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US4468493A Expired / Lapsed US ⏱️ 0.0 years remaining

High solid coating composition containing novel microparticles of crosslinked copolymer containing amphoionic groups

Assignee: Nippon Paint Co Ltd
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Filing: 1983-01-25
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Granted: 1984-08-28
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Expires: 2003-01-25
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Abstract

Abstract A high solid coating composition comprising (A) a film-forming polymer having functional group(s) capable of reacting with the crosslinking agent (D) hereinafter referred to, (B) a volatile organic liquid diluent in which the polymer (A) is carried, (C) polymer microparticles having an average diameter of from 0.02 to 40 microns, which are insoluble in the combination of the film-forming polymer (A) and the diluent (B) and are maintained in a stabilized state of dispersion therein, and (D) a crosslinking agent dissolved in the diluent (B), which is characterized by the fact that the microparticles (C) are composed of crosslinked copolymer obtained by copolymerizing at least one of the polymerizable amino acid compounds of the formula: <IMAGE> with other polymerizable alpha , beta -ethylenically unsaturated monomers, at least part of which is crosslinking monomer.

Inventors

  • 👤 Shinichi Ishikura
  • 👤 Kazunori Kanda
  • 👤 Katsuaki Kida
  • 👤 Ryuzo Mizuguchi

Bibliographic Details

Application Number —
Jurisdiction US
Data Source google_patents
Last Synchronized 2026-11-05 23:16
CPC Classifications
C; C09; C09D; C09D167/00; C08; C08G; C08G12/00; C08G12/02; C08G12/26; C08G12/34; C08G59/00; C08G59/14; C08G59/18; C08G59/40; C08G59/4007; C08G59/4064; C09D201/00

Claims Analysis

Total Claims: 2
Claim 1
Independent Claim 190 words
In a high solid coating composition comprising (A) a film-forming polymer having functional group(s) capable of reacting with the crosslinking agent (D) hereinafter referred to, (B) a volatile organic liquid diluent in which the polymer (A) is carried, (C) polymer microparticles having an average diameter of from 0.02 to 40 microns, which are insoluble in the combination of the film-forming polymer (A) and the diluent (B) and are maintained in a stabilized state of dispersion therein, and (D) a crosslinking agent dissolved in the diluent (B), the improvement wherein the microparticles (C) are composed of crosslinked copolymer obtained by copolymerizing at least one of the polymerizable amino acid compounds of the formula: ##STR7## in which R 1 is a substituent having a polymerizable α,β-ethylenic unsaturated bond, R 2 represents a member selected from the group consisting of hydrogen and substituted or unsubstituted C 1 ˜C 30 hydrogen residue, R 3 is a member selected from the group consisting of substituted or unsubstituted C 1 ˜C 2 hydrocarbon residue and A is --COOH or --SO 3 H, with other polymerizable α,β-ethylenically unsaturated monomers, at least part of which is crosslinking monomer.
Claim 2
Dependent Claim 190 words
In a high solid coating composition comprising (A) a film-forming polymer having functional group(s) capable of reacting with the crosslinking agent (D) hereinafter referred to, (B) a volatile organic liquid diluent in which the polymer (A) is carried, (C) polymer microparticles having an average diameter of from 0.02 to 40 microns, which are insoluble in the combination of the film-forming polymer (A) and the diluent (B) and are maintained in a stabilized state of dispersion therein, and (D) a crosslinking agent dissolved in the diluent (B), the improvement wherein the microparticles (C) are composed of crosslinked copolymer obtained by copolymerizing at least one of the polymerizable amino acid compounds of the formula: ##STR7## in which R 1 is a substituent having a polymerizable α,β-ethylenic unsaturated bond, R 2 represents a member selected from the group consisting of hydrogen and substituted or unsubstituted C 1 ˜C 30 hydrogen residue, R 3 is a member selected from the group consisting of substituted or unsubstituted C 1 ˜C 2 hydrocarbon residue and A is --COOH or --SO 3 H, with other polymerizable α,β-ethylenically unsaturated monomers, at least part of which is crosslinking monomer.

References Cited (Backward Citations)

US4116912A Cited
US4180489A Cited
US4309327A Cited
US4336177A Cited

USPTO Annuity & Maintenance Windows

Annuity Stage Window Opens Payment Deadline Surcharge Period Until Estimated Fee Status
3.5 Years (Year 4) 1987-08-28 1988-02-27 1988-08-28 $2000.00 Window Closed / Lapsed
7.5 Years (Year 8) 1991-08-28 1992-02-27 1992-08-28 $3760.00 Window Closed / Lapsed
11.5 Years (Year 12) 1995-08-28 1996-02-27 1996-08-28 $7700.00 Window Closed / Lapsed

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