Antistatic films

Claim 2

A coating composition comprising 1 to 95 weight percent of a hydrolyzate of a hydroxyorganosilane and 5 to 99 weight percent of an aqueous solvent, said hydroxyorganosilane having the general formula: R.sup.1 --Si(OR.sup.2).sub.3 wherein R 1 is a di-hydroxy- or polyhydroxy-substituted organic group selected from: (a) alkyl groups containing from 2 to about 8 carbon atoms and substituted by 2 to 7 hydroxy groups, with any single carbon atom having at most one hydroxy group attached; (b) alkyl groups and cyclic alkyl groups having 2 to 20 carbon atoms, which carbon chain may be interrupted by one or more oxygen atoms and containing at least two hydroxyl groups per 8 carbon atoms with any single carbon atom having at most one hydroxy group attached; (c) aralkyl or alkaryl groups containing 7 to 10 carbon atoms, said aralkyl or alkaryl group having 2 to 8 hydroxy groups, with any single carbon atom having at most one hydroxy group attached; (d) alkenyl groups containing 4 to 8 carbon atoms and 2 to 5 hydroxy groups with any single carbon atom having at most one hydroxy group attached; (e) cyclic or alkyl-substituted cyclic groups having 3 to 8 carbon atoms and substituted by 2 to 7 hydroxy groups, with any single carbon atom having at most one hydroxy group attached; and R 2 is selected from: (a) hydrogen, and (b) any organic group such that the --Si(OR 2 ) 3 moiety is hydrolyzable.

Claim 3

A coating composition comprising: (1) 1 to 95 weight percent of a hydrolyzate of a hydroxyorganosilane and 5 to 99 weight percent of an aqueous solvent, said hydroxyorganosilane having the general formula: R.sup.1 --Si(OR.sup.2).sub.3 wherein R 1 is a hydroxy or polyhydroxy-substituted organic group selected from: (a) alkyl groups containing from about 2 to about 8 carbon atoms and substituted by 1 to 7 hydroxy groups, with any single carbon atom having at most one hydroxy group attached; (b) alkyl groups and cyclic alkyl groups having up to 20 carbon atoms, which carbon chain may be interrupted by one or more oxygen atoms and containing at least one hydroxyl group per 8 carbon atoms with any single carbon atom having at most one hydroxy group attached; (c) aralkyl or alkaryl groups containing 7 to 10 carbon atoms, said aralkyl or alkaryl group having 1 to 8 hydroxy groups, with a single carbon atom having at most one hydroxy group attached; (d) alkenyl groups containing up to 8 carbon atoms and 1 to 5 hydroxy groups with any single carbon atom having at most one hydroxy group attached; (e) cyclic or alkyl-substituted cyclic groups having 3 to 8 carbon atoms and substituted by 1 to 7 hydroxy groups, with any single carbon atom having at most one hydroxy group attached; and R 2 is selected from: (a) hydrogen, and (b) any organic group such that the Si(OR 2 ) 3 moiety is hydrolyzable; and (2) in the range of 0.001 to 50 weight percent of a silanol-sulfonate compound having the general formula: ##STR13## wherein Q is selected from hydroxyl, alkyl groups containing from 1 to about 4 carbon atoms and alkoxy groups containing from 1 to about 4 carbon atoms; X is an organic linking group containing up to 10 carbon atoms; Y is an organic or inorganic cation; r is equal to the valence of Y; and n is 1 or 2, with the proviso that the mole ratio of silanol-sulfonate compound to organosilane is less than 5 to 1.

Claim 4

A coating composition comprising: (1) 1 to 95 weight percent of a hydrolyzate of a hydroxyorganosilane and 5 to 99 weight percent of an aqueous solvent, said hydroxyorganosilane having the general formula: R.sup.1 --Si(OR.sup.2).sub.3 wherein R 1 is a hydroxy or polyhydroxy-substituted organic group selected from: (a) alkyl groups containing from about 2 to about 8 carbon atoms and substituted by 1 to 7 hydroxy groups, with any single carbon atom having at most one hydroxy group attached; (b) alkyl groups and cyclic alkyl groups having up to 20 carbon atoms, which carbon chain may be interrupted by one or more oxygen atoms and containing at least one hydroxyl group per 8 carbon atoms with any single carbon atom having at most one hydroxy group attached; (c) aralkyl or alkaryl groups containing 7 to 10 carbon atoms, said aralkyl or alkaryl group having 1 to 8 hydroxy groups, with a single carbon atom having at most one hydroxy group attached; (d) alkenyl groups containing up to 8 carbon atoms and 1 to 5 hydroxy groups with any single carbon atom having at most one hydroxy group attached; (e) cyclic or alkyl-substituted cyclic groups having 3 to 8 carbon atoms and substituted by 1 to 7 hydroxy groups, with any single carbon atom having at most one hydroxy group attached; and R 2 is selected from: (a) hydrogen, and (b) any organic group such that the Si(OR 2 ) 3 moiety is hydrolyzable; and (2) in the range of 0.001 to 50 weight percent of a silanol-sulfonate compound having the general formula: ##STR13## wherein Q is selected from hydroxyl, alkyl groups containing from 1 to about 4 carbon atoms and alkoxy groups containing from 1 to about 4 carbon atoms; X is an organic linking group containing up to 10 carbon atoms; Y is an organic or inorganic cation; r is equal to the valence of Y; and n is 1 or 2, with the proviso that the mole ratio of silanol-sulfonate compound to organosilane is less than 5 to 1.

Claim 5

The coating composition according to claims 1 or 2 wherein R 1 is selected from (1) a hydroxyalkyl group having 2 to 4 carbon atoms, and (2) a dihydroxy-substituted alkyl group having 4 to 8 carbon atoms whose chain may be interrupted by 1 or 2 oxygen atoms.

Claim 6

The coating composition according to claim 2 wherein said hydroxyorganosilane or precursor is selected from the group consisting of: ##STR14##

Claim 7

The coating composition according to claims 1 or 2 wherein R 2 is selected from the group containing straight chain or branched alkyl, alkaryl, acyl, and aroyl groups having up to 8 carbon atoms.

Claim 8

The coating composition according to claim 2 wherein X is selected from alkylene, hydroxy-substituted alkylene, and mono-oxa alkylene groups having at least two or more methylene groups; cycloalkylene groups; alkyl-substituted cycloalkylene groups; hydroxy-substituted alkylene groups; hydroxy-substituted mono-oxa alkylene groups; divalent hydrocarbon groups having mono- or poly-oxa backbone substitution; divalent hydrocarbon groups having mono-thia backbone substitution; divalent hydrocarbon groups having mono-thia backbone substitution; divalent hydrocarbon groups having mono-oxa-thia backbone substitution; divalent hydrocarbon groups having dioxo-thia backbone substitution; arylene groups; arylalkylene groups; alkylarylene groups; substituted alkylarylene groups; and alkylarylalkylene groups.

Claim 9

The coating composition according to claim 2 wherein Y is selected from the class consisting of hydrogen, alkali metals, aklaline earth metals, transition metals, heavy metals, organic cations of protonated weak bases having an average molecular weight of less than 400 and a pK a of less than 11, and organic cations of strong organic basis having an average molecular weight of less than 400 and a pK a of greater than 11.

Claim 10

The coating composition according to claim 2 wherein said sulfonate moiety is replaced by a phosphonate moiety.

Claim 11

The coating composition according to claim 2 wherein said silanol-sulfonate compound is replaced by a monomeric or polymeric alkyl-, aryl-, alkaryl-, and aralkyl-sulfonic acid, or salt thereof, having up to 20 carbon atoms per sulfonic acid group.

Claim 12

The coating composition according to claim 7 wherein said silanol-sulfonate is selected from the group of compounds having the formulae ##STR15## wherein Q' is an alkyl group having 1 to 4 carbon atoms and X is an organic linking group containing up to 10 carbon atoms.

Claim 13

The coating composition according to claim 10 wherein said silanol-sulfonate is selected from the group of compounds consisting of ##STR16##

Claim 14

The coating composition according to claims 1 or 3 further comprising 1 to 5 weight percent of the total reactive monomers of an acid catalyst.

Claim 15

The coating composition according to claim 12 wherein said acid catalyst is hexafluoroantimonic acid hexahydrate.

Claim 16

The coating composition according to claim 12 wherein said acid catalyst is a photoactivatable initiator.

Claim 17

The coating composition according to claims 1 or 3 further comprising 0.001 to 95 weight percent of additives selected from viscosity modifiers, hardness modifiers, pigments, fillers, UV absorbers, colorants, and leveling agents.

Claim 18

The coating composition according to claim 15 wherein said additives further comprise at least one of co-reactive organosilane monomers, oligomers, and polymers.

Claim 19

The coating composition according to claim 16 wherein said organosilane monomer or oligomer is selected from methylsilanetriol and oligomers, orthosilicates, and hydroxyorganosilanes having the formula: ##STR17## wherein R 1 and R 2 are defined above; R 3 is a lower alkyl group having 1 to 4 carbon atoms or phenyl; a=2 or 3; b=1 or 2; with the proviso that (a+b) is equal to 3 or 4.

Claim 20

The cured polymeric product according to claim 1 cured in situ by at least one curing source selected from heat and radiation.

Claim 21

The cured polymeric product of claims 1 or 2.