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US4474857A Expired / Lapsed US ⏱️ 0.0 years remaining

Silicone resin coating composition containing an ultraviolet light absorbing agent

Assignee: General Electric Co
•
Filing: 1984-01-06
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Granted: 1984-10-02
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Expires: 2004-01-06
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Abstract

Abstract A silicone resin coating composition is provided which provides a tough, abrasion-resistant coating when applied to a solid substrate. The coating composition has a basic pH in the range of from 7.1-7.8 and is prepared by hydrolyzing an alkyltrialkoxysilane or aryltrialkoxysilane in an aqueous colloidal silica dispersion. A thickening agent and an ultraviolet light screening agent are added to the resultant hydrolysis product.

Inventors

  • 👤 Howard A. Vaughn, Jr.

Bibliographic Details

Application Number —
Jurisdiction US
Data Source google_patents
Last Synchronized 2026-11-02 10:13
CPC Classifications
C; C09; C09D; C09D183/00; C09D183/04; Y; Y10; Y10T; Y10T428/00; Y10T428/31504; Y10T428/31652; Y10T428/31663; Y10T428/31667; Y10T428/31844; Y10T428/31971

Claims Analysis

Total Claims: 15
Claim 1
Independent Claim 166 words
An article comprising a solid substrate having at least one surface coated with an aqueous coating composition comprising a dispersion of colloidal silica in an aliphatic alcohol-water solution of the partial condensate of a silanol of the formula RSi(OH) 3 , wherein R is selected from the group consisting of alkyl having from 1 to 3 carbon atoms and aryl, at least 70 weight percent of the silanol being CH 3 Si(OH) 3 , said composition containing 10 to 50 weight percent solids consisting essentially of 10 to 70 weight percent colloidal silica and 30 to 90 weight percent of the partial condensate, the composition further containing from about 0.1 to about 1.0 weight percent of a thickening agent selected from the group consisting of hydroxypropyl guar gum and hydroxypropyl cellulose and a small amount effective to prevent discoloration of the substrate of an ultraviolet light absorbing agent which is soluble in the coating composition, said composition having a pH of about 7.1 to about 7.8.
Claim 2
Dependent Claim 166 words
An article comprising a solid substrate having at least one surface coated with an aqueous coating composition comprising a dispersion of colloidal silica in an aliphatic alcohol-water solution of the partial condensate of a silanol of the formula RSi(OH) 3 , wherein R is selected from the group consisting of alkyl having from 1 to 3 carbon atoms and aryl, at least 70 weight percent of the silanol being CH 3 Si(OH) 3 , said composition containing 10 to 50 weight percent solids consisting essentially of 10 to 70 weight percent colloidal silica and 30 to 90 weight percent of the partial condensate, the composition further containing from about 0.1 to about 1.0 weight percent of a thickening agent selected from the group consisting of hydroxypropyl guar gum and hydroxypropyl cellulose and a small amount effective to prevent discoloration of the substrate of an ultraviolet light absorbing agent which is soluble in the coating composition, said composition having a pH of about 7.1 to about 7.8.
Claim 3
Dependent Claim 18 words
An article as defined in claim 1, wherein the solid substrate is comprised of a synthetic organic polymer.
Claim 4
Dependent Claim 14 words
An article as defined in claim 2, wherein said polymer is a transparent polymer.
Claim 5
Dependent Claim 13 words
An article as defined in claim 3, wherein said polymer is a polycarbonate.
Claim 6
Dependent Claim 12 words
An article as defined in claim 4, wherein said polycarbonate is transparent.
Claim 7
Dependent Claim 14 words
An article as defined in claim 4, wherein said polycarbonate is a poly(bisphenol-A carbonate).
Claim 8
Dependent Claim 13 words
An article as defined in claim 2, wherein said polymer is a polymethylmethacrylate.
Claim 9
Dependent Claim 12 words
An article as defined in claim 7, wherein said polymethylmethacrylate is transparent.
Claim 10
Dependent Claim 22 words
An article as defined in claim 1, wherein the aqueous coating composition has been cured on said surface of said solid substrate.
Claim 11
Dependent Claim 31 words
An article as defined in claim 1 wherein said surface of said solid substrate has been primed with a primer composition prior to having been coated with said aqueous coating composition.
Claim 12
Dependent Claim 18 words
An article as defined in claim 10, wherein said primer composition is comprised of a thermosetting acrylic emulsion.
Claim 13
Dependent Claim 28 words
An article as defined in claim 10, wherein said primer composition is comprised of a 2% solution of polymethylmethacrylate in an 80:20 mixture of 2-ethoxyethanol and diacetone alcohol.
Claim 14
Dependent Claim 51 words
An article as defined in claim 10, wherein said primer composition comprises a solution of about 4% polymethylmethacrylate dissolved in a mixture of an ether solvent and a ketone solvent containing an ultraviolet light absorbing compound, or a combination of an ultraviolet light absorbing compound and an ultraviolet radiation stabilizing agent.
Claim 15
Dependent Claim 21 words
An article as defined in claim 13, wherein said ultraviolet light absorbing compound is 2-ethylhexyl ester of 3,3 diphenyl 2 cyanoacrylate.

USPTO Annuity & Maintenance Windows

Annuity Stage Window Opens Payment Deadline Surcharge Period Until Estimated Fee Status
3.5 Years (Year 4) 1987-10-02 1988-04-02 1988-10-02 $2000.00 Window Closed / Lapsed
7.5 Years (Year 8) 1991-10-02 1992-04-02 1992-10-02 $3760.00 Window Closed / Lapsed
11.5 Years (Year 12) 1995-10-02 1996-04-02 1996-10-02 $7700.00 Window Closed / Lapsed

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