Polyester containing residues of a 1-hydroxy-3-6-bis(hydroxyalkoxy)xanth-9-one, process for preparing same and shaped articles thereof

Claim 2

A linear polyester which contains in its molecule esterification residues of a 1-hydroxy-3,6-bis(hydroxyalkoxy)xanth-9-one the amount of said residues being 0.01 to 30% by weight based on the total polymer.

Claim 3

A linear polyester according to claim 1 which has an intrinsic viscosity above 0.5 and which contains in its molecule esterification residues of: (A) a dicarboxylic acid selected from (i) terephthalic acid, (ii) isophthalic acid, (iii) naphthalene-2,6-dicarboxylic acid, (iv) bis(carboxyphenoxy)ethane, and (v) an aliphatic carboxylic acid with 4 to 50 carbon atoms in the molecule; (B) a glycol with 2 to 10 carbon atoms in the molecule or a polymeric ether formed from one or more of said glycols, and (C) a 1-hydroxy-3,6-bis(hydroxyalkoxy)xanth-9-one, the amount of (C) being between 0.1 and 30% by weight based on A+B+C.

Claim 4

A linear polyester according to claim 1 in which in the 1-hydroxy-3,6-bis(hydroxyalkoxy)xanth-9-one residue the alkoxy groups have 2 to 4 carbon atoms.

Claim 5

A linear polyester according to claim 1 which contains as repeating unit --OYO--CO--X--CO-- wherein at least 80 mole % of the X groups represent p-phenylene and the remainder represent m-phenylene and at least 90 mole % of the Y groups represent --C n H 2n -- where n is an integer from 2 to 10 and 0.01% to 30% by weight based on the total polymer of the Y groups represent the residue of a 1-hydroxy-3,6-bis(hydroxyalkoxy)xanth-9-one said residues having the formula ##STR1## where n' and n" are integers from 1 to 10.

Claim 6

A linear polyester according to claim 1 which contains as repeating unit: --OYO--CO--X--CO-- wherein at least 70 mole % of the X groups represent p-phenylene and at least x mole % of the X groups represent the esterification residues of dicarboxylic acids with 4 to 40 carbon atoms in the molecule and at least 70 mole % of the Y groups represent --C n H 2n -- where n is an integer from 2 to 10, at least y mole % of the Y groups represent --(C.sub.m H.sub.2m O).sub.m' C.sub.m H.sub.2m -- where m is an integer from 2 to 10 and m' is an integer from 2 to 50 and (x+y) is at least 5 and 0.01 to 30% by weight based on the total polymer of the Y groups represent residues of 1-hydroxy-3,6-bis(hydroxyalkoxy)xanth-9-one said residues having the formula ##STR2## where n' and n" are integers from 1 to 10.

Claim 7

A linear polyester according to claim 4 or 5 in which --C n H 2n -- is --CH 2 CH 2 --.

Claim 8

A linear polyester according to claim 4 or 5 in which n'=n"=2.

Claim 9

A linear polyester according to claim 5 in which the formula: --(C.sub.m H.sub.2m O).sub.m' C.sub.m H.sub.2m -- is --(C.sub.2 H.sub.2 O).sub.m" C.sub.2 H.sub.4 -- or --(C.sub.4 H.sub.8 O).sub.m" C.sub.4 H.sub.8 -- where m" is 15 to 45.

Claim 10

A linear polyester according to claim 2 which contains 0.05 to 5% by weight of residues of the 1-hydroxy-3,6-bis(hydroxyalkoxy)xanth-9-one.

Claim 11

A process for the production of a linear polyester according to claim 2 in which a dicarboxylic acid or a dialkylester thereof and a glycol or a polymeric ether formed from a glycol are reacted together with a 1,3,6-trihydroxy-xanth-9-one whereby one hydroxyl group of the trihydroxyxanthone remains unchanged and the other two react with combined or uncombined glycol to form an ether linkage.

Claim 12

A process for the production of a linear polyester according to claim 12 in which a dicarboxylic acid or a dialkylester thereof and a glycol or a polymeric ether formed from a glycol are reacted together with a 1-hydroxy-3,6-bis(hydroxyalkoxy)xanth-9-one whereby the 1-hydroxy group remains unchanged and the two hydroxy-alkoxy groups take part in the polyester-forming reaction.

Claim 13

A process according to claim 10 or 11 in which the dicarboxylic acid comprises terephthalic acid.

Claim 14

A process according to claim 10 or 11 in which the glycol comprises ethylene glycol.

Claim 15

Shaped articles obtained from a linear polyester according to claim 2.