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US4466995A Expired / Lapsed US ⏱️ 0.0 years remaining

Control of ledge formation in aluminum cell operation

Assignee: Rio Tinto Aluminium Ltd
•
Filing: 1982-07-22
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Granted: 1984-08-21
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Expires: 2002-07-22
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Abstract

Abstract The application of a Refractory Hard Material coating composition to selected areas of the surface of an aluminum cell cathode permits tailoring or control of ledge formation during cell operation. Cell voltage improvements are also noted, resulting in more efficient cell performance.

Inventors

  • 👤 Larry G. Boxall
  • 👤 Douglas W. Townsend

Bibliographic Details

Application Number —
Jurisdiction US
Data Source google_patents
Last Synchronized 2026-11-07 22:45
CPC Classifications
C; C25; C25C; C25C3/00; C25C3/06; C25C3/08

Claims Analysis

Total Claims: 11
Claim 1
Independent Claim 93 words
A method for the control of ledge formation in a Hall-Heroult electrolytic cell for the production of aluminum, which method consisting essentially of applying to a limited defined area of the cathode surface directly below the anode of said cell a coating composition comprising Refractory Hard Material, thermosetting binder, a mix liquid, carbonaceous filler, and carbonaceous additive, and curing and carbonizing said composition to produce an adherent coating composition comprising Refractory Hard Material in a carbonaceous matrix bonded by amorphous carbon on said limited defined area of the cathode surface below the anode.
Claim 2
Independent Claim 93 words
A method for the control of ledge formation in a Hall-Heroult electrolytic cell for the production of aluminum, which method consisting essentially of applying to a limited defined area of the cathode surface directly below the anode of said cell a coating composition comprising Refractory Hard Material, thermosetting binder, a mix liquid, carbonaceous filler, and carbonaceous additive, and curing and carbonizing said composition to produce an adherent coating composition comprising Refractory Hard Material in a carbonaceous matrix bonded by amorphous carbon on said limited defined area of the cathode surface below the anode.
Claim 3
Dependent Claim 31 words
A method as set forth in claim 1, wherein the area of said coating constitutes from 50 percent to 100 percent of the cathode area beneath the anodes of said cell.
Claim 4
Dependent Claim 31 words
A method as set forth in claim 1, wherein the area of said coating constitutes from 70 percent to 100 percent of the cathode area beneath the anodes of said cell.
Claim 5
Dependent Claim 27 words
A method as set forth in claim 3, wherein said coating is characterized by an expansion of less than 0.2 percent between 800° C. and 1000° C.
Claim 6
Dependent Claim 38 words
A method as set forth in claim 4, wherein said carbon matrix has an ablation rate essentially equal to the combined rate of wear and dissolution of said Refractory Hard Material in the environment of said aluminum cell.
Claim 7
Dependent Claim 31 words
A method as set forth in claim 5, wherein said Refractory Hard Material is selected from the group consisting of titanium diboride, titanium carbide, zirconium diboride, zirconium carbide, and alloys thereof.
Claim 8
Dependent Claim 21 words
A method as set forth in claim 6, wherein said coating composition is applied to said cathode surface within said cell.
Claim 9
Dependent Claim 21 words
A method as set forth in claim 5, wherein said coating composition is applied to said cathode surface within said cell.
Claim 10
Dependent Claim 29 words
A method as set forth in claim 8, wherein the area of said coating constitutes at least 90 percent of the cathode area beneath the anodes of said cell.
Claim 11
Dependent Claim 16 words
A method as set forth in claim 9, wherein said Refractory Hard Material is titanium diboride.

References Cited (Backward Citations)

US3429759A Cited
US3400061A Cited
US3492208A Cited
US3661736A Cited
US3657592A Cited
US4308114A Cited

USPTO Annuity & Maintenance Windows

Annuity Stage Window Opens Payment Deadline Surcharge Period Until Estimated Fee Status
3.5 Years (Year 4) 1987-08-21 1988-02-20 1988-08-21 $2000.00 Window Closed / Lapsed
7.5 Years (Year 8) 1991-08-21 1992-02-20 1992-08-21 $3760.00 Window Closed / Lapsed
11.5 Years (Year 12) 1995-08-21 1996-02-20 1996-08-21 $7700.00 Window Closed / Lapsed

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