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US4465718A Expired / Lapsed US ⏱️ 0.0 years remaining

Poly (meth)acrylate compounds and their use in anaerobic adhesives and sealants

Assignee: Henkel AG and Co KGaA
•
Filing: 1983-11-29
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Granted: 1984-08-14
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Expires: 2003-11-29
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Abstract

Abstract This invention is directed to compounds of the formula ##STR1## wherein R is a radical derived from an organic diisocyanate or triisocyanate and n is 2 or 3, and the preparation thereof. The compounds are especially useful in anaerobic adhesives and sealants.

Inventors

  • 👤 Werner Gruber

Bibliographic Details

Application Number —
Jurisdiction US
Data Source google_patents
Last Synchronized 2026-10-24 12:33
CPC Classifications
C; C08; C08G; C08G18/00; C08G18/06; C08G18/08; C08G18/10; C08G18/83; C08G18/831; C09; C09J; C09J4/00

Claims Analysis

Total Claims: 8
Claim 1
Independent Claim 24 words
A compound of the formula ##STR5## wherein R is a radical derived from an organic diisocyanate or triisocyanate and n is 2 or 3.
Claim 2
Dependent Claim 24 words
A compound of the formula ##STR5## wherein R is a radical derived from an organic diisocyanate or triisocyanate and n is 2 or 3.
Claim 3
Dependent Claim 17 words
The compound of claim 1, wherein R is an aralkyl having from 7 to 19 carbon atoms.
Claim 4
Dependent Claim 65 words
A process for preparing a compound of claim 1, wherein a compound which contains more than one isocyanate group in the molecule and of which the molecular weight does not exceed 2500 is reacted with 2,3-epoxy-1-propanol in such a ratio that epoxy groups replace all the isocyanate groups and the resulting product is subsequently reacted with an equivalent quantity of methacrylic acid and/or acrylic acid.
Claim 5
Dependent Claim 65 words
The process of claim 3, wherein the compound containing more than one isocyanate group in the molecule has a molecular weight not exceeding 700 and is selected from the group consisting of tolylene diisocyanate, dimerized tolylene diisocyanate, diphenylmethane diisocyanate, naphthylene diisocyanate, hexamethylene diisocyanate, isophorone diisocyanate, trimethyl hexamethylene diisocyanate, triphenylmethane diisocyanate, dianisidine diisocyanate, tris-(4-isocyanatophenyl)-thiophosphate, and the adduct of 3 moles of tolylene diisocyanate with trimethyl propane.
Claim 6
Dependent Claim 43 words
The process of claim 3, wherein the compound containing more than one isocyanate group in the molecule is a reaction product of a hydroxyl-terminated polyester having a molecular weight of from about 500 to 2000 with a low molecular weight diisocyanate or triisocyanate.
Claim 7
Dependent Claim 18 words
An aerobic adhesive or sealant composition comprising an effective amount of at least one compound of claim 1.
Claim 8
Dependent Claim 44 words
The composition of claim 6 which contains from about 20 to 80% by weight of at least one said compound and from 20 to 80% by weight of compounds selected from the group consisting of (meth)acrylic acid and (meth)acrylic acid esters as polymerizable components.

References Cited (Backward Citations)

US2830038A Cited
US3484413A Cited
US3629187A Cited
US3814578A Cited

USPTO Annuity & Maintenance Windows

Annuity Stage Window Opens Payment Deadline Surcharge Period Until Estimated Fee Status
3.5 Years (Year 4) 1987-08-14 1988-02-13 1988-08-14 $2000.00 Window Closed / Lapsed
7.5 Years (Year 8) 1991-08-14 1992-02-13 1992-08-14 $3760.00 Window Closed / Lapsed
11.5 Years (Year 12) 1995-08-14 1996-02-13 1996-08-14 $7700.00 Window Closed / Lapsed

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