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US4468488A Expired / Lapsed US ⏱️ 0.0 years remaining

Poly(piperidylamine) alkanes and synthetic resin compositions stabilized thereby

Assignee: Adeka Corp
•
Filing: 1983-02-28
•
Granted: 1984-08-28
•
Expires: 2003-02-28
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Abstract

Abstract Poly(piperidylamine) alkanes represented by the Formula (I) or (II): <IMAGE> (I) <IMAGE> (II) and synthetic resin compositions having improved resistance to deterioration by light containing such compounds.

Inventors

  • 👤 Motonobu Minagawa
  • 👤 Yutaka Nakahara
  • 👤 Toshihiro Shibata
  • 👤 Ryozo Arata

Bibliographic Details

Application Number —
Jurisdiction US
Data Source google_patents
Last Synchronized 2026-10-29 15:03
CPC Classifications
C; C07; C07D; C07D401/00; C07D401/02; C07D401/12; C07D211/00; C07D211/04; C07D211/06; C07D211/36; C07D211/56; C07D211/58; C08; C08K; C08K5/00; C08K5/16; C08K5/34; C08K5/3412; C08K5/3432; C08K5/3435

Claims Analysis

Total Claims: 31
Claim 1
Independent Claim 427 words
Poly-(2,2,6,6-tetramethylpiperidylamino)alkanes having the formula (I) or (II): ##STR173## wherein: X is hydrogen or ##STR174## Y 1 is carbonyl ##STR175## wherein Z 1 is a single bond; saturated or unsaturated alkylene having from one to twelve carbon atoms; or phenylene; dicarbamoyl ##STR176## where Z 2 is alkylene having from two to twelve carbon atoms; cyclohexylene and alkylcyclohexylene having five to ten carbon atoms; or phenylene and alkyl phenylene having six to twelve carbon atoms; diphenylene; diphenylene ether; diphenylene alkane, the alkane having one to four carbon atoms; or ##STR177## A 1 is hydrogen, alkyl, hydroxyalkyl or epoxy alkyl having one to eighteeen carbon atoms; phenalkyl having from six to ten carbon atoms; alkanoyl having from two to eighteen carbon atoms; acryloyl; phenoyl, alkylphenoyl, hydroxyphenoyl and alkylhydroxyphenoyl having from six to ten carbon atoms or B 1 --Y 1 --; B 1 is --OR 2 , ##STR178## Y 2 is carbonyl ##STR179## where Z 1 is a single bond; saturated or unsaturated alkylene having from one to twelve carbon atoms; or phenylene; dicarbamoyl ##STR180## where Z 2 is alkylene having from two to twelve carbon atoms; cyclohexylene and alkylcyclohexylene having five to ten carbon atoms; or phenylene and alkyl phenylene having six to twelve carbon atoms; diphenylene, diphenylene ether; diphenylene alkane, the alkane having one to four carbon atoms; or ##STR181## A 2 is hydrogen, alkyl, hydroxyalkyl or epoxy alkyl having one to eighteen carbon atoms; phenalkyl having from six to ten carbon atoms; alkanoyl having from two to eighteen carbon atoms; acryloyl; phenoyl, alkylphenoyl, hydroxyphenoyl and alkylhydroxyphenoyl having from six to ten carbon atoms or B 2 --Y 2 --; B 2 is --OR 2 --, ##STR182## R 1 is hydrogen, alkyl, hydroxyalkyl or epoxy alkyl having one to eighteen carbon atoms; phenalkyl having from six to ten carbon atoms; alkanoyl having from two to eighteen carbon atoms; acryloyl; phenoyl, alkylphenoyl, hydroxyphenoyl and alkyhydroxyphenoyl having from six to ten carbon atoms or oxy; R 2 is alkyl, hydroxyalkyl or epoxy alkyl having one to eighteen carbon atoms; phenalkyl having from six to ten carbon atoms; alkanoyl having from two to eighteen carbon atoms; acryloyl; phenoyl, alkylphenoyl, hydroxyphenoyl and alkylhydroxyphenoyl having from six to ten carbon atoms or aryl; R 3 and R 4 each is hydrogen, alkyl, hydroxyalkyl or epoxy alkyl having one to eighteen carbon atoms; phenalkyl having from six to ten carbon atoms; alkanoyl having from two to eighteen carbon atoms; acryloyl; phenoyl, alkylphenoyl, hydroxyphenoyl and alkylhydroxyphenoyl having from six to ten carbon atoms or ##STR183## m is 0 to 10; n is 1 to 20.
Claim 2
Dependent Claim 427 words
Poly-(2,2,6,6-tetramethylpiperidylamino)alkanes having the formula (I) or (II): ##STR173## wherein: X is hydrogen or ##STR174## Y 1 is carbonyl ##STR175## wherein Z 1 is a single bond; saturated or unsaturated alkylene having from one to twelve carbon atoms; or phenylene; dicarbamoyl ##STR176## where Z 2 is alkylene having from two to twelve carbon atoms; cyclohexylene and alkylcyclohexylene having five to ten carbon atoms; or phenylene and alkyl phenylene having six to twelve carbon atoms; diphenylene; diphenylene ether; diphenylene alkane, the alkane having one to four carbon atoms; or ##STR177## A 1 is hydrogen, alkyl, hydroxyalkyl or epoxy alkyl having one to eighteeen carbon atoms; phenalkyl having from six to ten carbon atoms; alkanoyl having from two to eighteen carbon atoms; acryloyl; phenoyl, alkylphenoyl, hydroxyphenoyl and alkylhydroxyphenoyl having from six to ten carbon atoms or B 1 --Y 1 --; B 1 is --OR 2 , ##STR178## Y 2 is carbonyl ##STR179## where Z 1 is a single bond; saturated or unsaturated alkylene having from one to twelve carbon atoms; or phenylene; dicarbamoyl ##STR180## where Z 2 is alkylene having from two to twelve carbon atoms; cyclohexylene and alkylcyclohexylene having five to ten carbon atoms; or phenylene and alkyl phenylene having six to twelve carbon atoms; diphenylene, diphenylene ether; diphenylene alkane, the alkane having one to four carbon atoms; or ##STR181## A 2 is hydrogen, alkyl, hydroxyalkyl or epoxy alkyl having one to eighteen carbon atoms; phenalkyl having from six to ten carbon atoms; alkanoyl having from two to eighteen carbon atoms; acryloyl; phenoyl, alkylphenoyl, hydroxyphenoyl and alkylhydroxyphenoyl having from six to ten carbon atoms or B 2 --Y 2 --; B 2 is --OR 2 --, ##STR182## R 1 is hydrogen, alkyl, hydroxyalkyl or epoxy alkyl having one to eighteen carbon atoms; phenalkyl having from six to ten carbon atoms; alkanoyl having from two to eighteen carbon atoms; acryloyl; phenoyl, alkylphenoyl, hydroxyphenoyl and alkyhydroxyphenoyl having from six to ten carbon atoms or oxy; R 2 is alkyl, hydroxyalkyl or epoxy alkyl having one to eighteen carbon atoms; phenalkyl having from six to ten carbon atoms; alkanoyl having from two to eighteen carbon atoms; acryloyl; phenoyl, alkylphenoyl, hydroxyphenoyl and alkylhydroxyphenoyl having from six to ten carbon atoms or aryl; R 3 and R 4 each is hydrogen, alkyl, hydroxyalkyl or epoxy alkyl having one to eighteen carbon atoms; phenalkyl having from six to ten carbon atoms; alkanoyl having from two to eighteen carbon atoms; acryloyl; phenoyl, alkylphenoyl, hydroxyphenoyl and alkylhydroxyphenoyl having from six to ten carbon atoms or ##STR183## m is 0 to 10; n is 1 to 20.
Claim 3
Dependent Claim 28 words
Poly(piperidylamine)alkanes according to claim 1 having the formula ##STR184## wherein: A 1 , B 1 , R 1 , X and Y 1 are as in claim 1.
Claim 4
Dependent Claim 26 words
Poly(piperidylamine)alkanes according to claim 1 having the formula ##STR185## wherein: A 2 , B 2 , R 1 and Y 2 are as in claim 1.
Claim 5
Dependent Claim 9 words
Poly(piperidylamine)alkane according to claim 1 wherein m is zero.
Claim 6
Dependent Claim 9 words
Poly(piperidylamine)alkane according to claim 1 wherein n is 1.
Claim 7
Dependent Claim 9 words
Poly(piperidylamine)alkane according to claim 1 wherein n is 2.
Claim 8
Dependent Claim 34 words
Poly(piperidylamine)alkane according to claim 1 wherein m is zero, n is 1, R 1 is hydrogen, A 1 is hydroxyphenoyl, Y 1 and Y 2 are C═O and B 1 is R 2 .
Claim 9
Dependent Claim 28 words
Poly(piperidylamine)alkane according to claim 1 wherein m is zero, n is 1, R 1 is hydrogen, X is --N ##STR186## and Y 1 and Y 2 are ##STR187##
Claim 10
Dependent Claim 27 words
Poly(piperidylamine)alkane according to claim 1 wherein m is zero, R 1 , X and A 1 are hydrogen, Y 1 is C═O and B 1 is ##STR188##
Claim 11
Dependent Claim 18 words
Poly(piperidylamine)alkane according to claim 1 wherein m is zero, Y 1 is ##STR189## and A 1 is alkanoyl.
Claim 12
Dependent Claim 18 words
Poly(piperidylamine)alkane according to claim 1 wherein m is zero, Y 1 is ##STR190## and B 1 is ##STR191##
Claim 13
Dependent Claim 14 words
Poly(piperidylamine)alkane according to claim 1 wherein m is zero and Y 1 is ##STR192##
Claim 14
Dependent Claim 14 words
Poly(piperidylamine)alkane according to claim 1 wherein m is zero and B 1 is ##STR193##
Claim 15
Dependent Claim 10 words
Poly(piperidylamine)alkane according to claim 1 wherein Y 1 is ##STR194##
Claim 16
Dependent Claim 9 words
Poly(piperidylamine)alkane according to claim 1 having the structure: ##STR195##
Claim 17
Dependent Claim 9 words
Poly(piperidylamine)alkane according to claim 1 having the structure: ##STR196##
Claim 18
Dependent Claim 9 words
Poly(piperidylamine)alkane according to claim 1 having the structure: ##STR197##
Claim 19
Dependent Claim 9 words
Poly(piperidylamine)alkane according to claim 1 having the structure: ##STR198##
Claim 20
Dependent Claim 9 words
Poly(piperidylamine)alkane according to claim 1 having the structure: ##STR199##
Claim 21
Dependent Claim 9 words
Poly(piperidylamine)alkane according to claim 1 having the structure: ##STR200##
Claim 22
Dependent Claim 9 words
Poly(piperidylamine)alkane according to claim 1 having the structure: ##STR201##
Claim 23
Dependent Claim 53 words
A polyvinyl chloride resin composition having improved resistance to deterioration upon exposure to light comprising a polyvinyl chloride resin formed at least in part of the recurring group: ##STR202## and having a chlorine content in excess of 40%, where X is either hydrogen or chlorine; and a compound in accordance with claim 1.
Claim 24
Dependent Claim 20 words
A polyvinyl chloride resin composition in accordance with claim 22 in which the polyvinyl chloride resin is polyvinyl chloride homopolymer.
Claim 25
Dependent Claim 25 words
A polyvinyl chloride resin composition in accordance with claim 22 in which the polyvinyl chloride resin is a copolymer of vinyl chloride and vinyl acetate.
Claim 26
Dependent Claim 43 words
An olefin polymer composition having improved resistance to deterioration upon exposure to light comprising an olefin polymer selected from the group consisting of polymers of alpha-olefins having from two to six carbon atoms and polystyrene, and a compound in accordance with claim 1.
Claim 27
Dependent Claim 14 words
An olefin polymer composition in accordance with claim 25 wherein the polyolefin is polypropylene.
Claim 28
Dependent Claim 14 words
An olefin polymer composition in accordance with claim 25 wherein the polyolefin is polyethylene.
Claim 29
Dependent Claim 15 words
An olefin polymer composition in accordance with claim 25 wherein the polyolefin is ethylene-propylene copolymer.
Claim 30
Dependent Claim 25 words
A polyurethane resin composition having improved resistance to deterioration upon exposure to light comprising a polyurethane resin and a compound in accordance with claim 1.
Claim 31
Dependent Claim 27 words
An ethylene-vinyl acetate copolymer composition having improved resistance to deterioration upon exposure to light comprising an ethylene-vinyl acetate copolymer and a compound in accordance with claim 1.

References Cited (Backward Citations)

US4263434A Cited
US4256627A Cited
EP0014683A1 Cited
US4321374A Cited
US4369321A Cited

USPTO Annuity & Maintenance Windows

Annuity Stage Window Opens Payment Deadline Surcharge Period Until Estimated Fee Status
3.5 Years (Year 4) 1987-08-28 1988-02-27 1988-08-28 $2000.00 Window Closed / Lapsed
7.5 Years (Year 8) 1991-08-28 1992-02-27 1992-08-28 $3760.00 Window Closed / Lapsed
11.5 Years (Year 12) 1995-08-28 1996-02-27 1996-08-28 $7700.00 Window Closed / Lapsed

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