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US4454046A Expired / Lapsed US ⏱️ 0.0 years remaining

Boiler scale prevention employing an organic chelant

Assignee: Dow Chemical Co
•
Filing: 1982-09-07
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Granted: 1984-06-12
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Expires: 2002-09-07
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Abstract

Abstract An improved method of treating boiler water which employs an oxygen scavenging compound and a compound to control pH together with a chelating agent, wherein the chelating agent is hydroxyethylethylenediaminetriacetic acid.

Inventors

  • 👤 Steven L. Wallace
  • 👤 Freddie Griffin, Jr.
  • 👤 Thorwald J. Tvedt, Jr.

Bibliographic Details

Application Number —
Jurisdiction US
Data Source google_patents
Last Synchronized 2026-11-09 03:33
CPC Classifications
C; C02; C02F; C02F5/00; C02F5/08; C02F5/10; C02F5/12; C23; C23F; C23F11/00; C23F11/08

Claims Analysis

Total Claims: 5
Claim 1
Independent Claim 127 words
In a process for the prevention of scale and corrosion in boilers from water containing Fe ++ , Ca ++ , or Mg ++ ions wherein the boiler water is treated with an effective amount of hydrazine as an oxygen scavenger, ammonium hydroxide as a pH control compound and a chelating compound, and wherein the pH is controlled at a value of from about 7 to about 12, the temperature is from about 100° to about 374° C., and the pressure is from about 15 to about 3200 psia the improvement which comprises adding to the boiler water as the chelating compound hydroxyethylethylenediaminetriacetic acid in an amount of from about 1 to about 10 moles of chelant per mole of scale or corrosion producing metal ions present.
Claim 2
Dependent Claim 127 words
In a process for the prevention of scale and corrosion in boilers from water containing Fe ++ , Ca ++ , or Mg ++ ions wherein the boiler water is treated with an effective amount of hydrazine as an oxygen scavenger, ammonium hydroxide as a pH control compound and a chelating compound, and wherein the pH is controlled at a value of from about 7 to about 12, the temperature is from about 100° to about 374° C., and the pressure is from about 15 to about 3200 psia the improvement which comprises adding to the boiler water as the chelating compound hydroxyethylethylenediaminetriacetic acid in an amount of from about 1 to about 10 moles of chelant per mole of scale or corrosion producing metal ions present.
Claim 3
Dependent Claim 26 words
The process of claim 1 wherein the hydroxyethylethylenediaminetriacetic acid is added in the form of an alkali metal, ammonia or amine salts or a combination thereof.
Claim 4
Dependent Claim 17 words
The process of claim 2 wherein the pH of the boiler water is from 9 to 10.
Claim 5
Dependent Claim 27 words
The process of claim 1 or 2 wherein the chelating agent is employed in a ratio from about 1.2 to 2 for each mole of metal ion.

References Cited (Backward Citations)

US1997256A Cited
US3099521A Cited
US3235324A Cited
US3492240A Cited
US3463730A Cited
US3549538A Cited
US3527609A Cited
US3684720A Cited
US4011171A Cited
US4306991A Cited

USPTO Annuity & Maintenance Windows

Annuity Stage Window Opens Payment Deadline Surcharge Period Until Estimated Fee Status
3.5 Years (Year 4) 1987-06-12 1987-12-12 1988-06-12 $2000.00 Window Closed / Lapsed
7.5 Years (Year 8) 1991-06-12 1991-12-12 1992-06-12 $3760.00 Window Closed / Lapsed
11.5 Years (Year 12) 1995-06-12 1995-12-12 1996-06-12 $7700.00 Window Closed / Lapsed

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