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US4477286A Expired / Lapsed US ⏱️ 0.0 years remaining

Breaking oil-in-water emulsions

Assignee: Henkel AG and Co KGaA
•
Filing: 1982-07-19
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Granted: 1984-10-16
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Expires: 2002-07-19
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Abstract

Abstract The invention relates to the use of 2,4,7,9-tetramethyl-5-decyne-4,7-diol for breaking oil-in-water emulsions and in regenerating used cleaning compositions by making it possible to remove emulsified oils therefrom.

Inventors

  • 👤 Christian Rossmann
  • 👤 Wolfgang Riedel

Bibliographic Details

Application Number —
Jurisdiction US
Data Source google_patents
Last Synchronized 2026-11-08 22:44
CPC Classifications
B; B01; B01D; B01D17/00; B01D17/02; B01D17/04; B01D17/047; C; C23; C23G; C23G1/00; C23G1/36

Claims Analysis

Total Claims: 12
Claim 1
Independent Claim 21 words
A process for breaking oil-in-water emulsions which comprises adding an emulsion breaking effective amount of 2,4,7,9-tetramethyl-5-decyne-4,7-diol to an emulsion containing composition.
Claim 2
Dependent Claim 21 words
A process for breaking oil-in-water emulsions which comprises adding an emulsion breaking effective amount of 2,4,7,9-tetramethyl-5-decyne-4,7-diol to an emulsion containing composition.
Claim 3
Dependent Claim 16 words
A process as set forth in claim 1, wherein the 2,4,7,9-tetramethyl-5-decyne-4,7,-diol is added at room temperature.
Claim 4
Dependent Claim 17 words
A process as set forth in claim 1 wherein the process is carried out at elevated temperatures.
Claim 5
Dependent Claim 31 words
A process as set forth in claim 1 or 2 or 3 wherein the 2,4,7,9-tetramethyl-5-decyne-4,7-diol is added in an amount of about 0.5 to 50 g/l of the emulsion containing composition.
Claim 6
Dependent Claim 22 words
A process as set forth in claim 4, wherein the 2,4,7,9-tetramethyl-5-decyne-4,7-diol is added in an amount of about 0.5 to 5 g/l.
Claim 7
Dependent Claim 49 words
A process as set forth in claim 1 or 2 or 3 wherein the emulsion containing composition includes neutral to strongly alkaline cleaning solutions, emulsified petroleum oils or fixed oils or both and fats, the emulsion is broken, the oil 2,4,7,9-tetramethyl-5-decyne-4,7-diol layer is separated and the cleaning solution reused.
Claim 8
Dependent Claim 21 words
A process as set forth in claim 6 wherein the separated, regenerated cleaning solution has its depleted components replenished before reuse.
Claim 9
Dependent Claim 30 words
A process for causing an oil-in-water emulsion to form separate, aqueous and oily phases which comprises adding from about 0.5 to 50 g/l of 2,4,7,9-tetramethyl-5-decyne-4,7-diol to an oil-in-water emulsion-containing composition.
Claim 10
Dependent Claim 30 words
A process for causing an oil-in-water emulsion to form separate, aqueous and oily phases which comprises adding from about 0.5 to 50 g/l of 2,4,7,9-tetramethyl-5-decyne-4,7-diol to an oil-in-water emulsion-containing composition.
Claim 11
Dependent Claim 79 words
A process for regenerating an oil-in-water emulsion-containing cleaning composition which comprises the steps of: (a) adding from 0.5 to 50 g/l of 2,4,7,9-tetramethyl-5-decyne-4,7-diol to an emulsion-containing composition comprising (i) neutral to strongly alkaline cleaning solution, (ii) emulsified petroleum oils, fixed oils, or both, and (iii) fats to form separate, aqueous and oily phases, said oily phase containing the 2,4,7,9-tetramethyl-5-decyne-4,7-diol; (b) separating the oily phase from the aqueous phase; and (c) replenishing depleted cleaning solution components in the aqueous phase.
Claim 12
Dependent Claim 79 words
A process for regenerating an oil-in-water emulsion-containing cleaning composition which comprises the steps of: (a) adding from 0.5 to 50 g/l of 2,4,7,9-tetramethyl-5-decyne-4,7-diol to an emulsion-containing composition comprising (i) neutral to strongly alkaline cleaning solution, (ii) emulsified petroleum oils, fixed oils, or both, and (iii) fats to form separate, aqueous and oily phases, said oily phase containing the 2,4,7,9-tetramethyl-5-decyne-4,7-diol; (b) separating the oily phase from the aqueous phase; and (c) replenishing depleted cleaning solution components in the aqueous phase.

References Cited (Backward Citations)

US1980118A Cited
US2711978A Cited
US3819522A Cited
US4082867A Cited
US4153545A Cited
US4321146A Cited

USPTO Annuity & Maintenance Windows

Annuity Stage Window Opens Payment Deadline Surcharge Period Until Estimated Fee Status
3.5 Years (Year 4) 1987-10-16 1988-04-16 1988-10-16 $2000.00 Window Closed / Lapsed
7.5 Years (Year 8) 1991-10-16 1992-04-16 1992-10-16 $3760.00 Window Closed / Lapsed
11.5 Years (Year 12) 1995-10-16 1996-04-16 1996-10-16 $7700.00 Window Closed / Lapsed

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