US4196115A
Expired / Lapsed
US
⏱️ 0.0 years remaining
Blends of different conjugated diene/monovinyl aromatic copolymers in bituminous based roofing and waterproofing membranes
Assignee: Phillips Petroleum Co
•
Filing: 1978-09-14
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Granted: 1980-04-01
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Expires: 1998-09-14
Abstract
Abstract A radial conjugated diene/monovinyl aromatic copolymer having a weight average molecular weight (M w ) above 200,000 and a conjugated diene/monovinyl aromatic ratio of 50/50 to 85/15 is used together with a conjugated diene/monovinyl aromatic copolymer having an M w below 200,000 and being radial or linear, with same conjugated diene/monovinyl aromatic weight ratios as earlier given, in an asphalt-containing composition to yield desirable high as well as low temperature properties.
Inventors
- 👤 Clarence R. Bresson
Bibliographic Details
Application Number
—
Jurisdiction
US
Data Source
google_patents
Last Synchronized
2026-10-24 09:44
CPC Classifications
E; E04; E04D; E04D5/00; E04D5/06; C; C08; C08L; C08L95/00; C09; C09D; C09D153/00; C09D153/02
Claims Analysis
Total Claims: 11
Claim 1
Independent Claim
254 words
A composition, suitable for use as a roofing material or as a waterproofing membrane having both high and low temperature desirable properties which comprises a. A first radial conjugated diene/monovinyl aromatic copolymer having a wt. average molecular weight (M w ) above 200,000 and a monomer ratio of from about 50/50 to about 85/15, represented by at least one of the formulas (A-B).sub.x Y or (A-B-A).sub.x Y wherein A represents an non-elastomeric poly(monovinyl aromatic) block containing 8-18 carbon atoms per molecule and B represents an elastomeric poly(conjugated diene) block, said diene contains 4 to 12 carbon atoms per molecule, Y is at least one atom derived from a polyfunctional treating agent used in the formation of the radial polymers and x represents the number of functional groups of said polyfunctional treating agent and is an integer equal to at least 3; b. A second conjugated diene monovinyl aromatic copolymer having an M w below 200,000 and being at least one of radial and linear, when radial the formula thereof being as above given in this claim and it having an M w in the range from 100,000 up to 200,000, and when linear represented by the formula AB, wherein A and B are as above given in this claim and having an M w in the range of from about 100,000 up to 200,000, the ratio of the high and low M w copolymers being in the range 13/1 to 1/13, and c. An asphalt having a penetration grade below about 300 (ASTM D5).
Claim 2
Dependent Claim
18 words
A composition according to claim 1 wherein the second copolymer when linear has an M w below 100,000.
Claim 3
Dependent Claim
55 words
A composition according to claim 1 wherein the final composition is made up as follows: ______________________________________
Operating Range
Ingredients Parts Per Hundred Asphalt
Wt. %
______________________________________
Asphalt 100 55-97
Copolymer Blend
3-25 1.6-20
a. High M.sub.w Copolymer
0.2-24.8 1.4-18.5
b. Low M.sub.w Copolymer
0.2-24.8 1.4-18.6
Extender Oil 0-25 0-20
Fillers, antioxidants,
0-55 0-30
etc.
______________________________________
Claim 4
Dependent Claim
55 words
A composition according to claim 2 wherein the final composition is made up as follows: ______________________________________
Operating Range
Ingredients Parts Per Hundred Asphalt
Wt. %
______________________________________
Asphalt 100 55-97
Copolymer Blend
3-25 1.6-20
a. High M.sub.w Copolymer
0.2-24.8 1.4-18.5
b. Low M.sub.w Copolymer
0.2-24.8 1.4-18.6
Extender Oil 0-25 0-20
Fillers, antioxidants,
0-55 0-30
etc.
______________________________________
Claim 5
Dependent Claim
173 words
A composition according to claim 1 wherein the composition passes the following tests a. heat asphalt to about 149° C., charge and mix therewith the remaining ingredients of the composition, introduce the rubber in about 5-15 minutes, the lower end of the time range being applicable for pellets and the upper end for crumb or ground rubber and spreading with a spatula on paper a portion of the hot mix, there should be no lumps in the spread, b. a viscosity of the composition at 180° C. in the range from about 500 to about 5,000 cps c. flow tests ASTM D-1191--flows of less than 10 mm at 70° C. and less than about 50 mm at 100° C., d. mandrel test ASTM D-1737 but not coated on a plate and conditioning the specimen and mandrel in a deep freeze at -25° C. for 16 hours and bending specimen over the mandrel through a 180 degrees in one second, with no breaking or cracking over a 25 mm and a 6 mm mandrel.
Claim 6
Dependent Claim
18 words
A composition according to claim 1 wherein the conjugated diene is 1,3-butadiene and the monovinyl aromatic is styrene.
Claim 7
Dependent Claim
26 words
A composition according to claim 1 wherein the ratio of the high M w copolymer to the lower M w copolymer is in the range 1/6-6/1.
Claim 8
Dependent Claim
26 words
A composition according to claim 1 wherein the ratio of the high M w copolymer to the lower M w copolymer is in the range 2/1-1/6.
Claim 9
Dependent Claim
42 words
A method for producing a composition suitable for use as a roofing material or as a waterproofing membrane according to claim 1 which comprises admixing the first and second conjugated diene/monovinyl aromatic copolymers of said claim with an asphalt of said claim.
Claim 10
Dependent Claim
18 words
A method according to claim 9 wherein the conjugated diene is 1,3-butadiene and the monovinyl aromatic is styrene.
Claim 11
Dependent Claim
18 words
A method according to claim 9 wherein the conjugated diene is isoprene and the monovinyl aromatic is styrene.
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USPTO Annuity & Maintenance Windows
| Annuity Stage | Window Opens | Payment Deadline | Surcharge Period Until | Estimated Fee | Status |
|---|---|---|---|---|---|
| 3.5 Years (Year 4) | 1983-04-01 | 1983-10-01 | 1984-04-01 | $2000.00 | Window Closed / Lapsed |
| 7.5 Years (Year 8) | 1987-04-01 | 1987-10-01 | 1988-04-01 | $3760.00 | Window Closed / Lapsed |
| 11.5 Years (Year 12) | 1991-04-01 | 1991-10-01 | 1992-04-01 | $7700.00 | Window Closed / Lapsed |