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US4469657A Expired / Lapsed US ⏱️ 0.0 years remaining

Rim elastomers with improved catalyst efficiency

Assignee: Huntsman Corp
•
Filing: 1982-09-13
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Granted: 1984-09-04
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Expires: 2002-09-13
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Abstract

Abstract The invention is a method for making reaction injection molded polyurethane of improved properties and decreased catalyst usage. The product is formulated by placing the tin catalyst in the A-component (isocyanate component) rather than in the B-component (polyol side). Reaction injection molded elastomers are useful as molded articles of commerce including, but not limited to, vehicle body parts.

Inventors

  • 👤 Richard J. G. Dominguez

Bibliographic Details

Application Number —
Jurisdiction US
Data Source google_patents
Last Synchronized 2026-10-23 17:53
CPC Classifications
C; C08; C08G; C08G18/00; C08G18/06; C08G18/28; C08G18/65; C08G18/66; C08G18/6666; C08G18/667; C08G18/08; C08G18/16; C08G18/22; C08G18/24; Y; Y10; Y10S; Y10S264/00; Y10S264/05; Y10S264/83

Claims Analysis

Total Claims: 29
Claim 1
Independent Claim 92 words
In a method for making a reaction injection molded polyurethane elastomer wherein a high molecular weight polyhydric polyether, a low molecular weight active hydrogen containing compound of at least two functionality and a polyisocyanate are reacted in the presence of a single tin catalyst or mixture of tin catalysts and wherein these ingredients are separated into two components prior to reaction and wherein one component contains all of the polyisocyanate the improvement which comprises mixing all of the tin catalyst or mixture of tin catalysts with the polyisocyanate component prior to reaction.
Claim 2
Dependent Claim 92 words
In a method for making a reaction injection molded polyurethane elastomer wherein a high molecular weight polyhydric polyether, a low molecular weight active hydrogen containing compound of at least two functionality and a polyisocyanate are reacted in the presence of a single tin catalyst or mixture of tin catalysts and wherein these ingredients are separated into two components prior to reaction and wherein one component contains all of the polyisocyanate the improvement which comprises mixing all of the tin catalyst or mixture of tin catalysts with the polyisocyanate component prior to reaction.
Claim 3
Dependent Claim 22 words
A method as in claim 1 wherein the polyol comprises a polyether of about 5000 molecular weight based on a trihydric initiator.
Claim 4
Dependent Claim 12 words
A method as in claim 1 wherein the polyisocyanate comprises 4,4'diphenylmethane diisocyanate.
Claim 5
Dependent Claim 15 words
A method as in claim 1 wherein the elastomer is postcured at about 325° F.
Claim 6
Dependent Claim 94 words
In a method for making a reaction injection molded polyurethane elastomer wherein a high molecular weight polyhydric polyether, a low molecular weight active hydrogen containing compound of at least two functionality and a polyisocyanate comprising 4,4'diphenylmethane diisocyanate are reacted in the presence of a single tin catalyst or mixture of tin catalysts and wherein these ingredients are separated into two components prior to reaction and wherein one component contains all of the polyisocyanate the improvement which comprises mixing all of the tin catalyst or mixing tin catalysts with the polyisocyanate component prior to reaction.
Claim 7
Dependent Claim 94 words
In a method for making a reaction injection molded polyurethane elastomer wherein a high molecular weight polyhydric polyether, a low molecular weight active hydrogen containing compound of at least two functionality and a polyisocyanate comprising 4,4'diphenylmethane diisocyanate are reacted in the presence of a single tin catalyst or mixture of tin catalysts and wherein these ingredients are separated into two components prior to reaction and wherein one component contains all of the polyisocyanate the improvement which comprises mixing all of the tin catalyst or mixing tin catalysts with the polyisocyanate component prior to reaction.
Claim 8
Dependent Claim 101 words
In a method for making a reaction injection molded polyurethane elastomer wherein a polyhydric polyether of about 5000 molecular weight based on the trihydric initiator, a low molecular weight active hydrogen containing compound of at least two functionality and a polyisocyanate comprising 4,4'diphenylmethane diisocyanate are reacted in the presence of a single tin catalyst or mixture of tin catalysts and wherein these ingredients are separated into two components prior to reaction and wherein one component contains all of the polyisocyanate improvement which comprises mixing all of the tin catalyst or mixture of tin catalysts with the polyisocyanate component prior to reaction.
Claim 9
Dependent Claim 101 words
In a method for making a reaction injection molded polyurethane elastomer wherein a polyhydric polyether of about 5000 molecular weight based on the trihydric initiator, a low molecular weight active hydrogen containing compound of at least two functionality and a polyisocyanate comprising 4,4'diphenylmethane diisocyanate are reacted in the presence of a single tin catalyst or mixture of tin catalysts and wherein these ingredients are separated into two components prior to reaction and wherein one component contains all of the polyisocyanate improvement which comprises mixing all of the tin catalyst or mixture of tin catalysts with the polyisocyanate component prior to reaction.
Claim 10
Dependent Claim 15 words
A method as in claim 6 wherein the elastomer is postcured at about 325° F.
Claim 11
Dependent Claim 84 words
In a method for making a reaction injection molded polyurethane elastomer wherein a high molecular weight polyhydric polyether, a low molecular weight active hydrogen containing compound of at least two functionality and a polyisocyanate are reacted in the presence of a mixture of tin catalysts and wherein these ingredients are separated into two components prior to reaction and wherein one component contains all of the polyisocyanate the improvement which comprises mixing all of the tin catalyst mixture with the polyisocyanate component prior to reaction.
Claim 12
Dependent Claim 84 words
In a method for making a reaction injection molded polyurethane elastomer wherein a high molecular weight polyhydric polyether, a low molecular weight active hydrogen containing compound of at least two functionality and a polyisocyanate are reacted in the presence of a mixture of tin catalysts and wherein these ingredients are separated into two components prior to reaction and wherein one component contains all of the polyisocyanate the improvement which comprises mixing all of the tin catalyst mixture with the polyisocyanate component prior to reaction.
Claim 13
Dependent Claim 22 words
A method as in claim 8 wherein the polyol comprises a polyether of about 5000 molecular weight based on a trihydric initiator.
Claim 14
Dependent Claim 12 words
A method as in claim 8 wherein the polyisocyanate comprises 4,4'diphenylmethane diisocyanate.
Claim 15
Dependent Claim 15 words
A method as in claim 8 wherein the elastomer is postcured at about 325° F.
Claim 16
Dependent Claim 86 words
In a method for making a reaction injection molded polyurethane elastomer wherein a high molecular weight polyhydric polyether, a low molecular weight active hydrogen containing compound of at least two functionality and a polyisocyanate comprising 4,4'diphenylmethane diisocyanate are reacted in the presence of a mixture of tin catalysts and wherein these ingredients are separated into two components prior to reaction and wherein one component contains all of the polyisocyanate the improvement which comprises mixing all the tin catalyst mixture with the polyisocyanate component prior to reaction.
Claim 17
Dependent Claim 86 words
In a method for making a reaction injection molded polyurethane elastomer wherein a high molecular weight polyhydric polyether, a low molecular weight active hydrogen containing compound of at least two functionality and a polyisocyanate comprising 4,4'diphenylmethane diisocyanate are reacted in the presence of a mixture of tin catalysts and wherein these ingredients are separated into two components prior to reaction and wherein one component contains all of the polyisocyanate the improvement which comprises mixing all the tin catalyst mixture with the polyisocyanate component prior to reaction.
Claim 18
Dependent Claim 92 words
In a method for making a reaction injection molded polyurethane elastomer wherein a polyhydric polyether of about 5000 molecular weight based on the trihydric initiator, a low molecular weight active hydrogen containing compound of at least two functionality and a polyisocyanate comprising 4,4'diphenylmethane diisocyanate are reacted in the presence of a mixture of tin catalysts wherein these ingredients are separated into two components prior to reaction and wherein one component contains all of the polyisocyanate improvement which comprises mixing all of the tin catalyst mixture with the polyisocyanate component prior to reaction.
Claim 19
Dependent Claim 92 words
In a method for making a reaction injection molded polyurethane elastomer wherein a polyhydric polyether of about 5000 molecular weight based on the trihydric initiator, a low molecular weight active hydrogen containing compound of at least two functionality and a polyisocyanate comprising 4,4'diphenylmethane diisocyanate are reacted in the presence of a mixture of tin catalysts wherein these ingredients are separated into two components prior to reaction and wherein one component contains all of the polyisocyanate improvement which comprises mixing all of the tin catalyst mixture with the polyisocyanate component prior to reaction.
Claim 20
Dependent Claim 15 words
A method as in claim 13 wherein the elastomer is postcured at about 325° F.
Claim 21
Dependent Claim 85 words
In a method for making a reaction injection molded polyurethane elastomer wherein a high molecular weight polyhydric polyether, a low molecular weight active hydrogen containing compound of at least two functionality and a polyisocyanate comprising 4,4'diphenylmethane diisocyanate are reacted in the presence of a single tin catalyst and wherein these ingredients are separated into two components prior to reaction and wherein one component contains all of the polyisocyanate the improvement which comprises mixing all of the tin catalyst with the polyisocyanate component prior to reaction.
Claim 22
Dependent Claim 85 words
In a method for making a reaction injection molded polyurethane elastomer wherein a high molecular weight polyhydric polyether, a low molecular weight active hydrogen containing compound of at least two functionality and a polyisocyanate comprising 4,4'diphenylmethane diisocyanate are reacted in the presence of a single tin catalyst and wherein these ingredients are separated into two components prior to reaction and wherein one component contains all of the polyisocyanate the improvement which comprises mixing all of the tin catalyst with the polyisocyanate component prior to reaction.
Claim 23
Dependent Claim 22 words
A method as in claim 15 wherein the polyol comprises a polyether of about 5000 molecular weight based on a trihydric initiator.
Claim 24
Dependent Claim 15 words
A metod as in claim 15 wherein the elastomer is postcured at about 325° F.
Claim 25
Dependent Claim 81 words
In a method for making a reaction injection molded polyurethane elastomer wherein a high molecular weight polyhydric polyether, a low molecular weight active hydrogen containing compound of at least two functionality and a polyisocyanate are reacted in the presence of a single tin catalyst and wherein these ingredients are separated into two components prior to reaction and wherein one component contains all of the polyisocyanate the improvement which comprises mixing all the tin catalyst with the polyisocyanate component prior to reaction.
Claim 26
Dependent Claim 81 words
In a method for making a reaction injection molded polyurethane elastomer wherein a high molecular weight polyhydric polyether, a low molecular weight active hydrogen containing compound of at least two functionality and a polyisocyanate are reacted in the presence of a single tin catalyst and wherein these ingredients are separated into two components prior to reaction and wherein one component contains all of the polyisocyanate the improvement which comprises mixing all the tin catalyst with the polyisocyanate component prior to reaction.
Claim 27
Dependent Claim 90 words
In a method for making a reaction injection molded polyurethane elastomer wherein a polyhydric polyether of about 5000 molecular weight based on the trihydric initiator, a low molecular weight active hydrogen containing compound of at least two functionality and a polyisocyanate comprising 4,4'diphenylmethane diisocyanate are reacted in the presence of a single tin catalyst wherein these ingredients are separated into two components prior to reaction and wherein one component contains all of the polyisocyanate improvement which comprises mixing all of the tin catalyst with the polyisocyanate component prior to reaction.
Claim 28
Dependent Claim 90 words
In a method for making a reaction injection molded polyurethane elastomer wherein a polyhydric polyether of about 5000 molecular weight based on the trihydric initiator, a low molecular weight active hydrogen containing compound of at least two functionality and a polyisocyanate comprising 4,4'diphenylmethane diisocyanate are reacted in the presence of a single tin catalyst wherein these ingredients are separated into two components prior to reaction and wherein one component contains all of the polyisocyanate improvement which comprises mixing all of the tin catalyst with the polyisocyanate component prior to reaction.
Claim 29
Dependent Claim 15 words
A method as in claim 19 wherein the elastomer is postcured at about 325° F.

References Cited (Backward Citations)

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USPTO Annuity & Maintenance Windows

Annuity Stage Window Opens Payment Deadline Surcharge Period Until Estimated Fee Status
3.5 Years (Year 4) 1987-09-04 1988-03-05 1988-09-04 $2000.00 Window Closed / Lapsed
7.5 Years (Year 8) 1991-09-04 1992-03-05 1992-09-04 $3760.00 Window Closed / Lapsed
11.5 Years (Year 12) 1995-09-04 1996-03-05 1996-09-04 $7700.00 Window Closed / Lapsed

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