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US4468445A Expired / Lapsed US ⏱️ 0.0 years remaining

Electrophotographic mixture containing toner particles and coated carrier particles

Assignee: Ricoh Co Ltd
•
Filing: 1983-01-31
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Granted: 1984-08-28
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Expires: 2003-01-31
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Abstract

Abstract Novel electrostatic developer compositions are provided comprising finely divided toner particles coated on carrier particles wherein the carrier particles comprise a solid core of an iron oxide and a coating of a thermoplastic consisting of a hydroxy ether copolymer of epichlorohydrin and 2,2-bis(p-hydroxy phenyl) propane.

Inventors

  • 👤 Paul P. Kelly
  • 👤 Trudy A. Bochantin Connor

Bibliographic Details

Application Number —
Jurisdiction US
Data Source google_patents
Last Synchronized 2026-10-29 19:37
CPC Classifications
G; G03; G03G; G03G9/00; G03G9/08; G03G9/10; G03G9/113; G03G9/1132; G03G9/1135

Claims Analysis

Total Claims: 13
Claim 1
Independent Claim 61 words
An electrophotographic developer composition comprising coated carrier particles, together with toner particles, the concentration of the toner particles being 1.5-3.5% by weight of the carrier particles, the coating on said carrier particles comprising a thermoplastic copolymer of epichlorohydrin and 2,2-bis-(p-hydroxyphenyl) propane or a hydroxyalkyl ether derivative thereof and said coating comprising from 0.1 to 1% by weight of said carrier particles.
Claim 2
Dependent Claim 61 words
An electrophotographic developer composition comprising coated carrier particles, together with toner particles, the concentration of the toner particles being 1.5-3.5% by weight of the carrier particles, the coating on said carrier particles comprising a thermoplastic copolymer of epichlorohydrin and 2,2-bis-(p-hydroxyphenyl) propane or a hydroxyalkyl ether derivative thereof and said coating comprising from 0.1 to 1% by weight of said carrier particles.
Claim 3
Dependent Claim 20 words
An electrophotographic developer composition of claim 1 further comprising a zinc stearate lubricant and silica as a cleaning assist agent.
Claim 4
Dependent Claim 35 words
An electrophotographic developer of claim 1 where said toner comprises about 91% by weight of a condensation product of 2,2-bis(4-hydroxyisopropoxyphenyl)-propane and fumaric acid and about 9% by weight carbon black with minor amounts of additives.
Claim 5
Dependent Claim 44 words
An electrophotographic developer of claim 1 where said toner comprises about 8.8% by weight of a condensation product of 2,2-bis-(4-hydroxyisopropoxyphenyl)-propane and fumaric acid; about 80% by weight bisphenol A epichlorohydrin epoxy thermoplastic resin and about 11% carbon black and a minor amount of additives.
Claim 6
Dependent Claim 34 words
An electrophotographic developer of claim 3 wherein the particle size of the toner is characterized by a cumulative number distribution of 85% greater than 5 microns, with an average size of approximately 8 microns.
Claim 7
Dependent Claim 34 words
An electrophotographic developer of claim 4 wherein the particle size of the toner is characterized by a cumulative number distribution of 85% greater than 5 microns, with an average size of approximately 8 microns.
Claim 8
Dependent Claim 54 words
A coated carrier for use in electrophotographic developer compositions comprising particles having an iron oxide core having a diameter in the range of about 30 to 1,000 microns coated with a thermoplastic hydroxyalkyl ether of epichlorohydrin and 2,2-bis(p-hydroxyphenyl) propane said thermoplastic hydroxyalkyl ether comprising from 0.1 to 1% by weight of said carrier particles.
Claim 9
Dependent Claim 54 words
A coated carrier for use in electrophotographic developer compositions comprising particles having an iron oxide core having a diameter in the range of about 30 to 1,000 microns coated with a thermoplastic hydroxyalkyl ether of epichlorohydrin and 2,2-bis(p-hydroxyphenyl) propane said thermoplastic hydroxyalkyl ether comprising from 0.1 to 1% by weight of said carrier particles.
Claim 10
Dependent Claim 19 words
A carrier according to claim 7 wherein said thermoplastic copolymer has a molecular weight range of 20,000 to 35,000.
Claim 11
Dependent Claim 22 words
A carrier according to claim 8 wherein said carrier particles comprise iron ferrite cores having a mean diameter of about 100 microns.
Claim 12
Dependent Claim 104 words
In an electrographic process wherein a visible image is produced by depositing toner particles from an electrophotographic developer composition onto a latent electrostatic image, said developer composition comprising coated carrier particles and toner particles, the improvement comprising the step of contacting said latent electrostatic images with a developer composition comprising finely divided toner particles coated on carrier particles wherein said carrier particles have an outer coating consisting of a polymeric material, said material selected from the group consisting of thermoplastic copolymers of epichlorohydrin and 2,2-bis-(p-hydroxyphenyl) propane and hydroxyalkyl derivatives thereof and said coating comprises from 0.1 to 1% by weight of said carrier particles.
Claim 13
Dependent Claim 104 words
In an electrographic process wherein a visible image is produced by depositing toner particles from an electrophotographic developer composition onto a latent electrostatic image, said developer composition comprising coated carrier particles and toner particles, the improvement comprising the step of contacting said latent electrostatic images with a developer composition comprising finely divided toner particles coated on carrier particles wherein said carrier particles have an outer coating consisting of a polymeric material, said material selected from the group consisting of thermoplastic copolymers of epichlorohydrin and 2,2-bis-(p-hydroxyphenyl) propane and hydroxyalkyl derivatives thereof and said coating comprises from 0.1 to 1% by weight of said carrier particles.

References Cited (Backward Citations)

US3965021A Cited
US3900588A Cited

USPTO Annuity & Maintenance Windows

Annuity Stage Window Opens Payment Deadline Surcharge Period Until Estimated Fee Status
3.5 Years (Year 4) 1987-08-28 1988-02-27 1988-08-28 $2000.00 Window Closed / Lapsed
7.5 Years (Year 8) 1991-08-28 1992-02-27 1992-08-28 $3760.00 Window Closed / Lapsed
11.5 Years (Year 12) 1995-08-28 1996-02-27 1996-08-28 $7700.00 Window Closed / Lapsed

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