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Electrophotographic light-sensitive material comprising a charge-generating material and a charge-transporting material

Assignee: Fujifilm Holdings Corp
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Filing: 1982-06-14
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Granted: 1984-09-04
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Expires: 2002-06-14
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Abstract

Abstract An electrophotographic light-sensitive material with an electrophotographic light-sensitive layer containing a charge-generating material and a charge-transporting material is described. The material is characterized in that the charge-generating material is a compound represented by the general formula (I) or (II): <IMAGE> (I) <IMAGE> (II) (wherein the symbols are the same as defined in the claims).

Inventors

  • 👤 Seiji Horie
  • 👤 Masayoshi Nagata
  • 👤 Junji Nakano
  • 👤 Hideo Sato

Bibliographic Details

Application Number —
Jurisdiction US
Data Source google_patents
Last Synchronized 2026-11-10 02:14
CPC Classifications
G; G03; G03G; G03G5/00; G03G5/02; G03G5/04; G03G5/06; G03G5/0622; G03G5/0644; G03G5/0661; C; C09; C09B; C09B23/00; C09B23/02; C09B23/04; C09B23/06; C09B23/10; C09B23/102; C09B23/105; G03G5/0601; G03G5/0605; G03G5/0607; G03G5/0624; G03G5/0627; G03G5/0635; G03G5/0664; G03G5/0666; G03G5/0668; G03G5/067

Claims Analysis

Total Claims: 15
Claim 1
Independent Claim 477 words
An electrophotographic light-sensitive material with an electrophotographic light-sensitive layer containing a charge-generating material and a charge-transporting material wherein the charge-generating material is a compound represented by the general formula (I) or (II): ##STR15## wherein (i) m is 0 or 1, and n is 0, 1 or 2; (ii) R 1 , R 2 , R 3 , R 4 and R 5 may be the same or different, and are each a hydrogen atom, an alkyl group, an aralkyl group, an aryl group or a heterocyclic group; (iii) A 1 is a univalent group which is derived from one of the substituted phenyl group, 5-membered monocyclic or condensed heterocyclic, and 6-membered condensed heterocyclic rings represented by the following formula: ##STR16## (wherein R 6 is an alkoxy group, an aralkyloxy group or a substituted amino group represented by the formula: ##STR17## (wherein R 12 and R 13 may be the same or different, and are each a substituted or unsubstituted alkyl group or a substituted or unsubstituted phenyl group, or groups capable of combining together to form a heterocyclic ring containing a nitrogen atom); R 7 and R 8 may be the same or different, and are each a hydrogen atom, a halogen atom, an alkyl group or a lower alkoxy group; Y and Z may be the same or different, and are each S, O or N-R 14 (wherein R 14 is an alkyl group containing from 1 to 4 carbon atoms); R 9 and R 10 may be the same or different, and are each a hydrogen atom, an alkyl group or an alkoxy group, or they are groups capable of combining together to form a benzene or naphthalene ring; and R 11 is a hydrogen atom, an alkyl group, an alkoxy group, an aryloxy group, an acyl group, an alkoxycarbonyl group, an aryloxycarbonyl group, a halogen atom, a monoalkylamino group, a dialkylamino group, an amido group or a nitro group, which may be either substituted or not substituted); (iv) A 2 is a divalent group which is derived from a heterocyclic ring nucleus selected from the group consisting of imidazole, 3H-indole, thiazole, benzothiazole, naphthothiazole, thianaphtheno-7',6',4,5-thiazole, oxazole, benzoxazole, naphthoxazole, selenazole, benzoselenazole, naphthoselenazole, thiazoline, 2-quinoline, 4-quinoline, 1-isoquinoline, benzimidazole, 2-pyridine, and 4-pyridine; and (v) B is an atom group necessary to form a divalent group which is derived from a carbon ring or heterocyclic ring containing the oxo oxygen atom of the carbonyl group linked to one of the rings represented by the following formulae: ##STR18## (wherein W is O, S or SO 2 ; R 15 is the same as R 11 ; R 16 is an alkyl group, an aralkyl group or an unsubstituted or substituted aryl group; and R 17 and R 18 may be the same or different, and are each an alkyl group, an arlkyl group; or an unsubstituted or substituted phenyl group).
Claim 2
Dependent Claim 477 words
An electrophotographic light-sensitive material with an electrophotographic light-sensitive layer containing a charge-generating material and a charge-transporting material wherein the charge-generating material is a compound represented by the general formula (I) or (II): ##STR15## wherein (i) m is 0 or 1, and n is 0, 1 or 2; (ii) R 1 , R 2 , R 3 , R 4 and R 5 may be the same or different, and are each a hydrogen atom, an alkyl group, an aralkyl group, an aryl group or a heterocyclic group; (iii) A 1 is a univalent group which is derived from one of the substituted phenyl group, 5-membered monocyclic or condensed heterocyclic, and 6-membered condensed heterocyclic rings represented by the following formula: ##STR16## (wherein R 6 is an alkoxy group, an aralkyloxy group or a substituted amino group represented by the formula: ##STR17## (wherein R 12 and R 13 may be the same or different, and are each a substituted or unsubstituted alkyl group or a substituted or unsubstituted phenyl group, or groups capable of combining together to form a heterocyclic ring containing a nitrogen atom); R 7 and R 8 may be the same or different, and are each a hydrogen atom, a halogen atom, an alkyl group or a lower alkoxy group; Y and Z may be the same or different, and are each S, O or N-R 14 (wherein R 14 is an alkyl group containing from 1 to 4 carbon atoms); R 9 and R 10 may be the same or different, and are each a hydrogen atom, an alkyl group or an alkoxy group, or they are groups capable of combining together to form a benzene or naphthalene ring; and R 11 is a hydrogen atom, an alkyl group, an alkoxy group, an aryloxy group, an acyl group, an alkoxycarbonyl group, an aryloxycarbonyl group, a halogen atom, a monoalkylamino group, a dialkylamino group, an amido group or a nitro group, which may be either substituted or not substituted); (iv) A 2 is a divalent group which is derived from a heterocyclic ring nucleus selected from the group consisting of imidazole, 3H-indole, thiazole, benzothiazole, naphthothiazole, thianaphtheno-7',6',4,5-thiazole, oxazole, benzoxazole, naphthoxazole, selenazole, benzoselenazole, naphthoselenazole, thiazoline, 2-quinoline, 4-quinoline, 1-isoquinoline, benzimidazole, 2-pyridine, and 4-pyridine; and (v) B is an atom group necessary to form a divalent group which is derived from a carbon ring or heterocyclic ring containing the oxo oxygen atom of the carbonyl group linked to one of the rings represented by the following formulae: ##STR18## (wherein W is O, S or SO 2 ; R 15 is the same as R 11 ; R 16 is an alkyl group, an aralkyl group or an unsubstituted or substituted aryl group; and R 17 and R 18 may be the same or different, and are each an alkyl group, an arlkyl group; or an unsubstituted or substituted phenyl group).
Claim 3
Dependent Claim 26 words
The electrophotographic light-sensitive material as claimed in claim 1, wherein the electrophotographic light-sensitive layer is a single layer containing the charge-generating material and the charge-transporting material.
Claim 4
Dependent Claim 30 words
The electrophotographic light-sensitive material as claimed in claim 1, wherein the electrophotographic light-sensitive layer comprises a charge-generating layer containing the charge-generating material and a charge-transporting layer containing the charge-transporting material.
Claim 5
Dependent Claim 22 words
An electrophotographic light-sensitive material as claimed in claim 2, wherein the light-sensitive layer has a thickness of from 3 to 50 μm.
Claim 6
Dependent Claim 22 words
An electrophotographic light-sensitive material as claimed in claim 2, wherein the thickness of the light-sensitive layer is from 5 to 20 μm.
Claim 7
Dependent Claim 20 words
An electrophotographic light-sensitive material as claimed in claim 3, wherein the charge-generating layer has thickness of 5 μm or less.
Claim 8
Dependent Claim 21 words
An electrophotographic light-sensitive material as claimed in claim 3, wherein the charge-generating layer has a thickness of 2 μm or less.
Claim 9
Dependent Claim 22 words
An electrophotographic light-sensitive material as claimed in claim 3, wherein the charge-transporting layer has a thickness of from 3 to 50 μm.
Claim 10
Dependent Claim 22 words
An electrophotographic light-sensitive material as claimed in claim 3, wherein the charge-transporting layer has a thickness of from 5 to 20 μm.
Claim 11
Dependent Claim 36 words
An electrophotographic light-sensitive material as claimed in claim 1, wherein the charge-generating material is present in the electrophotographic light-sensitive layer in a proportion of 1 to 150% by weight based on the weight of a binder.
Claim 12
Dependent Claim 36 words
An electrophotographic light-sensitive material as claimed in claim 1, wherein the charge-generating material is present in the electrophotographic light-sensitive layer in a proportion of 5 to 50% by weight based on the weight of a binder.
Claim 13
Dependent Claim 37 words
An electrophotographic light-sensitive material as claimed in claim 1, wherein the charge-transporting material is present in the electrophotographic light-sensitive layer in a proportion of from 10 to 150% by weight based on the weight of a binder.
Claim 14
Dependent Claim 37 words
An electrophotographic light-sensitive material as claimed in claim 1, wherein the charge-transporting material is present in the electrophotographic light-sensitive layer in a portion of from 30 to 100% by weight based on the weight of a binder.
Claim 15
Dependent Claim 49 words
An electrophotographic light-sensitive aterial as claimed in any of claims 2 or 3, wherein the charge-generating material is dispersed in a POLYMEROUS binder in an amount of 10 parts by weight or less per one part by weight of the compound represented by the general formula (I) or (II).

References Cited (Backward Citations)

US3982935A Cited
US3719480A Cited
US4105447A Cited
US4264694A Cited
US4346157A Cited

USPTO Annuity & Maintenance Windows

Annuity Stage Window Opens Payment Deadline Surcharge Period Until Estimated Fee Status
3.5 Years (Year 4) 1987-09-04 1988-03-05 1988-09-04 $2000.00 Window Closed / Lapsed
7.5 Years (Year 8) 1991-09-04 1992-03-05 1992-09-04 $3760.00 Window Closed / Lapsed
11.5 Years (Year 12) 1995-09-04 1996-03-05 1996-09-04 $7700.00 Window Closed / Lapsed

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