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US4460622A Expired / Lapsed US ⏱️ 0.0 years remaining

Electroconductive paste to be baked on ceramic bodies to provide capacitors, varistors or the like

Assignee: Taiyo Yuden Co Ltd
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Filing: 1983-06-06
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Granted: 1984-07-17
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Expires: 2003-06-06
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Abstract

Abstract An electroconductive paste consists essentially of 100 parts by weight of zinc in finely divided form, from about 0.01 to 15.00 parts by weight of an organic titanium compound such as, typically, tetrakisstearoxytitanium, and a vehicle, such as alpha-terpineol containing ethylcellulose as an organic binder, for pasting the mixture of the zinc powder and the organic titanium compound. The paste may contain an additive or additives such as the oxides of some metallic elements. By being baked on ceramic bodies at a temperature above the melting point of zinc, the paste forms conductors or electrodes of ceramic capacitors, varistors or the like. The conductors or electrodes thus prepared from the zinc paste are approximately equivalent in electrical and mechanical properties to those fabricated from the familiar silver paste.

Inventors

  • 👤 Nobutatsu Yamaoka
  • 👤 Kazuo Sasazawa

Bibliographic Details

Application Number —
Jurisdiction US
Data Source google_patents
Last Synchronized 2026-10-29 13:07
CPC Classifications
H; H01; H01G; H01G4/00; H01G4/002; H01G4/005; H01G4/008; H01G4/0085; H01B; H01B1/00; H01B1/14; H01B1/16; H01C; H01C17/00; H01C17/28; H01C17/281; H01C17/283; H01C17/286; B; B22; B22F; B22F2998/00

Claims Analysis

Total Claims: 8
Claim 1
Independent Claim 127 words
A method of forming a conductive electrode on a ceramic substrate to form a capacitor or the like, comprising the steps of: applying an electroconductive paste to said ceramic substrate, said paste comprising about 100 parts of zinc powder, from about 0.01 to 15.00 parts by weight of an organic titanium compound, and an organic vehicle for pasting the mixture of the zinc powder and the organic titanium; baking said ceramic substrate with the paste thereon to drive off the organic vehicle, whereby said organotitanium compound inhibits the oxidation of said zinc during said baking step, so that the unoxidized interiors of the zinc particles expand, breaking the oxide coatings thereon and are fused to one another, whereby an electrical conductor is formed of said zinc powders.
Claim 2
Independent Claim 127 words
A method of forming a conductive electrode on a ceramic substrate to form a capacitor or the like, comprising the steps of: applying an electroconductive paste to said ceramic substrate, said paste comprising about 100 parts of zinc powder, from about 0.01 to 15.00 parts by weight of an organic titanium compound, and an organic vehicle for pasting the mixture of the zinc powder and the organic titanium; baking said ceramic substrate with the paste thereon to drive off the organic vehicle, whereby said organotitanium compound inhibits the oxidation of said zinc during said baking step, so that the unoxidized interiors of the zinc particles expand, breaking the oxide coatings thereon and are fused to one another, whereby an electrical conductor is formed of said zinc powders.
Claim 3
Dependent Claim 14 words
The method of claim 1 wherein the zinc powder is of substantially spherical particles.
Claim 4
Independent Claim 24 words
The method of either of claims 1 or 2, wherein the zinc powder has a particle size ranging from about 0.1 to 30.0 microns.
Claim 5
Dependent Claim 24 words
The method of claim 1 wherein the organic titanium compound is selected from the class consisting of tetrakisstearoxytitanium, tetrabutoxytitanium, di-n-butoxydibenzyltitanium, di-i-propoxybisacetylacetonatetitanium, di-n-butoxybistriethanolaminatetitanium, and dihydroxybislactatetitanium.
Claim 6
Independent Claim 38 words
The method of claims 1 or 4, further comprising from about 0.01 to 5.00 parts by weight of an additive selected from the class consisting of lead, bismuth, prasedoymium, copper, cadmium, and the compounds of these metallic elements.
Claim 7
Dependent Claim 10 words
The method of claim 5 wherein the compounds are oxides.
Claim 8
Dependent Claim 25 words
The method of claim 6 wherein the oxides of the metallic elements include red lead oxide, bismuth trioxide, praseodymia, black copper oxide, and cadmium oxide.

References Cited (Backward Citations)

BE650584A Cited
US3832204A Cited
US3796582A Cited
US3725836A Cited
US3817905A Cited
US4097911A Cited
US4168519A Cited
US4138369A Cited

USPTO Annuity & Maintenance Windows

Annuity Stage Window Opens Payment Deadline Surcharge Period Until Estimated Fee Status
3.5 Years (Year 4) 1987-07-17 1988-01-16 1988-07-17 $2000.00 Window Closed / Lapsed
7.5 Years (Year 8) 1991-07-17 1992-01-16 1992-07-17 $3760.00 Window Closed / Lapsed
11.5 Years (Year 12) 1995-07-17 1996-01-16 1996-07-17 $7700.00 Window Closed / Lapsed

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