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US4463036A Expired / Lapsed US ⏱️ 0.0 years remaining

Process for imparting hydrophilicity to fabric

Assignee: Union Carbide Corp
•
Filing: 1982-12-29
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Granted: 1984-07-31
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Expires: 2002-12-29
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Abstract

Abstract A process for imparting hydrophilicity to fabric which comprises treating the fabric with a composition comprising a copolymer of an N-(oxymethyl)-acrylamide grafted onto a poly(oxyalkylene) backbone and an acid catalyst to facilitate cross-linking of the graft copolymer on the fabric surface and drying said fabric at a temperature sufficient to cure the graft copolymer.

Inventors

  • 👤 George E. Totten
  • 👤 Angelo J. Sabia

Bibliographic Details

Application Number —
Jurisdiction US
Data Source google_patents
Last Synchronized 2026-11-03 16:00
CPC Classifications
D; D06; D06M; D06M15/00; D06M15/19; D06M15/37; D06M15/53

Claims Analysis

Total Claims: 6
Claim 1
Independent Claim 257 words
A process to impart durable hydrophilicity to fabric which comprises: (a) treating a polyester fabric with a neat composition, solution or dispersion containing: (i) at least about 0.001% by solution weight or neat composition weight of an acid catalyst selected from the group consisting of p-toluene sulfonic acid and zinc fluoroborate, and (ii) from about 0.1% to about 5% by solution weight or neat composition weight of a graft copolymer prepared by grafting to a poly(oxyalkylene) from about 0.5% to about 50% by graft copolymer weight of an N-(oxymethyl)-acrylamide having the formula: ##STR3## wherein R 1 , R 2 , R 3 and R 4 are hydrogen or monovalent hydrocarbon radicals containing from 1 to 6 carbon atoms each and may be the same or different to a poly(oxyalkylene) of the formula: R.sup.5 [(OC.sub.2 H.sub.4).sub.x (OC.sub.3 H.sub.6).sub.z OR.sup.6 ].sub.a wherein R 5 is a hydrocarbon radical having a valence of a and containing up to about 21 carbon atoms, a is an integer having a value between 1 and 4, R 6 is a hydrogen atom or hydrocarbon radical containing up to about 6 carbon atoms and x is an integer having a value from about 2 to about 5000, and z is an integer having a value from about zero to about 5000; (b) drying said treated textile fabric at a temperature between about 100° C. and about 170° C. to produce a fabric having a wettability of no more than 40 seconds after 20 launderings in accordance with AATCC Test Methods 39-1977 and 130-1977, respectively.
Claim 2
Dependent Claim 257 words
A process to impart durable hydrophilicity to fabric which comprises: (a) treating a polyester fabric with a neat composition, solution or dispersion containing: (i) at least about 0.001% by solution weight or neat composition weight of an acid catalyst selected from the group consisting of p-toluene sulfonic acid and zinc fluoroborate, and (ii) from about 0.1% to about 5% by solution weight or neat composition weight of a graft copolymer prepared by grafting to a poly(oxyalkylene) from about 0.5% to about 50% by graft copolymer weight of an N-(oxymethyl)-acrylamide having the formula: ##STR3## wherein R 1 , R 2 , R 3 and R 4 are hydrogen or monovalent hydrocarbon radicals containing from 1 to 6 carbon atoms each and may be the same or different to a poly(oxyalkylene) of the formula: R.sup.5 [(OC.sub.2 H.sub.4).sub.x (OC.sub.3 H.sub.6).sub.z OR.sup.6 ].sub.a wherein R 5 is a hydrocarbon radical having a valence of a and containing up to about 21 carbon atoms, a is an integer having a value between 1 and 4, R 6 is a hydrogen atom or hydrocarbon radical containing up to about 6 carbon atoms and x is an integer having a value from about 2 to about 5000, and z is an integer having a value from about zero to about 5000; (b) drying said treated textile fabric at a temperature between about 100° C. and about 170° C. to produce a fabric having a wettability of no more than 40 seconds after 20 launderings in accordance with AATCC Test Methods 39-1977 and 130-1977, respectively.
Claim 3
Dependent Claim 15 words
The process of claim 1 wherein said optionally substituted N-oxymethyl derivative of acrylamide is N-methylol-acrylamide.
Claim 4
Dependent Claim 16 words
The process of claim 1 wherein said optionally substituted N-(oxymethyl) derivative of acrylamide is N-(isobutoxymethyl) acrylamide.
Claim 5
Dependent Claim 32 words
The process of claim 1 wherein said poly(oxyalkylene) is made by reacting an alkylene oxide, or mixtures thereof, with an aliphatic unsaturation and which contains from one to four active hydrogen atoms.
Claim 6
Dependent Claim 16 words
The process of claim 1 wherein the poly(oxyalkylene) is poly(oxyethylene), poly(oxypropylene) or mixtures or copolymers thereof.

References Cited (Backward Citations)

US3213053A Cited
FR1427787A Cited
CH513282A Cited

USPTO Annuity & Maintenance Windows

Annuity Stage Window Opens Payment Deadline Surcharge Period Until Estimated Fee Status
3.5 Years (Year 4) 1987-07-31 1988-01-30 1988-07-31 $2000.00 Window Closed / Lapsed
7.5 Years (Year 8) 1991-07-31 1992-01-30 1992-07-31 $3760.00 Window Closed / Lapsed
11.5 Years (Year 12) 1995-07-31 1996-01-30 1996-07-31 $7700.00 Window Closed / Lapsed

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