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US4475983A Expired / Lapsed US ⏱️ 0.0 years remaining

Base metal composite electrical contact material

Assignee: Nokia Bell Labs
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Filing: 1982-09-03
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Granted: 1984-10-09
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Expires: 2002-09-03
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Abstract

Abstract A composite contact material for light-duty electrical contacts is formed by combining, typically by powder-metallurgical techniques, a matrix metal and particles of a conductive material that is typically harder and more corrosion resistant than the matrix metal, and by removing, in a differential material removal step, some of the matrix metal from a surface of the composite, thereby producing a "sandpaper" surface with a substantial number of the particles projecting by a substantial amount above the matrix metal surface. Typical matrix metals are copper, copper alloys, or nickel, and typical particle materials are metals such as Ru, Re, Os, and intermetallics, oxides, borides, nitrides, carbides, silicides, and phosphides of such metals as Al, Ti, Ni, Nb, Mo, Ru, Ta, W, Re, or Os. Particle size is typically between about 0.1 μm and 100 μm, preferably less than 10 μm, and the particle volume fraction is typically between about 1% and 50%, preferably between 5% and 30%. Any appropriate differential material removal method, including chemical, plasma, sputter, thermal, and electrolytic etching, can be used.

Inventors

  • 👤 Frank E. Bader
  • 👤 Martin L. Green

Bibliographic Details

Application Number —
Jurisdiction US
Data Source google_patents
Last Synchronized 2026-10-25 15:52
CPC Classifications
H; H01; H01H; H01H1/00; H01H1/02; H01H1/021; H01H1/025; C; C23; C23F; C23F1/00; C25; C25F; C25F3/00; C25F3/02; Y; Y10; Y10T; Y10T29/00; Y10T29/49; Y10T29/49002; Y10T29/49117; Y10T29/49204; Y10T29/49206; Y10T428/00; Y10T428/12; Y10T428/12014; Y10T428/12028; Y10T428/12063

Claims Analysis

Total Claims: 16
Claim 1
Independent Claim 157 words
Method for producing an article comprising an electrical contact comprising a composite material, the method comprising (a) forming the composite comprising a matrix metal and an electrically conducting particle material in particulate form, characterized in that (b) the matrix metal is a base metal and the particle material is harder and more corrosion resistant than the matrix metal and the oxides and sulfides of the matrix metal, (c) the particles of the particle material have an average diameter between about 0.1 μm and about 100 μm, and the volume fraction of particle material in the composite is between about 1% and about 50%, and the method further comprises (d) carrying out, subsequent to (a), a differential material removal step on at least one surface of the composite, with the removal rate of the matrix metal being greater than the removal rate of the particle material, thereby creating a "sandpaper" surface having particles projecting above the matrix surface.
Claim 2
Dependent Claim 157 words
Method for producing an article comprising an electrical contact comprising a composite material, the method comprising (a) forming the composite comprising a matrix metal and an electrically conducting particle material in particulate form, characterized in that (b) the matrix metal is a base metal and the particle material is harder and more corrosion resistant than the matrix metal and the oxides and sulfides of the matrix metal, (c) the particles of the particle material have an average diameter between about 0.1 μm and about 100 μm, and the volume fraction of particle material in the composite is between about 1% and about 50%, and the method further comprises (d) carrying out, subsequent to (a), a differential material removal step on at least one surface of the composite, with the removal rate of the matrix metal being greater than the removal rate of the particle material, thereby creating a "sandpaper" surface having particles projecting above the matrix surface.
Claim 3
Dependent Claim 27 words
Method of claim 1, wherein a substantial fraction of the projecting particles project above the matrix surface by at least about 25% of the average particle diameter.
Claim 4
Dependent Claim 17 words
Method of claim 2, wherein the composite is formed by a process comprising a powder metallurgical procedure.
Claim 5
Dependent Claim 21 words
Method of claim 3, wherein the base matrix metal is selected from the group consisting of copper, copper alloys, and nickel.
Claim 6
Dependent Claim 42 words
Method of claim 4, wherein the particle material is selected from the group consisting of the metals Ru, Re, and Os, and intermetallics, oxides, borides, nitrides, carbides, silicides, and phosphides of Al, Ti, Ni, Nb, Mo, Ru, Ta, W, Re, and Os.
Claim 7
Dependent Claim 17 words
Method of claim 5, wherein the particles have an average size not greater than about 10 μm.
Claim 8
Dependent Claim 20 words
Method of claim 6, wherein the volume fraction of particle material in the composite is between about 5% and 30%.
Claim 9
Dependent Claim 18 words
Method of claim 1, wherein the differential material removal step comprises contacting the surface with a reactive medium.
Claim 10
Dependent Claim 14 words
Method of claim 8, wherein the reactive medium is a liquid chemical etching medium.
Claim 11
Dependent Claim 13 words
Method of claim 8, wherein the reactive medium is a gaseous etching medium.
Claim 12
Dependent Claim 13 words
Method of claim 10, wherein the gaseous medium is at least partially ionized.
Claim 13
Dependent Claim 12 words
Method of claim 1, wherein the differential material removal step comprises sputtering.
Claim 14
Dependent Claim 13 words
Method of claim 1, wherein the differential material removal step comprises thermal etching.
Claim 15
Dependent Claim 15 words
Method of claim 1, wherein the differential material removal step comprises electrolytic etching or electropolishing.
Claim 16
Dependent Claim 35 words
Method of claim 7, wherein the matrix metal consists substantially of copper, the particle material consists substantially of ruthenium, and the differential material removal step comprises contacting the surface with a liquid chemical etching medium.

References Cited (Backward Citations)

US2504906A Cited
US3778257A Cited
US3841869A Cited
US3920452A Cited
NL8001555A Cited

USPTO Annuity & Maintenance Windows

Annuity Stage Window Opens Payment Deadline Surcharge Period Until Estimated Fee Status
3.5 Years (Year 4) 1987-10-09 1988-04-09 1988-10-09 $2000.00 Window Closed / Lapsed
7.5 Years (Year 8) 1991-10-09 1992-04-09 1992-10-09 $3760.00 Window Closed / Lapsed
11.5 Years (Year 12) 1995-10-09 1996-04-09 1996-10-09 $7700.00 Window Closed / Lapsed

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