline olefin polymer phase and said matrix, a crystalline or elastomeric hydrogenated styrene-conjugated diene polymer, and (ii) a crystalline hydrogenated styrene-conjugated diene polymer phase comprising a functional derivative of a hydrogenated styrene-conjugated diene polymer containing functional groups having an affinity for both said inorganic filler and a blend of said functional derivative of a hydrogenated styrene-conjugated diene polymer with an underivatized crystalline hydrogenated styrene-conjugated diene polymer.
Claim 3
Dependent Claim
52 words
The composition of claim 1, wherein said poly(phenylene oxide) comprises 17 to 97 wt%, said styrene-based polymer comprises 0 to 80 wt%, said resin forming the dispersed phase comprises 0.5 to 50 wt%, and said inorganic filler comprises 1 to 60 wt% based on the total weight of the poly(phenylene oxide) composition.
Claim 4
Dependent Claim
52 words
The composition of claim 1, wherein said poly(phenylene oxide) comprises 22 to 90 wt%, said styrene-based polymer comprises 5 to 73 wt%, said resin forming the dispersed phase comprises 1.0 to 45 wt%, and said inorganic filler comprises 2.0 to 55 wt% based on the total weight of said poly(phenylene oxide) composition.
Claim 5
Dependent Claim
52 words
The composition of claim 1, wherein said poly(phenylene oxide) comprises 30 to 80 wt%, said styrene-based polymer comprises 10 to 60 wt%, said resin forming the dispersed phase comprises 2.0 to 40 wt%, and said inorganic filler comprises 3.0 to 45 wt% based on the total weight of the poly(phenylene oxide) composition.
Claim 6
Dependent Claim
44 words
The composition of claim 1, wherein said resin forming the dispersed phase comprises 20 to 97 wt% of said crystalline olefin polymer phase and 80 to 3 wt% of said hydrogenated styrene-conjugated diene copolymer interposed between said crystalline olefin polymer phase and said matrix.
Claim 7
Dependent Claim
75 words
The composition of claim 1, wherein said crystalline olefin polymer phase is a blend comprising 2 to 95 wt% of said functional derivative of a crystalline olefin polymer and 2 to 93 wt% of said underivatized crystalline olefin polymer based on the total quantity of said crystalline olefin polymer phase, said blend having a degree of crystallinity greater than 30 wt%, and 3 to 80 wt% of a hydrogenated styrene-conjugated diene copolymer surrounding said mixture.
Claim 8
Dependent Claim
63 words
The composition of claim 1, wherein said crystalline hydrogenated styrene-conjugated diene polymer phase comprises 5 to 95 wt% of a functional derivative of hydrogenated styrene-conjugated diene copolymer and 95 to 5 wt% of an underivatized crystalline hydrogenated styrene-conjugated diene copolymer based on the total quantity of said crystalline hydrogenated styrene-conjugated diene polymer phase, and has a degree of crystallinity greater than 5 wt%.
Claim 9
Dependent Claim
37 words
The composition of claim 6, wherein said functional derivative of a crystalline olefin polymer is a crystalline copolymer of an olefin and an unsaturated carboxylic acid or anhydride thereof and contains 0.25 to 25 wt% of --COOH.
Claim 10
Dependent Claim
34 words
The composition of claim 6, wherein said functional derivative of a crystalline olefin polymer is a crystalline copolymer of an olefin and an unsaturated organosilane compound and contains 0.05 to 5 wt% of Si.
Claim 11
Dependent Claim
41 words
The composition of claim 7, wherein said functional derivative of a hydrogenated styrene-conjugated diene copolymer is a hydrogenated styrene-conjugated diene copolymer in which an unsaturated carboxylic acid or anhydride thereof is copolymerized, said copolymer containing 0.25 to 25 wt% of --COOH.
Claim 12
Dependent Claim
38 words
The composition of claim 7, wherein said functional derivative of a hydrogenated styrene-conjugated diene copolymer is a hydrogenated styrene-conjugated diene copolymer in which an unsaturated organosilane compound is copolymerized, said copolymer containing 0.05 to 5 wt% of Si.
Claim 13
Dependent Claim
18 words
The composition of claim 1, wherein the inorganic filler has an average particle diameter smaller than 2 microns.
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USPTO Annuity & Maintenance Windows
| Annuity Stage | Window Opens | Payment Deadline | Surcharge Period Until | Estimated Fee | Status |
|---|---|---|---|---|---|
| 3.5 Years (Year 4) | 1987-10-30 | 1988-04-30 | 1988-10-30 | $2000.00 | Window Closed / Lapsed |
| 7.5 Years (Year 8) | 1991-10-30 | 1992-04-30 | 1992-10-30 | $3760.00 | Window Closed / Lapsed |
| 11.5 Years (Year 12) | 1995-10-30 | 1996-04-30 | 1996-10-30 | $7700.00 | Window Closed / Lapsed |