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Extraction of halocarbons from aqueous solutions

Assignee: Wyeth Holdings LLC
•
Filing: 1982-09-30
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Granted: 1984-09-11
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Expires: 2002-09-30
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Abstract

Abstract A method for removing halogenated hydrocarbons from water is disclosed. The method comprises contacting said aqueous solution with a phosphine oxide either alone or on a solid support.

Inventors

  • 👤 John H. Bright

Bibliographic Details

Application Number —
Jurisdiction US
Data Source google_patents
Last Synchronized 2026-11-01 19:01
CPC Classifications
B; B01; B01J; B01J20/00; B01J20/30; B01J20/32; B01J20/3231; B01J20/3242; B01J20/3244; B01J20/3246; B01J20/3248; B01D; B01D15/00; C; C02; C02F; C02F1/00; C02F1/28; C02F1/285; C07; C07C; C07C17/00; C07C17/38; C07C17/389; Y; Y10; Y10S; Y10S210/00; Y10S210/902; Y10S210/908; Y10S210/909

Claims Analysis

Total Claims: 13
Claim 1
Independent Claim 66 words
A method for removing halogenated hydrocarbons from aqueous solutions thereof which comprises: (a) contacting said aqueous solutions for a time sufficient to extract said halogenated hydrocarbon with a phosphine oxide compound wherein said phosphine oxide compound has the formula: R.sub.3 P═O wherein the three R groups are each individually alkyl, cycloalkyl, aralkyl and substituted-aralkyl; and (b) separating the extracted aqueous solution from said phosphine oxide compound.
Claim 2
Independent Claim 66 words
A method for removing halogenated hydrocarbons from aqueous solutions thereof which comprises: (a) contacting said aqueous solutions for a time sufficient to extract said halogenated hydrocarbon with a phosphine oxide compound wherein said phosphine oxide compound has the formula: R.sub.3 P═O wherein the three R groups are each individually alkyl, cycloalkyl, aralkyl and substituted-aralkyl; and (b) separating the extracted aqueous solution from said phosphine oxide compound.
Claim 3
Dependent Claim 15 words
A method according to claim 1 wherein said phosphine oxide is on a solid support.
Claim 4
Dependent Claim 25 words
A method according to claim 2 wherein solid support material is a copolymer of at least one monovinyl compound and at least one polyvinyl compound.
Claim 5
Dependent Claim 14 words
A method according to claim 3 wherein said solid support material is divinylbenzene-cross-linked polystyrene.
Claim 6
Dependent Claim 40 words
A method according to claim 2 wherein said alkyl moiety is branched or linear and contains from about 6 to 18 carbon atoms and where said cycloalkyl moiety contains about 6 to 8 carbon atoms and is substituted or unsubstituted.
Claim 7
Independent Claim 19 words
A method according to claims 1, 2, 3, 4 or 5 wherein said phosphine oxide compound is trialkylphosphine oxide.
Claim 8
Dependent Claim 20 words
A method according to claim 6 wherein said trialkylphosphine oxide is tri-n-octylphosphine oxide or tri-n-hexylphosphine oxide or a mixture thereof.
Claim 9
Dependent Claim 18 words
A method according to claim 2 wherein said inert, solid support material is a naturally occurring inorganic material.
Claim 10
Dependent Claim 13 words
A method according to claim 8 wherein said support material is diatomaceous earth.
Claim 11
Dependent Claim 13 words
A method according to claim 2 wherein said support material is silica gel.
Claim 12
Independent Claim 23 words
A method according to claims 2, 3, 4 or 5 wherein said phosphine oxide compound is incorporated on said support material by impregnation.
Claim 13
Independent Claim 20 words
A method according to claims 3 or 4 wherein said phosphine oxide compound is incorporated on said support by encapsulation.

References Cited (Backward Citations)

US4224415A Cited
US4224415B1 Cited
US3708462A Cited
US4042498A Cited
US3906762A Cited
JPS5081965A Cited
JPS53101847A Cited
US4276179A Cited

USPTO Annuity & Maintenance Windows

Annuity Stage Window Opens Payment Deadline Surcharge Period Until Estimated Fee Status
3.5 Years (Year 4) 1987-09-11 1988-03-12 1988-09-11 $2000.00 Window Closed / Lapsed
7.5 Years (Year 8) 1991-09-11 1992-03-12 1992-09-11 $3760.00 Window Closed / Lapsed
11.5 Years (Year 12) 1995-09-11 1996-03-12 1996-09-11 $7700.00 Window Closed / Lapsed

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