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Polyurethanes prepared from polyoxyalkylenes containing alkaline catalyst residues chelated with benzoic acid derivatives

Assignee: BASF Corp
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Filing: 1983-10-14
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Granted: 1984-08-28
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Expires: 2003-10-14
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Abstract

Abstract The oxidation promoting harmful effects of the presence of an alkaline catalyst in a polyoxyalkylene can be eliminated and the product made more resistant to oxidation especially at elevated temperatures by the incorporation therein of soluble salts of certain benzoic acid derivatives. The soluble salts can be formed by reaction with the alkali or alkaline earth metal ion derived from the alkaline catalyst utilized in the polymerization of the polyoxyalkylene.

Inventors

  • 👤 Edward M. Dexheimer
  • 👤 Michael J. Anchor
  • 👤 Basil Thir
  • 👤 Stephen E. Eisenstein

Bibliographic Details

Application Number —
Jurisdiction US
Data Source google_patents
Last Synchronized 2026-11-08 04:53
CPC Classifications
D; D06; D06M; D06M13/00; D06M13/10; D06M13/184; D06M13/188; C; C08; C08G; C08G18/00; C08G18/06; C08G18/28; C08G65/00; C08G65/02; C08G65/30; D06M7/00; D06M2200/00; D06M2200/40

Claims Analysis

Total Claims: 9
Claim 1
Independent Claim 195 words
A polyurethane comprising the reaction product of at least one organic polyisocyanate with an organic compound containing at least two active hydrogen atoms as determined by the Zerewitinoff Method wherein said organic compound comprises at least one polyoxyalkylene containing an effective oxidation inhibiting amount of an alkali or alkaline earth metal salt of at least one acid having the formulas: ##STR2## wherein R 1 is selected from the group consisting of alkyl and alkenyl of up to 6 carbon atoms; R 2 is selected from the group consisting of hydroxyl, an alkyl ether residue having up to 4 carbon atoms, an hydroxyalkyl ether residue having up to 4 carbon atoms, and an alkenoxy or oxyalkanoic acid ester residue having up to 18 carbon atoms, and benzoyl; R 3 is individually selected from the group consisting of hydrogen, an alkyl ether residue having up to 4 carbon atoms, an hydroxyalkyl ether having up to 4 carbon atoms, an alkyl or alkenyl group having up to 6 carbon atoms, halogen, and carboxyl groups; and X is selected from the group consisting of (1) carbon and (2) carbon together with at least one of nitrogen, sulfur, or oxygen.
Claim 2
Dependent Claim 195 words
A polyurethane comprising the reaction product of at least one organic polyisocyanate with an organic compound containing at least two active hydrogen atoms as determined by the Zerewitinoff Method wherein said organic compound comprises at least one polyoxyalkylene containing an effective oxidation inhibiting amount of an alkali or alkaline earth metal salt of at least one acid having the formulas: ##STR2## wherein R 1 is selected from the group consisting of alkyl and alkenyl of up to 6 carbon atoms; R 2 is selected from the group consisting of hydroxyl, an alkyl ether residue having up to 4 carbon atoms, an hydroxyalkyl ether residue having up to 4 carbon atoms, and an alkenoxy or oxyalkanoic acid ester residue having up to 18 carbon atoms, and benzoyl; R 3 is individually selected from the group consisting of hydrogen, an alkyl ether residue having up to 4 carbon atoms, an hydroxyalkyl ether having up to 4 carbon atoms, an alkyl or alkenyl group having up to 6 carbon atoms, halogen, and carboxyl groups; and X is selected from the group consisting of (1) carbon and (2) carbon together with at least one of nitrogen, sulfur, or oxygen.
Claim 3
Dependent Claim 75 words
The composition of claim 1 wherein said polyoxyalkylene comprises the reaction product derived from at least one alkylene oxide having up to 4 carbon atoms selected from the group consisting of ethylene oxide, 1,2-propylene oxide, butylene oxide and tetrahydrofuran prepared by polymerizing at least one of said oxides in the presence of an alkaline catalyst selected from the group consisting of at least one of an alkali metal hydroxide and an alkaline earth metal hydroxide.
Claim 4
Dependent Claim 49 words
The composition of claim 2 wherein said polyoxyalkylene is derived from the reaction of 1,2-propylene oxide with an initiator selected from the group consisting of at least one of trimethylolpropane, pentaerythritol, ethylene glycol, propylene glycol and wherein said polyoxyalkylene has a molecular weight of about 400 to about 12,500.
Claim 5
Dependent Claim 94 words
The composition of claim 3 wherein said acid is selected from the group consisting of at least one of salicylic acid, acetylsalicylic acid, and ortho-hydroxycinnamic acid and said polyoxyalkylene comprises a graft copolymer dispersion prepared by the in situ polymerization in the presence of a free radical catalyst at a temperature of from 70° C. to about 170° C. of (a) an ethylenically unsaturated monomer or mixture of said monomers in (b) an essentially saturated polyol or (c) an unsaturated polyol containing from 0.10 mole to 0.70 mole of unsaturation per mole of polyol.
Claim 6
Dependent Claim 15 words
The composition of claim 4 wherein said monomer is a mixture of acrylonitrile and styrene.
Claim 7
Dependent Claim 13 words
The composition of claim 5 wherein said polyurethane is a flexible foam polyurethane.
Claim 8
Dependent Claim 13 words
The composition of claim 1 wherein said polyurethane is a rigid foam polyurethane.
Claim 9
Dependent Claim 12 words
The polyurethane of claim 1 wherein said polyurethane is a non-cellular polyurethane.

References Cited (Backward Citations)

US4426301A Cited
US4426300A Cited

USPTO Annuity & Maintenance Windows

Annuity Stage Window Opens Payment Deadline Surcharge Period Until Estimated Fee Status
3.5 Years (Year 4) 1987-08-28 1988-02-27 1988-08-28 $2000.00 Window Closed / Lapsed
7.5 Years (Year 8) 1991-08-28 1992-02-27 1992-08-28 $3760.00 Window Closed / Lapsed
11.5 Years (Year 12) 1995-08-28 1996-02-27 1996-08-28 $7700.00 Window Closed / Lapsed

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