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US4467073A Expired / Lapsed US ⏱️ 0.0 years remaining

Transparent anti-fog coating compositions

Assignee: Hydromer Inc
•
Filing: 1982-10-20
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Granted: 1984-08-21
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Expires: 2002-10-20
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Abstract

Abstract An anti-fog liquid coating composition comprises: a polymer which is polyvinylpyrrolidone, polydimethylacrylamide or a polyvinylpyrrolidone copolymer with a polymerizable alpha olefin free of functional groups reactive with isocyanates; a polyisocyanate prepolymer; a surfactant which will chemically bond to a reaction product of the polymer and prepolymer, and an organic solvent to form a solution of the foregoing ingredients. The invention includes a substrate having an anti-fog transparent coating comprising the reaction product of polyvinylpyrrolidione, a polyvinylpyrrolidone copolymer with a polymerizable alpha olefin free of functional groups reactive with isocyanates or polydimethylacrylamide with a polyisocyanate prepolymer, said reaction product being chemically bound to a surfactant. On curing, the surfactant is chemically combined with the hydrophilic polymer/isocyanate prepolymer composition and is not subject to extraction in any significant amount while still conferring improved fog resistance to the coated substrate.

Inventors

  • 👤 Walter S. Creasy

Bibliographic Details

Application Number —
Jurisdiction US
Data Source google_patents
Last Synchronized 2026-10-24 15:57
CPC Classifications
C; C08; C08G; C08G18/00; C08G18/06; C08G18/28; C08G18/40; C08G18/62; C08G18/6283; C08F; C08F8/00; C08F8/30; C08F8/32; C09; C09K; C09K3/00; C09K3/18

Claims Analysis

Total Claims: 16
Claim 1
Independent Claim 57 words
An anti-fog liquid coating composition comprising: a polymer which is polyvinylpyrrolidone, a polyvinylpyrrolidone copolymer with a polymerizable alpha olefin free of functional groups reactive with isocyanates or polydimethylacrylamide, a polyisocyanate prepolymer, a surfactant which will bond to a reaction product of the polymer and prepolymer, and an organic solvent to form a solution of the foregoing ingredients.
Claim 2
Dependent Claim 57 words
An anti-fog liquid coating composition comprising: a polymer which is polyvinylpyrrolidone, a polyvinylpyrrolidone copolymer with a polymerizable alpha olefin free of functional groups reactive with isocyanates or polydimethylacrylamide, a polyisocyanate prepolymer, a surfactant which will bond to a reaction product of the polymer and prepolymer, and an organic solvent to form a solution of the foregoing ingredients.
Claim 3
Dependent Claim 25 words
A coating composition in accordance with claim 1 in which the surfactant is ionic and complexes with a reaction product of the polymer and prepolymer.
Claim 4
Dependent Claim 25 words
A coating composition in accordance with claim 1 in which the surfactant is nonionic and reacts with a reaction product of the polymer and prepolymer.
Claim 5
Dependent Claim 40 words
A coating composition in accordance with claim 1 in which the surfactant is a combination of an ionic surfactant which complexes with a reaction product of the polymer and prepolymer and a nonionic surfactant which reacts with said reaction product.
Claim 6
Dependent Claim 48 words
A coating composition in accordance with any of claims 1, 2, 3 or 4 in which the ratio of the weight of the polymer to the weight of the isocyanate in the prepolymer is in the range of from about 10 to 1 to about 3 to 1.
Claim 7
Dependent Claim 74 words
A coating composition in accordance with any of claims 1, 2, 3 or 4 in which the ratio of the weight of the polymer to the weight of the isocyanate in the prepolymer is in the range of from about 10 to 1 to about 3 to 1 and the surfactant is present in an amount by weight of from about 0.1% to about 40% of the combined weights of the polymer and copolymer.
Claim 8
Dependent Claim 74 words
A coating composition in accordance with any of claims 1, 2, 3 or 4 in which the ratio of the weight of the polymer to the weight of the isocyanate in the prepolymer is in the range of from about 10 to 1 to about 3 to 1 and the surfactant is present in an amount by weight of from about 5% to about 25% of the combined weights of the polymer and copolymer.
Claim 9
Dependent Claim 48 words
A substrate, an anti-fog transparent coating on the substrate comprising the reaction product of a polymer of the group consisting of polyvinylpyrrolidone, a polyvinylpyrrolidone copolymer with a polymerizable alpha olefin free of functional groups reactive with isocyanates, or polydimethylacrylamide with a polyisocyanate prepolymer chemically bonded to a surfactant.
Claim 10
Dependent Claim 48 words
A substrate, an anti-fog transparent coating on the substrate comprising the reaction product of a polymer of the group consisting of polyvinylpyrrolidone, a polyvinylpyrrolidone copolymer with a polymerizable alpha olefin free of functional groups reactive with isocyanates, or polydimethylacrylamide with a polyisocyanate prepolymer chemically bonded to a surfactant.
Claim 11
Dependent Claim 18 words
The combination of claim 8 in which the surfactant is ionic and is complexed with the reaction product.
Claim 12
Dependent Claim 18 words
The combination of claim 8 in which the surfactant is nonionic and is reacted with the reaction product.
Claim 13
Dependent Claim 30 words
The combination of claim 8 in which the surfacant is a combination of an ionic surfactant complexed with the reaction product and a nonionic surfactant reacted with the reaction product.
Claim 14
Dependent Claim 45 words
The combination of any of claims 8, 9, 10 or 11 in which the ratio of the weight of the polymer to the weight of the isocyanate in the prepolymer is in the range of from about 10 to 1 to about 3 to 1.
Claim 15
Dependent Claim 71 words
The combination of any of claims 8, 9, 10 or 11 in which the ratio of the weight of the polymer to the weight of the isocyanate in the prepolymer is in the range of from about 10 to 1 to about 3 to 1 and the surfactant is present in an amount by weight of from about 0.1% to about 40% of the combined weights of the polymer and copolymer.
Claim 16
Dependent Claim 71 words
The combination of any of claims 8, 9, 10 or 11 in which the ratio of the weight of the polymer to the weight of the isocyanate in the prepolymer is in the range of from about 10 to 1 to about 3 to 1 and the surfactant is present in an amount by weight of from about 5% to about 25% of the combined weights of the polymer and copolymer.

References Cited (Backward Citations)

US4100309A Cited
US4254239A Cited

USPTO Annuity & Maintenance Windows

Annuity Stage Window Opens Payment Deadline Surcharge Period Until Estimated Fee Status
3.5 Years (Year 4) 1987-08-21 1988-02-20 1988-08-21 $2000.00 Window Closed / Lapsed
7.5 Years (Year 8) 1991-08-21 1992-02-20 1992-08-21 $3760.00 Window Closed / Lapsed
11.5 Years (Year 12) 1995-08-21 1996-02-20 1996-08-21 $7700.00 Window Closed / Lapsed

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