Patent US4469657A successfully refreshed from Google Patents.
US4469657A
Expired / Lapsed
US
⏱️ 0.0 years remaining
Rim elastomers with improved catalyst efficiency
Assignee: Huntsman Corp
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Filing: 1982-09-13
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Granted: 1984-09-04
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Expires: 2002-09-13
Abstract
Abstract The invention is a method for making reaction injection molded polyurethane of improved properties and decreased catalyst usage. The product is formulated by placing the tin catalyst in the A-component (isocyanate component) rather than in the B-component (polyol side). Reaction injection molded elastomers are useful as molded articles of commerce including, but not limited to, vehicle body parts.
Inventors
- 👤 Richard J. G. Dominguez
Bibliographic Details
Application Number
—
Jurisdiction
US
Data Source
google_patents
Last Synchronized
2026-10-23 20:44
CPC Classifications
C; C08; C08G; C08G18/00; C08G18/06; C08G18/28; C08G18/65; C08G18/66; C08G18/6666; C08G18/667; C08G18/08; C08G18/16; C08G18/22; C08G18/24; Y; Y10; Y10S; Y10S264/00; Y10S264/05; Y10S264/83
Claims Analysis
Total Claims: 29
Claim 1
Independent Claim
92 words
In a method for making a reaction injection molded polyurethane elastomer wherein a high molecular weight polyhydric polyether, a low molecular weight active hydrogen containing compound of at least two functionality and a polyisocyanate are reacted in the presence of a single tin catalyst or mixture of tin catalysts and wherein these ingredients are separated into two components prior to reaction and wherein one component contains all of the polyisocyanate the improvement which comprises mixing all of the tin catalyst or mixture of tin catalysts with the polyisocyanate component prior to reaction.
Claim 2
Dependent Claim
92 words
In a method for making a reaction injection molded polyurethane elastomer wherein a high molecular weight polyhydric polyether, a low molecular weight active hydrogen containing compound of at least two functionality and a polyisocyanate are reacted in the presence of a single tin catalyst or mixture of tin catalysts and wherein these ingredients are separated into two components prior to reaction and wherein one component contains all of the polyisocyanate the improvement which comprises mixing all of the tin catalyst or mixture of tin catalysts with the polyisocyanate component prior to reaction.
Claim 3
Dependent Claim
22 words
A method as in claim 1 wherein the polyol comprises a polyether of about 5000 molecular weight based on a trihydric initiator.
Claim 4
Dependent Claim
12 words
A method as in claim 1 wherein the polyisocyanate comprises 4,4'diphenylmethane diisocyanate.
Claim 5
Dependent Claim
15 words
A method as in claim 1 wherein the elastomer is postcured at about 325° F.
Claim 6
Dependent Claim
94 words
In a method for making a reaction injection molded polyurethane elastomer wherein a high molecular weight polyhydric polyether, a low molecular weight active hydrogen containing compound of at least two functionality and a polyisocyanate comprising 4,4'diphenylmethane diisocyanate are reacted in the presence of a single tin catalyst or mixture of tin catalysts and wherein these ingredients are separated into two components prior to reaction and wherein one component contains all of the polyisocyanate the improvement which comprises mixing all of the tin catalyst or mixing tin catalysts with the polyisocyanate component prior to reaction.
Claim 7
Dependent Claim
94 words
In a method for making a reaction injection molded polyurethane elastomer wherein a high molecular weight polyhydric polyether, a low molecular weight active hydrogen containing compound of at least two functionality and a polyisocyanate comprising 4,4'diphenylmethane diisocyanate are reacted in the presence of a single tin catalyst or mixture of tin catalysts and wherein these ingredients are separated into two components prior to reaction and wherein one component contains all of the polyisocyanate the improvement which comprises mixing all of the tin catalyst or mixing tin catalysts with the polyisocyanate component prior to reaction.
Claim 8
Dependent Claim
101 words
In a method for making a reaction injection molded polyurethane elastomer wherein a polyhydric polyether of about 5000 molecular weight based on the trihydric initiator, a low molecular weight active hydrogen containing compound of at least two functionality and a polyisocyanate comprising 4,4'diphenylmethane diisocyanate are reacted in the presence of a single tin catalyst or mixture of tin catalysts and wherein these ingredients are separated into two components prior to reaction and wherein one component contains all of the polyisocyanate improvement which comprises mixing all of the tin catalyst or mixture of tin catalysts with the polyisocyanate component prior to reaction.
Claim 9
Dependent Claim
101 words
In a method for making a reaction injection molded polyurethane elastomer wherein a polyhydric polyether of about 5000 molecular weight based on the trihydric initiator, a low molecular weight active hydrogen containing compound of at least two functionality and a polyisocyanate comprising 4,4'diphenylmethane diisocyanate are reacted in the presence of a single tin catalyst or mixture of tin catalysts and wherein these ingredients are separated into two components prior to reaction and wherein one component contains all of the polyisocyanate improvement which comprises mixing all of the tin catalyst or mixture of tin catalysts with the polyisocyanate component prior to reaction.
Claim 10
Dependent Claim
15 words
A method as in claim 6 wherein the elastomer is postcured at about 325° F.
Claim 11
Dependent Claim
84 words
In a method for making a reaction injection molded polyurethane elastomer wherein a high molecular weight polyhydric polyether, a low molecular weight active hydrogen containing compound of at least two functionality and a polyisocyanate are reacted in the presence of a mixture of tin catalysts and wherein these ingredients are separated into two components prior to reaction and wherein one component contains all of the polyisocyanate the improvement which comprises mixing all of the tin catalyst mixture with the polyisocyanate component prior to reaction.
Claim 12
Dependent Claim
84 words
In a method for making a reaction injection molded polyurethane elastomer wherein a high molecular weight polyhydric polyether, a low molecular weight active hydrogen containing compound of at least two functionality and a polyisocyanate are reacted in the presence of a mixture of tin catalysts and wherein these ingredients are separated into two components prior to reaction and wherein one component contains all of the polyisocyanate the improvement which comprises mixing all of the tin catalyst mixture with the polyisocyanate component prior to reaction.
Claim 13
Dependent Claim
22 words
A method as in claim 8 wherein the polyol comprises a polyether of about 5000 molecular weight based on a trihydric initiator.
Claim 14
Dependent Claim
12 words
A method as in claim 8 wherein the polyisocyanate comprises 4,4'diphenylmethane diisocyanate.
Claim 15
Dependent Claim
15 words
A method as in claim 8 wherein the elastomer is postcured at about 325° F.
Claim 16
Dependent Claim
86 words
In a method for making a reaction injection molded polyurethane elastomer wherein a high molecular weight polyhydric polyether, a low molecular weight active hydrogen containing compound of at least two functionality and a polyisocyanate comprising 4,4'diphenylmethane diisocyanate are reacted in the presence of a mixture of tin catalysts and wherein these ingredients are separated into two components prior to reaction and wherein one component contains all of the polyisocyanate the improvement which comprises mixing all the tin catalyst mixture with the polyisocyanate component prior to reaction.
Claim 17
Dependent Claim
86 words
In a method for making a reaction injection molded polyurethane elastomer wherein a high molecular weight polyhydric polyether, a low molecular weight active hydrogen containing compound of at least two functionality and a polyisocyanate comprising 4,4'diphenylmethane diisocyanate are reacted in the presence of a mixture of tin catalysts and wherein these ingredients are separated into two components prior to reaction and wherein one component contains all of the polyisocyanate the improvement which comprises mixing all the tin catalyst mixture with the polyisocyanate component prior to reaction.
Claim 18
Dependent Claim
92 words
In a method for making a reaction injection molded polyurethane elastomer wherein a polyhydric polyether of about 5000 molecular weight based on the trihydric initiator, a low molecular weight active hydrogen containing compound of at least two functionality and a polyisocyanate comprising 4,4'diphenylmethane diisocyanate are reacted in the presence of a mixture of tin catalysts wherein these ingredients are separated into two components prior to reaction and wherein one component contains all of the polyisocyanate improvement which comprises mixing all of the tin catalyst mixture with the polyisocyanate component prior to reaction.
Claim 19
Dependent Claim
92 words
In a method for making a reaction injection molded polyurethane elastomer wherein a polyhydric polyether of about 5000 molecular weight based on the trihydric initiator, a low molecular weight active hydrogen containing compound of at least two functionality and a polyisocyanate comprising 4,4'diphenylmethane diisocyanate are reacted in the presence of a mixture of tin catalysts wherein these ingredients are separated into two components prior to reaction and wherein one component contains all of the polyisocyanate improvement which comprises mixing all of the tin catalyst mixture with the polyisocyanate component prior to reaction.
Claim 20
Dependent Claim
15 words
A method as in claim 13 wherein the elastomer is postcured at about 325° F.
Claim 21
Dependent Claim
85 words
In a method for making a reaction injection molded polyurethane elastomer wherein a high molecular weight polyhydric polyether, a low molecular weight active hydrogen containing compound of at least two functionality and a polyisocyanate comprising 4,4'diphenylmethane diisocyanate are reacted in the presence of a single tin catalyst and wherein these ingredients are separated into two components prior to reaction and wherein one component contains all of the polyisocyanate the improvement which comprises mixing all of the tin catalyst with the polyisocyanate component prior to reaction.
Claim 22
Dependent Claim
85 words
In a method for making a reaction injection molded polyurethane elastomer wherein a high molecular weight polyhydric polyether, a low molecular weight active hydrogen containing compound of at least two functionality and a polyisocyanate comprising 4,4'diphenylmethane diisocyanate are reacted in the presence of a single tin catalyst and wherein these ingredients are separated into two components prior to reaction and wherein one component contains all of the polyisocyanate the improvement which comprises mixing all of the tin catalyst with the polyisocyanate component prior to reaction.
Claim 23
Dependent Claim
22 words
A method as in claim 15 wherein the polyol comprises a polyether of about 5000 molecular weight based on a trihydric initiator.
Claim 24
Dependent Claim
15 words
A metod as in claim 15 wherein the elastomer is postcured at about 325° F.
Claim 25
Dependent Claim
81 words
In a method for making a reaction injection molded polyurethane elastomer wherein a high molecular weight polyhydric polyether, a low molecular weight active hydrogen containing compound of at least two functionality and a polyisocyanate are reacted in the presence of a single tin catalyst and wherein these ingredients are separated into two components prior to reaction and wherein one component contains all of the polyisocyanate the improvement which comprises mixing all the tin catalyst with the polyisocyanate component prior to reaction.
Claim 26
Dependent Claim
81 words
In a method for making a reaction injection molded polyurethane elastomer wherein a high molecular weight polyhydric polyether, a low molecular weight active hydrogen containing compound of at least two functionality and a polyisocyanate are reacted in the presence of a single tin catalyst and wherein these ingredients are separated into two components prior to reaction and wherein one component contains all of the polyisocyanate the improvement which comprises mixing all the tin catalyst with the polyisocyanate component prior to reaction.
Claim 27
Dependent Claim
90 words
In a method for making a reaction injection molded polyurethane elastomer wherein a polyhydric polyether of about 5000 molecular weight based on the trihydric initiator, a low molecular weight active hydrogen containing compound of at least two functionality and a polyisocyanate comprising 4,4'diphenylmethane diisocyanate are reacted in the presence of a single tin catalyst wherein these ingredients are separated into two components prior to reaction and wherein one component contains all of the polyisocyanate improvement which comprises mixing all of the tin catalyst with the polyisocyanate component prior to reaction.
Claim 28
Dependent Claim
90 words
In a method for making a reaction injection molded polyurethane elastomer wherein a polyhydric polyether of about 5000 molecular weight based on the trihydric initiator, a low molecular weight active hydrogen containing compound of at least two functionality and a polyisocyanate comprising 4,4'diphenylmethane diisocyanate are reacted in the presence of a single tin catalyst wherein these ingredients are separated into two components prior to reaction and wherein one component contains all of the polyisocyanate improvement which comprises mixing all of the tin catalyst with the polyisocyanate component prior to reaction.
Claim 29
Dependent Claim
15 words
A method as in claim 19 wherein the elastomer is postcured at about 325° F.
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USPTO Annuity & Maintenance Windows
| Annuity Stage | Window Opens | Payment Deadline | Surcharge Period Until | Estimated Fee | Status |
|---|---|---|---|---|---|
| 3.5 Years (Year 4) | 1987-09-04 | 1988-03-05 | 1988-09-04 | $2000.00 | Window Closed / Lapsed |
| 7.5 Years (Year 8) | 1991-09-04 | 1992-03-05 | 1992-09-04 | $3760.00 | Window Closed / Lapsed |
| 11.5 Years (Year 12) | 1995-09-04 | 1996-03-05 | 1996-09-04 | $7700.00 | Window Closed / Lapsed |