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US4478903A Expired / Lapsed US ⏱️ 0.0 years remaining

Composite plastics sheet having conductive surface

Assignee: Denka Co Ltd
•
Filing: 1982-05-18
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Granted: 1984-10-23
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Expires: 2002-05-18
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Abstract

Abstract A composite plastics sheet made of a polystyrene base resin or an ABS base resin is provided. The composite plastics sheet has a conductive covering layer laminated by co-extrusion on the face of the substrate sheet. The material for the conductive covering layer is made of a polystyrene base resin or an ABS base resin and mixed with a conductive carbon black material, such as furnace black or channel black, in an amount such that the flow index at the extrusion step thereof at 200° C. and under a loading of 5 kg is not lower than 0.1 g/10 min and such that the surface specific resistance of the resultant mixture is not more than 10 10 ohms.

Inventors

  • 👤 Kozi Kishida
  • 👤 Noboru Iwato
  • 👤 Yuji Ozeki

Bibliographic Details

Application Number —
Jurisdiction US
Data Source google_patents
Last Synchronized 2026-11-08 03:21
CPC Classifications
B; B32; B32B; B32B27/00; B32B27/30; B32B27/06; B32B27/08; B32B27/18; B32B27/302; B32B27/308; B32B27/32; B32B2250/00; B32B2250/40; B32B2270/00; B32B2307/00; B32B2307/20; B32B2307/202; B32B2307/70; B32B2307/718; B32B2310/00; B32B2310/021; B32B2310/022; B32B2355/00; B32B2355/02; B32B2553/00; Y; Y10; Y10T; Y10T428/00; Y10T428/13; Y10T428/1352; Y10T428/1386; Y10T428/24; Y10T428/24942; Y10T428/2495; Y10T428/24967; Y10T428/24975; Y10T428/31504; Y10T428/31855; Y10T428/31931; Y10T428/31935

Claims Analysis

Total Claims: 16
Claim 1
Independent Claim 199 words
A composite plastics sheet having a conductive surface, comprising a substrate sheet made of a resin selected from the group consisting of a polystyrene base resin and an ABS base resin, and a conductive surface layer made of a resin selected from the group consisting of a polystyrene base resin and an ABS base resin, said conductive surface layer containing 5 to 50%, by weight, of carbon black and having a specific surface resistance of not more than 10 10 ohms, said conductive surface layer being laminated on one or both surfaces of said substrate sheet by co-extrusion, said polystyrene base resin being selected from the group consisting of high impact strength polystyrenes, a blended polystyrene base resin, and mixtures thereof, said polystyrene base resin and said ABS base resin for the conductive surface layer after being compounded with carbon black each having a melt flow index of not less than 0.1 g/10 min. at 200° C. and under the loading of 5 kg, the total thickness of said composite plastics sheet being from 0.1 to 3.0 mm, the thickness of said conductive surface layer ranging from 2% and 70% of said total thickness of the composition plastics sheet.
Claim 2
Dependent Claim 199 words
A composite plastics sheet having a conductive surface, comprising a substrate sheet made of a resin selected from the group consisting of a polystyrene base resin and an ABS base resin, and a conductive surface layer made of a resin selected from the group consisting of a polystyrene base resin and an ABS base resin, said conductive surface layer containing 5 to 50%, by weight, of carbon black and having a specific surface resistance of not more than 10 10 ohms, said conductive surface layer being laminated on one or both surfaces of said substrate sheet by co-extrusion, said polystyrene base resin being selected from the group consisting of high impact strength polystyrenes, a blended polystyrene base resin, and mixtures thereof, said polystyrene base resin and said ABS base resin for the conductive surface layer after being compounded with carbon black each having a melt flow index of not less than 0.1 g/10 min. at 200° C. and under the loading of 5 kg, the total thickness of said composite plastics sheet being from 0.1 to 3.0 mm, the thickness of said conductive surface layer ranging from 2% and 70% of said total thickness of the composition plastics sheet.
Claim 3
Dependent Claim 30 words
The composite plastics sheet as claimed in claim 1, wherein said high impact strength polystyrene is a graft polymer in which styrene is graft polymerized with rubber-like polymers of dienes.
Claim 4
Dependent Claim 33 words
The composite plastics sheet as claimed in claim 2 wherein said diene is a homopolymer of a conjugated diene monomer selected from the group consisting of butadiene, isoprene, dimethylbutadiene, cyclopentadiene, chloroprene and cyanoprene.
Claim 5
Dependent Claim 44 words
The composite plastics sheet as claimed in claim 1, wherein the blended polystyrene base resin is a polystyrene base resin blended with a resin selected from the group consisting of copolymers of styrene, rubber-like polymers of dienes, polymers of olefins and copolymers of olefins.
Claim 6
Dependent Claim 53 words
The composite plastics sheet as claimed in claim 4, wherein said resin blended with the polystyrene base resin is selected from the group consisting of styrene-butadiene block copolymer, styrene-butadiene random copolymer, styrene-isoprene block copolymer, polybutadiene, polyisoprene, dimethylbutadiene polymer, polymers of cyclopentadiene, polychloroprene, polycyanoprene, polyethylene, polypropylene, polybutene, ethylene-propylene copolymer, ethylene-butene copolymer and propylene-butene copolymer.
Claim 7
Dependent Claim 32 words
The composite plastics sheet as claimed in claim 1, wherein the ABS base resin is a graft copolymer containing a rubber-like polymer of dienes, an aromatic vinyl compound and an acrylic monomer.
Claim 8
Dependent Claim 56 words
The composite plastics sheet as claimed in claim 6, wherein said rubber-like polymer of dienes is a homopolymer of conjugated diene monomer selected from the group consisting of butadiene, isoprene, dimethylbutadiene, cyclopentadiene, chloroprene and cyanoprene and a copolymer thereof with a coplymerizable monomer selected from the group consisting of styrene, acrylonitrile, methylmethacrylate, ethylacrylate, isobutylene and 1-butene.
Claim 9
Dependent Claim 28 words
The composite plastics sheet as claimed in claim 6, wherein the aromatic vinyl compound is selected from the group consisting of styrene, α -methylstyrene, vinyltoluene, chlorostyrene and tert-butylstyrene.
Claim 10
Dependent Claim 27 words
The composite plastics sheet as claimed in claim 6, wherein said acrylic monomer is selected from the group consisting of acrylonitrile, methacrylonitrile, methylacrylate, methylmethacrylate, ethylacrylate and butylacrylate.
Claim 11
Dependent Claim 24 words
The composite plastics sheet as claimed in claim 6, wherein the ABS base resin is an ABS base resin blended with an acrylonitrile-styrene copolymer.
Claim 12
Dependent Claim 49 words
The composite plastics sheet as claimed in claim 1, wherein an additive is admixed with said polystyrene base resin and an ABS base resin for the substrate sheet to bring the fluidity thereof closer to that of said polystyrene and said ABS base resin for the conductive surface layer.
Claim 13
Dependent Claim 27 words
The composite plastics sheet as claimed in claim 11, wherein said additive is selected from the group consisting of liquid paraffin, mineral oils, lubricants and mixtures thereof.
Claim 14
Dependent Claim 41 words
The composite plastics sheet as claimed in claim 1, wherein said polystyrene base resin and said ABS base resin for the conductive surface layer further includes one selected from the group consisting of liquid paraffin, mineral oils, lubricants, and mixtures thereof.
Claim 15
Dependent Claim 31 words
The composite plastics sheet as claimed in claim 1, wherein said carbon black is selected from the group consisting of furnace black, channel black, super conductive furnace, and electric conductive furnace.
Claim 16
Dependent Claim 20 words
The composite plastics sheet as claimed in claim 1, further comprising an internal conductive layer sandwiched by non-conductive substrate layers.

References Cited (Backward Citations)

US4009093A Cited
US4051298A Cited
US4101050A Cited

USPTO Annuity & Maintenance Windows

Annuity Stage Window Opens Payment Deadline Surcharge Period Until Estimated Fee Status
3.5 Years (Year 4) 1987-10-23 1988-04-23 1988-10-23 $2000.00 Window Closed / Lapsed
7.5 Years (Year 8) 1991-10-23 1992-04-23 1992-10-23 $3760.00 Window Closed / Lapsed
11.5 Years (Year 12) 1995-10-23 1996-04-23 1996-10-23 $7700.00 Window Closed / Lapsed

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