US4460723A
Expired / Lapsed
US
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Asphalt compositions
Assignee: Phillips Petroleum Co
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Filing: 1982-11-29
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Granted: 1984-07-17
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Expires: 2002-11-29
Abstract
Abstract Stabilization of asphalt and asphalt rubber compositions against degradation, e.g., viscosity increase by addition of a finite small but effective viscosity stabilizing amount of at least one alkali metal salt of an organic or inorganic acid.
Inventors
- 👤 Kent W. Rollmann
Bibliographic Details
Application Number
—
Jurisdiction
US
Data Source
google_patents
Last Synchronized
2026-11-01 04:39
CPC Classifications
C; C08; C08K; C08K5/00; C08K5/04; C08K5/09; C08K5/098; C08K3/00; C08K3/28; C08K5/36; C08K5/41; C08K5/42; C08L; C08L95/00
Claims Analysis
Total Claims: 25
Claim 1
Independent Claim
106 words
An asphalt composition stabilized against viscosity increases at elevated temperatures comprising asphalts substantially free of rubber, susceptible to viscosity increase and a finite small but effective viscosity stabilizing amount of at least one of (a) alkali metal salts of aliphatic carboxylic acids having from 1-20 carbon atoms per molecule (b) lithium and sodium salts of aromatic carboxylic acids having from 7-20 carbon atoms per molecule (c) lithium and sodium salts of cycloaliphatic carboxylic acids having from 4-20 carbon atoms per molecule (d) lithium and sodium salts of aromatic sulfonic acids having from 6-20 carbon atoms per molecule and (e) lithium and sodium salts of nitric acid.
Claim 2
Dependent Claim
106 words
An asphalt composition stabilized against viscosity increases at elevated temperatures comprising asphalts substantially free of rubber, susceptible to viscosity increase and a finite small but effective viscosity stabilizing amount of at least one of (a) alkali metal salts of aliphatic carboxylic acids having from 1-20 carbon atoms per molecule (b) lithium and sodium salts of aromatic carboxylic acids having from 7-20 carbon atoms per molecule (c) lithium and sodium salts of cycloaliphatic carboxylic acids having from 4-20 carbon atoms per molecule (d) lithium and sodium salts of aromatic sulfonic acids having from 6-20 carbon atoms per molecule and (e) lithium and sodium salts of nitric acid.
Claim 3
Dependent Claim
121 words
An asphalt composition stabilized against viscosity increases at elevated temperatures comprising asphalts, substantially free of rubber, susceptible to viscosity increase and at least one of (a) alkali metal salts of aliphatic carboxylic acids having from 1-20 carbon atoms per molecule (b) lithium and sodium salts of aromatic carboxylic acids having from 7-20 carbon atoms per molecule (c) lithium and sodium salts of cycloaliphatic carboxylic acids having from 4-20 carbon atoms per molecule (d) lithium and sodium salts of aromatic sulfonic acids having from 6-20 carbon atoms per molecule and (e) lithium and sodium salts of nitric acid, wherein the amount of said salt present ranges from about 0.05 to about 2 weight percent based on the total weight of the composition.
Claim 4
Dependent Claim
121 words
An asphalt composition stabilized against viscosity increases at elevated temperatures comprising asphalts, substantially free of rubber, susceptible to viscosity increase and at least one of (a) alkali metal salts of aliphatic carboxylic acids having from 1-20 carbon atoms per molecule (b) lithium and sodium salts of aromatic carboxylic acids having from 7-20 carbon atoms per molecule (c) lithium and sodium salts of cycloaliphatic carboxylic acids having from 4-20 carbon atoms per molecule (d) lithium and sodium salts of aromatic sulfonic acids having from 6-20 carbon atoms per molecule and (e) lithium and sodium salts of nitric acid, wherein the amount of said salt present ranges from about 0.05 to about 2 weight percent based on the total weight of the composition.
Claim 5
Dependent Claim
13 words
A composition according to claim 1 wherein said salts are alkali metal acetates.
Claim 6
Dependent Claim
22 words
A composition according to claim 2 wherein said salts is present in amounts ranging from about 0.2 to about 0.8 weight percent.
Claim 7
Dependent Claim
119 words
A process for stabilizing the viscosity of asphalt comprising incorporating into an asphalt, substantially free of rubber, susceptible to viscosity increase when exposed to elevated temperatures a finite small but effective stabilizing amount of at least one of (a) alkali metal salts of aliphatic carboxylic acids having from 1-20 carbon atoms per molecule (b) lithium and sodium salts of aromatic carboxylic acids having from 7-20 carbon atoms per molecule (c) lithium and sodium salts of cycloaliphatic carboxylic acids having from 4-20 carbon atoms per molecule (d) lithium and sodium salts of aromatic sulfonic acids having from 6-20 carbon atoms per molecule and (e) lithium and sodium salts of nitric acid, (f) lithium and sodium salts of hydrogen halide acids.
Claim 8
Dependent Claim
119 words
A process for stabilizing the viscosity of asphalt comprising incorporating into an asphalt, substantially free of rubber, susceptible to viscosity increase when exposed to elevated temperatures a finite small but effective stabilizing amount of at least one of (a) alkali metal salts of aliphatic carboxylic acids having from 1-20 carbon atoms per molecule (b) lithium and sodium salts of aromatic carboxylic acids having from 7-20 carbon atoms per molecule (c) lithium and sodium salts of cycloaliphatic carboxylic acids having from 4-20 carbon atoms per molecule (d) lithium and sodium salts of aromatic sulfonic acids having from 6-20 carbon atoms per molecule and (e) lithium and sodium salts of nitric acid, (f) lithium and sodium salts of hydrogen halide acids.
Claim 9
Dependent Claim
27 words
A process according to claim 5 wherein said stabilizing amount ranges from about 0.05 to about 2 weight percent based on the total weight of the composition.
Claim 10
Dependent Claim
14 words
A process according to claim 5 wherein said salt is an alkali metal acetate.
Claim 11
Dependent Claim
50 words
A process according to claim 5 wherein said salt is an alkali metal salt of hydroxy substituted polycarboxylic acids having from 4 to 20 carbon atoms per molecule and is present in amounts ranging from about 0.2 to about 0.8 weight percent based on the total weight of the composition.
Claim 12
Dependent Claim
12 words
A process according to claim 8 wherein said salt is sodium tartrate.
Claim 13
Dependent Claim
112 words
An asphalt composition stabilized against viscosity increases at elevated temperatures comprising asphalts susceptible to viscosity increase and a finite small but effective viscosity stabilizing amount of at least one of (a) lithium, sodium, and potassium salts of aliphatic carboxylic acids having from 1-20 carbon atoms per molecule, (b) lithium and sodium salts of aromatic carboxylic acids having from 7-20 carbon atoms per molecule, (c) lithium and sodium salts of cycloaliphatic acids having from 4-20 carbon atoms per molecule, (d) lithium and sodium salts of aromatic sulfonic acids having from 6-20 carbon atoms per molecule, and (e) lithium and sodium salts of nitric acid and wherein the composition additionally contains a rubbery polymer.
Claim 14
Dependent Claim
112 words
An asphalt composition stabilized against viscosity increases at elevated temperatures comprising asphalts susceptible to viscosity increase and a finite small but effective viscosity stabilizing amount of at least one of (a) lithium, sodium, and potassium salts of aliphatic carboxylic acids having from 1-20 carbon atoms per molecule, (b) lithium and sodium salts of aromatic carboxylic acids having from 7-20 carbon atoms per molecule, (c) lithium and sodium salts of cycloaliphatic acids having from 4-20 carbon atoms per molecule, (d) lithium and sodium salts of aromatic sulfonic acids having from 6-20 carbon atoms per molecule, and (e) lithium and sodium salts of nitric acid and wherein the composition additionally contains a rubbery polymer.
Claim 15
Dependent Claim
29 words
A composition according to claim 10 wherein the amount of rubber present in said composition ranges from about 1-30 weight percent based on the total weight of said composition.
Claim 16
Dependent Claim
30 words
A composition according to claim 10 wherein the amount of said salt present ranges from about 0.05 to about 2 weight percent based on the total weight of the composition.
Claim 17
Dependent Claim
15 words
A composition according to claim 10 wherein said rubbery polymer is a butadiene/styrene block copolymer.
Claim 18
Dependent Claim
23 words
A composition according to claim 10 wherein said salts are lithium, sodium or potassium acetates and said rubber is a butadiene/styrene block copolymer.
Claim 19
Dependent Claim
14 words
A composition according to claim 10 wherein said alkali metal salt is sodium tartrate.
Claim 20
Dependent Claim
98 words
A process for stabilizing the viscosity of asphalts comprising incorporating into an asphalt susceptible to viscosity increase when exposed to elevated temperatures a finite small but effective stabilizing amount of at least one of (a) lithium, sodium, and potassium salts of aliphatic carboxylic acids having from 1-20 carbon atoms per molecule, (b) lithium and sodium salts of aromatic carboxylic acids having from 7-20 carbon atoms per molecule, (c) lithium and sodium salts of cycloaliphatic acids having from 4-20 carbon atoms per molecule, (d) lithium and sodium salts of aromatic sulfonic acids having from 6-20 carbon atoms per molecule,
Claim 21
Dependent Claim
98 words
A process for stabilizing the viscosity of asphalts comprising incorporating into an asphalt susceptible to viscosity increase when exposed to elevated temperatures a finite small but effective stabilizing amount of at least one of (a) lithium, sodium, and potassium salts of aliphatic carboxylic acids having from 1-20 carbon atoms per molecule, (b) lithium and sodium salts of aromatic carboxylic acids having from 7-20 carbon atoms per molecule, (c) lithium and sodium salts of cycloaliphatic acids having from 4-20 carbon atoms per molecule, (d) lithium and sodium salts of aromatic sulfonic acids having from 6-20 carbon atoms per molecule,
Claim 22
Dependent Claim
38 words
(e) lithium and sodium salts of nitric acid (f) lithium and sodium salts of hydrogen halide acids wherein said asphalt further contains from about 1-30 weight percent based on the total weight of the composition a rubbery polymer.
Claim 23
Dependent Claim
38 words
(e) lithium and sodium salts of nitric acid (f) lithium and sodium salts of hydrogen halide acids wherein said asphalt further contains from about 1-30 weight percent based on the total weight of the composition a rubbery polymer.
Claim 24
Dependent Claim
15 words
A process according to claim 16 wherein said salt is lithium sodium or potassium acetate.
Claim 25
Dependent Claim
27 words
A process according to claim 16 wherein said stabilizing amount ranges from about 0.05 to about 2 weight percent based on the total weight of the composition.
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USPTO Annuity & Maintenance Windows
| Annuity Stage | Window Opens | Payment Deadline | Surcharge Period Until | Estimated Fee | Status |
|---|---|---|---|---|---|
| 3.5 Years (Year 4) | 1987-07-17 | 1988-01-16 | 1988-07-17 | $2000.00 | Window Closed / Lapsed |
| 7.5 Years (Year 8) | 1991-07-17 | 1992-01-16 | 1992-07-17 | $3760.00 | Window Closed / Lapsed |
| 11.5 Years (Year 12) | 1995-07-17 | 1996-01-16 | 1996-07-17 | $7700.00 | Window Closed / Lapsed |