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US4470826A
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Nitro-derivatives of the benzene series and their use in the dyeing of keratin fibres
Assignee: L' O R E A L
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Filing: 1981-10-15
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Granted: 1984-09-11
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Expires: 2001-10-15
Abstract
Abstract The invention provides novel nitro-paraphenylenediamine derivatives of the formula: <IMAGE> in which R1 denotes an alkyl group, a monohydroxy- or polyhydroxy-alkyl group or an aminoalkyl group, the amino group of which is optionally monosubstituted or disubstituted by an alkyl group, and R2 denotes an alkyl group, or a cosmetically acceptable salt thereof. These derivatives are useful as direct dyes, especially for dyeing human hair.
Inventors
- 👤 Andre/e/ Bugaut
- 👤 Jean Cotteret
Bibliographic Details
Application Number
—
Jurisdiction
US
Data Source
google_patents
Last Synchronized
2026-10-31 12:29
CPC Classifications
A; A61; A61K; A61K8/00; A61K8/18; A61K8/30; A61K8/40; A61K8/41; A61K8/418; A61Q; A61Q5/00; A61Q5/06; A61Q5/065; A61Q5/10; C; C09; C09B; C09B51/00; C09B53/00
Claims Analysis
Total Claims: 20
Claim 1
Independent Claim
54 words
A nitro-paraphenylenediamine derivative which corresponds to the formula (I): ##STR17## in which R 1 denotes an alkyl group, a monohydroxy- or polyhydroxy-alkyl group or an aminoalkyl group, the amino group of which is optionally monosubstituted or disubstituted by an alkyl group, and R 2 denotes an alkyl group, or a cosmetically acceptable salt thereof.
Claim 2
Dependent Claim
54 words
A nitro-paraphenylenediamine derivative which corresponds to the formula (I): ##STR17## in which R 1 denotes an alkyl group, a monohydroxy- or polyhydroxy-alkyl group or an aminoalkyl group, the amino group of which is optionally monosubstituted or disubstituted by an alkyl group, and R 2 denotes an alkyl group, or a cosmetically acceptable salt thereof.
Claim 3
Dependent Claim
19 words
A derivative according to claim 1 in which the alkyl group or groups have 1 to 4 carbon atoms.
Claim 4
Dependent Claim
47 words
A derivative according to claim 1 which corresponds to the formula: ##STR18## in which R' 1 denotes a monohydroxy- or polyhydroxy-alkyl radical or an aminoalkyl radical, the amino group of which is optionally monosubstituted or disubstituted by an alkyl radical, and R 2 denotes an alkyl group.
Claim 5
Dependent Claim
23 words
A derivative according to claim 3 in which R 2 is methyl and R' 1 is β-hydroxyethyl, β-diethylaminoethyl, β,γ-dihydroxypropyl, β-aminoethyl, γ-aminopropyl or γ-hydroxypropyl.
Claim 6
Dependent Claim
29 words
A composition suitable for dyeing human hair which comprises, in a diluent, at least one compound as defined in claim 1 in amount from 0.001 to 5% by weight.
Claim 7
Dependent Claim
32 words
A composition according to claim 5 suitable for dyeing human hair which contains, in a cosmetically acceptable medium, at least one said compound in an amount from 0.001 to 5% by weight.
Claim 8
Dependent Claim
26 words
A composition according to claim 5 or 6 in which the diluent is water, a lower alkanol, polyol, glycol or glycol ether, or a mixture thereof.
Claim 9
Dependent Claim
30 words
A composition according to claim 5 which also contains at least one of a surface-active agent, thickener, penetrating agent, sequestering agent, film-forming agent, buffer, perfume or alkalising or acidifying agent.
Claim 10
Dependent Claim
38 words
A composition according to claim 5 for the direct colouration of hair, which also contains a direct dyestuff which is an azo or anthraquinone dyestuff or nitro dyestuff of the benzene series other than one of formula (I).
Claim 11
Dependent Claim
26 words
A composition according to claim 5 which is in the form of an aqueous, alcoholic or aqueous-alcoholic solution and also containing at least one cosmetic resin.
Claim 12
Dependent Claim
20 words
A composition according to claim 5 for use in oxidation dyeing which also contains at least one oxidation dyestuff precursor.
Claim 13
Dependent Claim
20 words
A composition according to claim 11 which has a pH of 7 to 11.5 and also contains a reducing agent.
Claim 14
Dependent Claim
44 words
Process for the colouration of human hair, which comprises applying thereto a composition as defined in claim 5, in an amount sufficient to dye hair, leaving it on said hair, rinsing said hair, optionally washing and rinsing said hair again, and drying said hair.
Claim 15
Dependent Claim
41 words
Process for the colouration of human hair which comprises applying a composition as defined in claim 10, in an amount sufficient to dye hair, to washed and rinsed said hair, optionally winding said hair onto the rollers and drying said hair.
Claim 16
Dependent Claim
58 words
Process for the colouration of human hair which comprises applying thereto a composition as defined in claim 11, in an amount sufficient to dye hair, to which an oxidizing agent has been added, leaving it on said hair for 10 to 50 minutes and rinsing said hair, optionally shampooing and rinsing said hair again, and drying said hair.
Claim 17
Dependent Claim
3 words
(3-Nitro-4-N-β-hydroxyethylamino)phenyl β,γ-dihydroxypropyl ether.
Claim 18
Dependent Claim
3 words
(3-Nitro-4-N-β-hydroxyethylamino)phenyl β,γ-dihydroxypropyl ether.
Claim 19
Dependent Claim
2 words
(3-Nitro-4-N-β-hydroxyethylamino)phenoxy ethanol.
Claim 20
Dependent Claim
2 words
(3-Nitro-4-N-β-hydroxyethylamino)phenoxy ethanol.
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USPTO Annuity & Maintenance Windows
| Annuity Stage | Window Opens | Payment Deadline | Surcharge Period Until | Estimated Fee | Status |
|---|---|---|---|---|---|
| 3.5 Years (Year 4) | 1987-09-11 | 1988-03-12 | 1988-09-11 | $2000.00 | Window Closed / Lapsed |
| 7.5 Years (Year 8) | 1991-09-11 | 1992-03-12 | 1992-09-11 | $3760.00 | Window Closed / Lapsed |
| 11.5 Years (Year 12) | 1995-09-11 | 1996-03-12 | 1996-09-11 | $7700.00 | Window Closed / Lapsed |