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US4476323A Expired / Lapsed US ⏱️ 0.0 years remaining

Surface-active quaternary ammonium compounds for treatment of textiles and cellulosic materials

Assignee: Nouryon Surface Chemistry AB
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Filing: 1981-02-24
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Granted: 1984-10-09
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Expires: 2001-02-24
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Abstract

Abstract The invention relates to new surface-active quaternary ammonium compounds having the general formula: ##STR1## wherein: R 1 and R 2 are each hydrocarbon groups having from about twelve to about forty carbon atoms; R 3 and R 4 are selected from the group consisting of methyl, ethyl and hydroxyethyl; A is an oxyalkylene group derived from both ethylene oxide and propylene oxide, having a ratio of oxyethylene units to the total number of oxyalkylene groups within the range from about 1:6 to about 5:6; m is a number corresponding to the valence of X; n 1 and n 2 represent the average number of oxyalkylene units and are within the range from about 6 to about 30; and X is an anion. The compounds impart to the treated textiles and cellulosic materials a reduced tendency to retain an electrostatic charge and/or improved softness and/or reduced mechanical strength due to a reduction in interfiber bonding, and at the same time preserve good hydrophilic properties.

Inventors

  • 👤 Karl M. E. Hellsten
  • 👤 Jan G. Emanuelsson
  • 👤 Svante L. Wahlen
  • 👤 Axel I. Thebrin

Bibliographic Details

Application Number —
Jurisdiction US
Data Source google_patents
Last Synchronized 2026-11-04 16:45
CPC Classifications
D; D21; D21H; D21H17/00; D21H17/03; D21H17/05; D21H17/07; C; C09; C09K; C09K23/00; C09K23/16; C11; C11D; C11D1/00; C11D1/38; C11D1/62; D06; D06M; D06M13/00; D06M13/322; D06M13/372; D06M13/46; D06M13/463; D21C; D21C9/00; D21C9/001; D21C9/002; D21C9/005

Claims Analysis

Total Claims: 15
Claim 1
Independent Claim 117 words
Surface-active quaternary ammonium compounds having the general formula: ##STR12## wherein: R 1 and R 2 are each hydrocarbon groups having from about twelve to about forty carbon atoms; R 3 and R 4 are selected from the group consisting of methyl, ethyl and hydroxyethyl; A is an oxyalkylene group derived from both ethylene oxide and propylene oxide, having a ratio of oxyethylene units to the total number of oxyalkylene groups within the range from about 1:6 to about 5:6; m is a number corresponding to the valence of X; n 1 and n 2 represent the average number of oxyalkylene units and are within the range from about 6 to about 30; and X is an anion.
Claim 2
Dependent Claim 117 words
Surface-active quaternary ammonium compounds having the general formula: ##STR12## wherein: R 1 and R 2 are each hydrocarbon groups having from about twelve to about forty carbon atoms; R 3 and R 4 are selected from the group consisting of methyl, ethyl and hydroxyethyl; A is an oxyalkylene group derived from both ethylene oxide and propylene oxide, having a ratio of oxyethylene units to the total number of oxyalkylene groups within the range from about 1:6 to about 5:6; m is a number corresponding to the valence of X; n 1 and n 2 represent the average number of oxyalkylene units and are within the range from about 6 to about 30; and X is an anion.
Claim 3
Dependent Claim 14 words
Compounds according to claim 1 in which R 3 and R 4 are methyl.
Claim 4
Dependent Claim 32 words
Compounds according to claim 1 in which R 1 and R 2 are aliphatic hydrocarbon having from twelve to twenty-two carbon atoms, and n is within the range from 6 to 15.
Claim 5
Dependent Claim 32 words
Compounds according to claim 1 in which R 1 and R 2 are alkyl-substituted phenyl having from fourteen to thirty carbon atoms, and n is within the range from 8 to 25.
Claim 6
Dependent Claim 65 words
A process for the treatment of textiles and cellulosic materials to impart to the treated textiles and cellulosic materials a reduced tendency to retain an electrostatic charge and/or improved softness and/or reduced mechanical strength due to a reduction in interfiber bonding, and at the same time preserve good hydrophilic properties, which comprises applying to the textile or cellulosic material a compound according to claim 1.
Claim 7
Dependent Claim 15 words
A process according to claim 5 in which R 3 and R 4 are methyl.
Claim 8
Dependent Claim 33 words
A process according to claim 5 in which R 1 and R 2 are aliphatic hydrocarbon having from twelve to twenty-two carbon atoms, and n is within the range from 6 to 15.
Claim 9
Dependent Claim 33 words
A process according to claim 5 in which R 1 and R 2 are alkyl-substituted phenyl having from fourteen to thirty carbon atoms, and n is within the range from 8 to 25.
Claim 10
Dependent Claim 16 words
A process according to claim 5 in which the compound is applied as an aqueous solution.
Claim 11
Dependent Claim 28 words
A process according to claim 9 in which the concentration compound in the aqueous solution is within the range from 0.01 to 0.5 g per liter of solution.
Claim 12
Dependent Claim 31 words
A process according to claim 5 in which the compound is applied to the material as an aqueous solution containing from about 0.01 to about 25% by weight of the compound.
Claim 13
Dependent Claim 17 words
A process according to claim 5 in which the compound is applied to cellulosic material after bleaching.
Claim 14
Dependent Claim 33 words
A process according to claim 12 in which the compound is applied to material in the form of an aqueous solution having a concentration of 1 to 15% by weight of the compound.
Claim 15
Dependent Claim 14 words
A process according to claim 12 in which the cellulosic material is cellulose fluff.

References Cited (Backward Citations)

US3972855A Cited
US3919319A Cited
US4134970A Cited
US4144122A Cited
US4074970A Cited
US4240984A Cited
US4281196A Cited

USPTO Annuity & Maintenance Windows

Annuity Stage Window Opens Payment Deadline Surcharge Period Until Estimated Fee Status
3.5 Years (Year 4) 1987-10-09 1988-04-09 1988-10-09 $2000.00 Window Closed / Lapsed
7.5 Years (Year 8) 1991-10-09 1992-04-09 1992-10-09 $3760.00 Window Closed / Lapsed
11.5 Years (Year 12) 1995-10-09 1996-04-09 1996-10-09 $7700.00 Window Closed / Lapsed

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