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Thermoplastic compositions of vinyl chloride polymers and imide containing polymers

Assignee: Ethyl Corp
•
Filing: 1982-07-20
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Granted: 1984-07-03
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Expires: 2002-07-20
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Abstract

Abstract A thermoplastic composition made up of an intimate admixture of (a) a vinyl chloride polymer, and (b) a thermoplastic copolymer of vinyl aromatic compound and an imide derivative of an ethylenically unsaturated dicarboxylic acid. The preferred blends contain from 90 to 40 weight percent of (a) and 10 to 60 weight percent of (b).

Inventors

  • 👤 Edwin D. Hornbaker
  • 👤 Jesse D. Jones

Bibliographic Details

Application Number —
Jurisdiction US
Data Source google_patents
Last Synchronized 2026-11-02 09:17
CPC Classifications
C; C08; C08L; C08L27/00; C08L27/02; C08L27/04; C08L27/06; C08L35/00; C08L35/06

Claims Analysis

Total Claims: 33
Claim 1
Independent Claim 83 words
A thermoplastic composition which comprises in intimate admixture: (a) a vinyl chloride polymer; and (b) (i) a thermoplastic binary copolymer of a vinyl aromatic compound and an imide derivative of an ethylenically unsaturated dicarboxylic acid or (II) a thermoplastic ternary copolymer of a vinyl aromatic compound, an imide derivative of an ethylenically unsaturated dicarboxylic acid and an anyhydride derivative of an ethylenically unsaturated dicarboxylic acid; said admixture containing 90 to 40 weight percent of (a) and 10 to 60 weight percent of (b).
Claim 2
Dependent Claim 83 words
A thermoplastic composition which comprises in intimate admixture: (a) a vinyl chloride polymer; and (b) (i) a thermoplastic binary copolymer of a vinyl aromatic compound and an imide derivative of an ethylenically unsaturated dicarboxylic acid or (II) a thermoplastic ternary copolymer of a vinyl aromatic compound, an imide derivative of an ethylenically unsaturated dicarboxylic acid and an anyhydride derivative of an ethylenically unsaturated dicarboxylic acid; said admixture containing 90 to 40 weight percent of (a) and 10 to 60 weight percent of (b).
Claim 3
Dependent Claim 29 words
A composition of claim 1 wherein (b) is (i) a copolymer of a styrene monomer and maleimide or (ii) a copolymer of a styrene monomer, maleimide and maleic anhydride.
Claim 4
Dependent Claim 56 words
A composition of claim 1 wherein (b) is a styrene-maleimide copolymer containing about 95 to about 75 weight percent of styrene and about 5 to about 25 weight percent of maleimide, and from zero up to about 25 parts by weight of a rubber per 100 parts by weight of the resin phase of said copolymer.
Claim 5
Dependent Claim 60 words
A composition of claim 1 wherein (b) is a styrene-maleimide-maleic anhydride copolymer containing about 95 to about 75 weight percent of styrene and about 5 to about 25 weight percent of maleimide and maleic anhydride, and from zero up to about 25 parts by weight of a rubber per 100 parts by weight of the resin phase of said copolymer.
Claim 6
Dependent Claim 26 words
A composition of claim 1 wherein said admixture contains about 60 to 40 weight percent of (a) and about 40 to 60 weight percent of (b).
Claim 7
Dependent Claim 22 words
A composition of claim 1 wherein said admixture contains about 50 weight percent of (a) and about 50 weight percent of (b).
Claim 8
Dependent Claim 10 words
A composition of claim 1 wherein (a) is polyvinyl chloride.
Claim 9
Dependent Claim 40 words
A composition of claim 1 wheren (a) is polyvinyl chloride having a relative viscosity as measured at a concentration of 1 gram per 100 grams of cyclohexanone at 25° C. falling within the range of about 1.50 to about 1.85.
Claim 10
Dependent Claim 34 words
A composition of claim 1 wherein (a) is polyvinyl chloride and (b) is (i) a copolymer of a styrene monomer and maleimide or (ii) a copolymer of a styrene monomer, maleimide and maleic anhydride.
Claim 11
Dependent Claim 91 words
A composition of claim 1 wherein (a) is polyvinyl chloride having a relative viscosity as measured at a concentration of 1 gram per 100 grams of cyclohexanone at 25° C. falling within the range of about 1.50 to about 1.85 and (b) is a styrene-maleimide copolymer containing about 95 to about 75 weight percent of styrene and about 5 to about 25 weight percent of maleimide, and from zero up to about 25 parts by weight of a rubber per 100 parts by weight of the resin phase of said copolymer.
Claim 12
Dependent Claim 95 words
A composition of claim 1 wherein (a) is polyvinyl chloride having a relative viscosity as measured at a concentration of 1 gram per 100 grams of cyclohexanone at 25° C. falling within the range of about 1.50 to about 1.85 and (b) is a styrene-maleimide-maleic anhydride copolymer containing about 95 to about 75 weight percent of styrene and about 5 to about 25 weight percent of maleimide and maleic anhydride, and from zero up to about 25 parts by weight of a rubber per 100 parts by weight of the resin phase of said copolymer.
Claim 13
Dependent Claim 91 words
A composition of claim 1 wherein (a) is polyvinyl chloride having a relative viscosity as measured at a concentration of 1 gram per 100 grams of cyclohexanone at 25° C. falling within the range of about 1.50 to about 1.65, and (b) is a styrene-maleimide copolymer containing about 90 to about 80 weight percent of styrene and about 10 to about 20 weight percent of maleimide, and from zero up to about 25 parts by weight of a rubber per 100 parts by weight of the resin phase of said copolymer.
Claim 14
Dependent Claim 95 words
A composition of claim 1 wherein (a) is polyvinyl chloride having a relative viscosity as measured at a concentration of 1 gram per 100 grams of cyclohexanone at 25° C. falling within the range of about 1.50 to about 1.65, and (b) is a styrene-maleimide-maleic anhydride copolymer containing about 90 to about 80 weight percent of styrene and about 10 to about 20 weight percent of maleimide and maleic anhydride, and from zero up to about 25 parts by weight of a rubber per 100 parts by weight of the resin phase of said copolymer.
Claim 15
Dependent Claim 23 words
A composition of claim 1 wherein said admixture additionally contains at least a thermal stabilizer and an impact modifier for vinyl chloride polymers.
Claim 16
Dependent Claim 12 words
A composition of claim 14 wherein the stabilizer is a lead stabilizer.
Claim 17
Dependent Claim 16 words
A composition of claim 14 wherein the impact modifier includes an impact modifier of the MBS-type.
Claim 18
Dependent Claim 94 words
A thermoplastic composition which comprises in intimate admixture: (a) a vinyl chloride polymer; and (b) (i) a rubber-modified thermoplastic binary copolymer of a vinyl aromatic compound and an imide derivative of an ethylenically unsaturated dicarboxylic acid grafted onto a substrate rubber or (ii) a thermoplastic ternary copolymer of a vinyl aromatic compound, an imide derivative of an ethylenically unsaturated dicarboxylic acid and an anhydride derivative of an ethylenically unsaturated dicarboxylic acid grafted onto a substrate rubber; said admixture containing 90 to 25 weight percent of (a) and 10 to 75 weight percent of (b).
Claim 19
Dependent Claim 94 words
A thermoplastic composition which comprises in intimate admixture: (a) a vinyl chloride polymer; and (b) (i) a rubber-modified thermoplastic binary copolymer of a vinyl aromatic compound and an imide derivative of an ethylenically unsaturated dicarboxylic acid grafted onto a substrate rubber or (ii) a thermoplastic ternary copolymer of a vinyl aromatic compound, an imide derivative of an ethylenically unsaturated dicarboxylic acid and an anhydride derivative of an ethylenically unsaturated dicarboxylic acid grafted onto a substrate rubber; said admixture containing 90 to 25 weight percent of (a) and 10 to 75 weight percent of (b).
Claim 20
Dependent Claim 31 words
A composition of claim 17 wherein (b) is (i) a rubber-modified copolymer of a styrene monomer and maleimide or (ii) a rubber-modified copolymer of a styrene monomer, maleimide and maleic anhydride.
Claim 21
Dependent Claim 55 words
A composition of claim 17 wherein (b) is a rubber-modified styrene-maleimide copolymer containing about 95 to about 75 weight percent of styrene and about 5 to about 25 weight percent of maleimide, and up to about 35 parts by weight of a rubber per 100 parts by weight of the resin phase of said copolymer.
Claim 22
Dependent Claim 35 words
A composition of claim 19 wherein the rubber-modified copolymer of (b) contains about 5 to about 25 parts by weight of a rubber per 100 parts by weight of the resin phase of said copolymer.
Claim 23
Dependent Claim 59 words
A composition of claim 17 wherein (b) is a rubber-modified styrene-maleimide-maleic anhydride copolymer containing about 95 to about 75 weight percent of styrene and about 5 to about 25 weight percent of maleimide and maleic anhydride, and up to about 35 parts by weight of a rubber per 100 parts by weight of the resin phase of said copolymer.
Claim 24
Dependent Claim 35 words
A composition of claim 21 wherein the rubber-modified copolymer of (b) contains about 5 to about 25 parts by weight of a rubber per 100 parts by weight of the resin phase of said copolymer.
Claim 25
Dependent Claim 28 words
A composition of claim 17 wherein said admixture contains about 60 to about 35 weight percent of (a) and about 40 to about 65 weight percent of (b).
Claim 26
Dependent Claim 22 words
A composition of claim 17 wherein said admixture contains about 50 weight percent of (a) and about 50 weight percent of (b).
Claim 27
Dependent Claim 11 words
A composition of claim 17 wherein (a) is a polyvinyl chloride.
Claim 28
Dependent Claim 40 words
A composition of claim 17 wherein (a) is polyvinyl chloride having a relative viscosity as measured at a concentration of 1 gram per 100 grams of cyclohexanone at 25° C. falling within the range of about 1.50 to about 1.65.
Claim 29
Dependent Claim 36 words
A composition of claim 17 wherein (a) is polyvinyl chloride and (b) is (i) a rubber-modified copolymer of a styrene monomer and maleimide or (ii) a rubber-modified copolymer of a styrene monomer, maleimide and maleic anhydride.
Claim 30
Dependent Claim 103 words
A composition of claim 17 wherein (a) is polyvinyl chloride having a relative viscosity as measured at a concentration of 1 gram per 100 grams of cyclohexanone at 25° C. falling within the range of about 1.50 to about 1.65, and (b) is (i) a rubber-modified styrene-maleimide copolymer containing about 5 to about 15 parts by weight of a rubber per 100 parts by weight of the resin phase of the copolymer of (ii) a rubber-modified styrene-maleimide-maleic anhydride copolymer containing about 5 to about 15 parts by weight of a rubber per 100 parts by weight of the resin phase of the copolymer.
Claim 31
Dependent Claim 23 words
A composition of claim 17 wherein said admixture additionally contains a least a thermal stabilizer and an impact modifier for vinyl chloride polymers.
Claim 32
Dependent Claim 12 words
A composition of claim 29 wherein the stabilizer is a lead stabilizer.
Claim 33
Dependent Claim 16 words
A composition of claim 29 wherein the impact modifier includes an impact modifier of the MBS-type.

References Cited (Backward Citations)

US3652726A Cited
US3639509A Cited
GB1293542A Cited
US4122130A Cited
US4129614A Cited
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US4284735A Cited
US4339554A Cited
US4311806A Cited

USPTO Annuity & Maintenance Windows

Annuity Stage Window Opens Payment Deadline Surcharge Period Until Estimated Fee Status
3.5 Years (Year 4) 1987-07-03 1988-01-02 1988-07-03 $2000.00 Window Closed / Lapsed
7.5 Years (Year 8) 1991-07-03 1992-01-02 1992-07-03 $3760.00 Window Closed / Lapsed
11.5 Years (Year 12) 1995-07-03 1996-01-02 1996-07-03 $7700.00 Window Closed / Lapsed

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